PROCESS FOR MAKING AND REFINING 3-PENTENENITRILE, AND FOR REFINING 2-METHYL-3-BUTENENITRILE
    43.
    发明申请
    PROCESS FOR MAKING AND REFINING 3-PENTENENITRILE, AND FOR REFINING 2-METHYL-3-BUTENENITRILE 审中-公开
    制备和精制3-苯并呋喃和精制2-甲基-3-保护素的方法

    公开(公告)号:WO2009091771A2

    公开(公告)日:2009-07-23

    申请号:PCT/US2009/030913

    申请日:2009-01-14

    Abstract: The invention provides an integrated, continuous process for the production of 3-pentenenitrile, the refining of 3-pentenenitrile, and the refining of 2-methyl-3-butenenitrile, the process comprising: (a) contacting, in a reaction zone, a hydrogen cyanide-containing feed, a butadiene-containing feed, and a catalyst composition, wherein the catalyst composition comprises a zero-valent nickel and at least one bidentate phosphorus-containing ligand selected from the group consisting of a phosphite, a phosphonite, a phosphinite, a phosphine, a mixed phosphorus-containing ligand, and combination thereof; (b) maintaining a residence time in the reaction zone sufficient to convert about 95% or more of the hydrogen cyanide and to produce a reaction mixture comprising 3-pentenenitrile and 2-methyi-3-butenenitrile, wherein the 2-methyl-3- butenenitrile concentration is maintained below about 15 weight percent of the total mass of the reaction mixture; (c) distilling the reaction mixture to obtain a first stream comprising 1,3- butadiene, a second stream comprising 3-pentenenitrile, 2-methyl-3-butenenitrile, (Z)-2-methyl-2-butenenitrile, and optionally 1,3-butadiene, and a third stream comprising the catalyst composition; (d) distilling the second stream to obtain a fourth stream comprising 1,3- butadiene, a fifth stream comprising 2-methyl-3-butenenitrile, (Z)-2-methyl-2- butenenitrile, and optionally 1,3-butadiene, and a sixth stream comprising 3- pentenenitrile; and (e) distilling the fifth stream to obtain a seventh stream comprising 1,3- butadiene, an eighth stream comprising (Z)-2-methyl-2-butenenitrile, and a ninth stream comprising 2-methyl-3-butenenitrile.

    Abstract translation: 本发明提供了一种用于生产3-戊烯腈的整合的连续方法,3-戊烯腈的精制和2-甲基-3-丁烯腈的精炼,该方法包括:(a)在反应区中将 含有氰化氢的进料,含丁二烯的进料和催化剂组合物,其中催化剂组合物包含零价镍和至少一种选自亚磷酸酯,亚膦酸酯,亚磷酸盐的二齿含磷配位体 膦,混合含磷配体及其组合; (b)保持反应区中的停留时间足以转化约95%或更多的氰化氢,并产生包含3-戊烯腈和2-甲基-3-丁烯腈的反应混合物,其中2-甲基-3- 丁烯腈浓度保持在反应混合物总质量的约15重量%以下; (c)蒸馏反应混合物以获得包含1,3-丁二烯的第一料流,包含3-戊烯腈,2-甲基-3-丁烯腈,(Z)-2-甲基-2-丁烯腈和任选的1 1,3-丁二烯和包含该催化剂组合物的第三料流; (d)蒸馏第二料流以获得包含1,3-丁二烯的第四料流,包含2-甲基-3-丁烯腈,(Z)-2-甲基-2-丁烯腈和任选的1,3-丁二烯的第五料流 ,和包含3-戊烯腈的第六料流; 和(e)蒸馏第五料流以获得包含1,3-丁二烯的第七料流,包含(Z)-2-甲基-2-丁烯腈的第八料流和包含2-甲基-3-丁烯腈的第九料流。

    MULTILAYER VARIABLE STRETCH NONWOVEN FABRIC COMPOSITES
    44.
    发明申请
    MULTILAYER VARIABLE STRETCH NONWOVEN FABRIC COMPOSITES 审中-公开
    多层可变拉伸非织造布复合材料

