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    Metal-Organic Framework Materials Comprising A Pyrazolylbenzoate Ligand and Methods for Production Thereof
    41.
    发明申请
    Metal-Organic Framework Materials Comprising A Pyrazolylbenzoate Ligand and Methods for Production Thereof 有权

    公开(公告)号：US20220305456A1

    公开(公告)日：2022-09-29

    申请号：US17607168

    申请日：2020-05-26

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Joseph M. Falkowski ,  Yogesh V. Joshi ,  Mary S. Abdulkarim ,  Simon C. Weston

    IPC: B01J20/22 ,  B01J20/28 ,  C07C7/12 ,  C07F3/06

    Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Some highly porous MOFs lack stability at ambient conditions. MOFs having ambient condition stability may comprise a plurality of metal clusters (M4O clusters, M=a metal), and a plurality of 4-(1H-pyrazol-4-yl)benzoate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. Methods for synthesizing these MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-(1H-pyrazol-4-yl)benzoic acid, and reacting the preformed metal cluster with the 4-(1H-pyrazol-4-yl)benzoic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-(1H-pyrazol-4-yl)benzoate.

    Process and System to Make Olefin Epoxides
    45.
    发明申请
    Process and System to Make Olefin Epoxides 有权

    公开(公告)号：US20220169624A1

    公开(公告)日：2022-06-02

    申请号：US17597888

    申请日：2020-06-30

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Kun Wang ,  Timothy D. Shaffer

    IPC: C07D301/19

    Abstract: Processes and systems for producing olefin epoxides with three or more carbon atoms by oxidation of the corresponding branched hydrocarbons using oxygen are disclosed. An example process for producing olefin epoxides may include oxidizing a branched alkane to produce at least an organic hydroperoxide. The example process may further include epoxidizing a branched alkene by a catalytic reaction with least a portion of the organic hydroperoxide to produce at least an olefin epoxide and an alcohol. The example process may further include converting at least a portion of the alcohol to either additional branched alkane and/or additional branched alkene.

    Metal-Organic Framework Materials Comprising A Diimine Scaffold and Methods For Production Thereof
    46.
    发明申请
    Metal-Organic Framework Materials Comprising A Diimine Scaffold and Methods For Production Thereof 有权

    公开(公告)号：US20220153757A1

    公开(公告)日：2022-05-19

    申请号：US17310622

    申请日：2020-03-30

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Joseph M. Falkowski ,  Carter W. Abney ,  Mary S. Abdulkarim ,  Aaron Sattler ,  Michele Paccagnini ,  Simon C. Weston

    IPC: C07F3/06 ,  C07F15/04 ,  C01B37/00

    Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Crystallization may be problematic in some instances when secondary binding sites are present in the multidentate organic ligand. Multidentate organic ligands comprising first and second binding sites bridged together with a third binding site comprising a diimine moiety may alleviate these issues, particularly when using a preformed metal cluster as a metal source to form a MOF. Such MOFs may comprise a plurality of metal centers, and a multidentate organic ligand coordinated to the plurality of metal centers to define an at least partially crystalline network structure having a plurality of internal pores, and in which the multidentate organic ligand comprises first and second binding sites bridged together with a third binding site comprising a diimine moiety. Particular MOFs may comprise N,N′-di(1H-pyrazol-4-yl)ethane-1,2-diimine as a multidentate organic ligand.

    FCC CO-PROCESSING OF BIOMASS OIL
    47.
    发明申请
    FCC CO-PROCESSING OF BIOMASS OIL 有权

    公开(公告)号：US20220145188A1

    公开(公告)日：2022-05-12

    申请号：US17453191

    申请日：2021-11-02

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Hyung R. Kim ,  Jihad M. Dakka ,  Xiaochun Xu

    IPC: C10G3/00 ,  C10G47/30 ,  C01B3/12

    Abstract: Systems and methods are provided for co-processing of biomass oil in a fluid catalytic cracking (FCC) system that include recovering an additional source of H2 or synthesis gas from the overhead product gas stream. The additional H2 can be used to partially hydrogenate biomass oil prior to co-processing the biomass oil in the fluid catalytic cracking system. Additionally or alternately, the additional synthesis gas can represent an additional yield of products from the process, such as an additional yield that can be used for synthesis of further liquid products.

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