    公开(公告)号:WO2009032868A1

    公开(公告)日:2009-03-12

    申请号:PCT/US2008/075168

    申请日:2008-09-04

    Abstract: Disclosed herein are nonwoven fabric composites comprising layers of spunbond and meltblown nonwoven webs. Such composites are prepared by forming or assembling the layers of the composite such that there is at least one outer layer of spunbond fibers disposed on at least one inner meltblown layer. The at least one outer layer comprises substantially parallel stripes of spunbond, continuous filament fibers with at least two different types of stripes being used. The stripes of fibers within the spunbond layer(s) are also predominately oriented in the machine direction of the nonwoven fabric composite. All layers of the fabric composites herein are bonded together via thermal, adhesive, ultra-sonic or mechanical bonding means. Such composites can be fashioned to vary the ratio of cross direction stretch to machine direction stretch.

    Abstract translation: 本文公开了包括纺粘和熔喷非织造纤维网层的非织造织物复合材料。 这样的复合材料通过形成或组装复合材料的层来制备,使得至少一个外层的纺粘纤维设置在至少一个内熔喷层上。 所述至少一个外层包含基本平行的纺粘条带,连续长丝纤维具有至少两种不同类型的条纹。 纺粘层中的纤维条也在无纺织物复合材料的纵向方向上主要取向。 这里的织物复合材料的所有层通过热粘合剂,超声波或机械粘合手段粘合在一起。 这种复合材料可以被形成以改变横向拉伸与机器方向拉伸的比例。

    KNIT FABRICS AND SOCKS MADE THEREFROM INCORPORATING HIGH TENSILE NYLON STAPLE
    46.
    发明申请
    KNIT FABRICS AND SOCKS MADE THEREFROM INCORPORATING HIGH TENSILE NYLON STAPLE 审中-公开
    针织织物和袜子制造高压尼龙书架

    公开(公告)号:WO2008144160A2

    公开(公告)日:2008-11-27

    申请号:PCT/US2008/061373

    申请日:2008-04-24

    Abstract: Knit fabrics and socks made therefrom and a process for producing such articles are disclosed. The fabrics are constructed from blended yarns containing at least 30% by weight high tensile nylon, which imparts abrasion resistance, and at least one companion fiber, which is chosen to confer a specific desirable attribute. Exemplary is the fabric constructed from blended yarn containing high tensile nylon staple and polyester staple, the fabric being particularly useful for the manufacture of socks demonstrating improved durability and moisture management.

    Abstract translation: 公开了由其制成的针织物和袜子及其制造方法。 织物由含有至少30重量%的高拉伸尼龙(其赋予耐磨性)的混纺纱线和至少一个伴随纤维构成,其被选择以赋予特定的期望特性。 示例性的是由含有高拉伸尼龙短纤维和聚酯短纤维的混纺纱线构成的织物,该织物特别可用于制造袜子,其显示出改进的耐久性和湿度管理。

    METHOD FOR THE PURIFICATION OF TRIORGANOPHOSPHITES BY TREATMENT WITH A BASIC ADDITIVE
    47.
    发明申请
    METHOD FOR THE PURIFICATION OF TRIORGANOPHOSPHITES BY TREATMENT WITH A BASIC ADDITIVE 审中-公开
    通过用基本添加剂处理三氯磷酸盐来净化方法

    公开(公告)号:WO2007109005A2

    公开(公告)日:2007-09-27

    申请号:PCT/US2007/006242

    申请日:2007-03-09

    Abstract: The invention provides a method for separating one or more triorganophosphite components from a crude phosphite mixture containing acidic hydrolysis products, the method comprising: contacting said crude phosphite mixture with a basic additive to produce a second mixture comprising a first phase and a second phase, wherein said first phase comprises the basic additive and one or more components independently selected from the group consisting of (R 2 O)(R 3 O)POH, (R 1 O)(HO)PO(H) and H 3 PO 3 , wherein R 1 , R 2 and R 3 are independently selected from the group consisting of C 1 to C 18 alkyl, C 6 to C 18 aryl and hydroxyaryl, and C 3 to C 18 cycloalkyl and hydroxyalkyl radicals, and wherein R 2 and R 3 can optionally be connected to each other directly by a chemical bond or through an intermediate divalent group R 9 ; and said second phase comprises one or more triorganophosphite components independently selected from the group consisting of (R 4 O)(R 5 O)P(OR 6 ) and ((R 7 O)(R 8 O)PO) n A, wherein R 4 , R 5 , R 6 , R 7 and R 8 are independently selected from the group consisting of C 1 to C 18 alkyl, C 6 to C 18 aryl and C 3 to C 18 cycloalkyl radicals, wherein each of R 4 , R 5 and R 6 can optionally be connected to one or both of the other two directly by a chemical bond or through an intermediate divalent group R 10 , wherein R 7 and R 8 can optionally be connected to each other directly by a chemical bond or through an intermediate divalent group R 11 , wherein A is an optionally substituted or unsubstituted aliphatic, aromatic or heteroaromatic radical, and wherein n is an integer greater than 1; and R 9 , R 10, and R 11 are independently selected from the group consisting of - O-, -S-, and -CH(R 12 )-, wherein R 12 is selected from the group consisting of H, C 6 to C 18 aryl, and C 1 to C 18 alkyl.

    Abstract translation: 本发明提供了从含有酸性水解产物的粗亚硫酸盐混合物中分离一种或多种三有机亚磷酸酯组分的方法,所述方法包括:使所述粗亚磷酸酯混合物与碱性添加剂接触以产生包含第一相和第二相的第二混合物,其中 所述第一相包括基本添加剂和独立地选自(R 2 O)(R 3 O)POH,(R O)O) 1 O)(HO)PO(H)和H 3 PO 3,其中R 1,R 2, R 3和R 3独立地选自C 1至C 18烷基,C 6 - 烷基,C 6 - C 18 -C 18芳基和羟基芳基,C 3〜C 18环烷基和羟烷基,并且其中R 2, SUP>和R 3可以任选地通过化学键直接连接或通过中间二价基团R 9彼此连接; 并且所述第二相包含一种或多种独立选自(R 4 O)(R 5 O)P(OR 6 O))的三有机亚磷酸酯成分, SUP))和((R 7 O)(R 8 O)PO)n A A,其中R 4 O / >,R 5,R 6,R 7和R 8独立地选自C C 1至C 18烷基,C 6至C 18芳基和C 3〜 至C 18环烷基,其中R 4,R 5和R 6中的每一个可以任选地连接到 其中一个或两个直接通过化学键或通过中间二价基团R 10,其中R 7和R 8可任选地 通过化学键直接连接或通过中间二价基团R 11彼此连接,其中A是任选取代或未取代的脂族,芳族或杂芳族基团,其中ni s大于1的整数; 和R 9,R 10,R 11和R 11独立地选自-O - , - S - 和-CH (R 12) - ,其中R 12选自H,C 6至C 18

    PROCESS OF MAKING 3-AMINOPENTANENITRILE
    48.
    发明申请
    PROCESS OF MAKING 3-AMINOPENTANENITRILE 审中-公开
    制备3-氨基戊酸的方法

    公开(公告)号:WO2007046799A1

    公开(公告)日:2007-04-26

    申请号:PCT/US2005/037642

    申请日:2005-10-18

    Inventor: AMEY, Ronald L.

    CPC classification number: C07C253/30 C07C255/24

    Abstract: A process for making 3-aminopentanenitrile from a crude 2-pentenenitrile ("crude 2PN") comprising 2-pentenenitrile, 2-methyl-2-butenenitrile, and 2-methyl-3-butenenitrile includes contacting the crude 2PN with an ammonia-containing fluid and water. The ammonia-containing fluid can include at least one reactant selected from the group consisting of ammonia, aqueous ammonia, and ammonium hydroxide.

    Abstract translation: 包含2-戊烯腈,2-甲基-2-丁烯腈和2-甲基-3-丁烯腈的粗2-戊烯腈(“粗制2PN”)制备3-氨基戊腈的方法包括使粗制2PN与含氨的 流体和水。 含氨流体可以包括至少一种选自氨,氨水和氢氧化铵的反应物。

    A COMPACT SINGLE MANDREL CREEL FOR OVER END TAKE-OFF THREAD DELIVERY
    49.
    发明申请
    A COMPACT SINGLE MANDREL CREEL FOR OVER END TAKE-OFF THREAD DELIVERY 审中-公开
    一个紧凑的单人马桶,用于结束切断螺纹输送

    公开(公告)号:WO2007044823A1

    公开(公告)日:2007-04-19

    申请号:PCT/US2006/039773

    申请日:2006-10-10

    CPC classification number: D02H1/00 B65H49/12 B65H49/16 B65H2701/31 D03D47/34

    Abstract: The present invention relates to a compact creel using the OETO method that accommodates an increased number of packages in a relatively small footprint while providing a straight in-line delivery path in which fiber bends and changes in direction are minimized. In addition, the present invention is a system, apparatus and method for tension control in a fiber feeding system that provides a fast and reliable method for feeding high tack elastomeric thread or fiber from a package to a manufacturing process. Furthermore, the present invention provides a method and apparatus for changing packages on a creel without interrupting the manufacturing process. In particular, the compact creel of the present invention provides for continuous operation of unwinding and fiber delivery by allowing a standby package to be loaded on the same mandrel as an active package that is presently being unwound.

    Abstract translation: 本发明涉及一种使用OETO方法的紧凑型架架,其在相对小的占地面积中容纳增加数量的包装,同时提供了一种直线的直线传送路径,其中纤维弯曲和方向变化最小化。 另外,本发明是一种用于纤维馈送系统中的张力控制的系统,装置和方法,其提供了用于将高粘性弹性体线或纤维从包装送入制造过程的快速可靠的方法。 此外,本发明提供了一种用于在不中断制造过程的情况下改变纱架架上的包装的方法和装置。 特别地,本发明的紧凑型上架架通过允许待机包装被装载在与当前正在展开的活动包装件相同的芯轴上,从而可以连续地进行展开和纤维输送。

    SCALLOPED OVAL BICOMPONENT FIBERS WITH GOOD WICKING, AND HIGH UNIFORMITY SPUN YARNS COMPRISING SUCH FIBERS
    50.
    发明申请
    SCALLOPED OVAL BICOMPONENT FIBERS WITH GOOD WICKING, AND HIGH UNIFORMITY SPUN YARNS COMPRISING SUCH FIBERS 审中-公开
    带有良好的点烟器的高分子椭圆形双面纤维,以及包含这种纤维的高均匀弹力纱线

    公开(公告)号:WO2007040848A1

    公开(公告)日:2007-04-12

    申请号:PCT/US2006/032373

    申请日:2006-08-17

    Abstract: The invention provides a polyester bicomponent staple fiber comprising poly(trimethylene terephthalate) and at least one polymer selected from the group consisting of poly(ethylene terephthalate), poly(trimethylene terephthalate), and poly(tetramethylene terephthalate) or a combination of such members, said bicomponent staple fiber having: a) a scalloped oval cross-section shape having an aspect ratio a:b of about 2:1 to about 5:1 wherein 'a' is a fiber cross-section major axis length and 'b' is a fiber cross- section minor axis length; b) a polymer interface substantially perpendicular to the major axis; c) a cross-section configuration selected from the group consisting of side-by- side and eccentric sheath-core; d) a plurality of longitudinal grooves; and e) a groove ratio of about 1.05:1 to about 1.9:1. Additionally, the invention provides a spun yarn comprising cotton and the polyester bicomponent staple fiber of the invention, as well as fabrics and garments comprising the spun yarn of the invention.

    Abstract translation: 本发明提供一种包含聚(对苯二甲酸丙二醇酯)和至少一种选自聚(对苯二甲酸乙二醇酯),聚(对苯二甲酸丙二醇酯)和聚(对苯二甲酸四亚甲酯))或其组合的聚合物双组分短纤维, 所述双组分短纤维具有:a)具有约2:1至约5:1的纵横比a:b的扇形椭圆形横截面形状,其中“a”是纤维横截面长轴长度,“b”是 纤维横截面短轴长度; b)基本上垂直于长轴的聚合物界面; c)选自并列和偏心皮芯的横截面构型; d)多个纵向凹槽; 和e)约1.05:1至约1.9:1的槽比。 另外,本发明提供了一种包含棉和本发明的聚酯双组分短纤维的细纱,以及包含本发明纺织纱线的织物和服装。

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