Abstract:
The present invention refers to a hybrid photopolymer composition for additive manufacturing, comprising 50-95% by weight of a free radically curable-component, farther comprising at least one (meth)acrylate monomer or oligomer, 5-49% by weight of a cationically curable component, further comprising a cycloaliphatic epoxide, an oxetane mixture, containing a monooxetane compound and a polyoxetane compound, and a thermoplastic polycaprolactone with a molecular weight of 20,000-100,000 g/mol, a free radical photoinitiator, a UV blocker, a cationic photoinitiator, optionally a cationic photosensitiser, and optionally a thermal initiator, wherein the percent by weight is based on the total weight of the photopolymer' composition. The invention also relates to the use of a photopolymer composition according to the present invention for producing a three-dimensional object through additive manufacturing and to a three-dimensional object obtained through additive manufacturing using the photopolymer composition—according the present invention.
Abstract:
Disclosed is an oxidatively drying alkyd resin composition and a method for preparing said composition. Said composition is obtained by admixing an aqueous silica sol into a substantially 100% alkyd resin being in a liquid state either at ambient temperature or at an elevated temperature. Said silica sol is added in an amount of 0.1-10% by weight calculated as 100% silica on 100% alkyd resin. The use of a said composition is in a further aspect disclosed.
Abstract:
Disclosed is an oxidatively drying alkyd resin composition and a method for preparing said composition. Said composition is obtained by admixing an aqueous silica sol into a substantially 100% alkyd resin being in a liquid state either at ambient temperature or at an elevated temperature. Said silica sol is added in an amount of 0.1-10% by weight calculated as 100% silica on 100% alkyd resin. The use of a said composition is in a further aspect disclosed.
Abstract:
The present invention refers to a method for producing a low-emitting plasticised polyvinylchloride composition, having a fusion time of less than 5.50 s and a volatility of less than 10% weight loss, by mixing pentaerythritol tetravalerate with a polyvinylchloride composition, the fusion time being measured according to DIN 54 802 and ISO/DIS 4574 and the volatility being measured according to ISO 176 Method A. In a further aspect the present invention refers to a thermoplastic article suitable for use in environments where the article is exposed to heat, wherein the thermoplastic article is based on a plasticized polyvinylchloride composition produced by the method of the present invention.
Abstract:
Disclosed is a process for obtaining an acrylic compound haying a tertaoxaspiro backbone and at least one acrylic unsaturation. Said compound is in embodiments an acrylate, a methacrylate or a crotonate of an alkoxylated, such as an ethoxylated, a propoxylated and/or a butoxylated 2,4,8,10-tetraoxaspiro[5.5]undecane-3, 9- dialkanol.
Abstract in simplified Chinese:本文揭示一种紫外线固化涂布组成物,包含(a)40-70%重量比之至少一种胺基甲酸乙酯(甲基)丙烯酸酯,其为至少一种聚己内酯多元醇(a1)与至少一种加合物(a2)间之反应产物,该加合物(a2)为至少一种多异氰酸酯(a3)与至少一种(甲基)丙烯酸羟基烷酯(a4)间之反应产物,该聚己内酯多元醇(a1)为至少一种多烷氧基化多元醇(a5)与至少一种己内酯单体(a6)间之反应产物,(b)20-50%重量比之具有至少一个烯属碳-碳双键的至少一种反应性稀释剂,及(c)0.5-10%重量比之至少一种光起始剂,及选择性地(d)1-15%重量比之至少一种消光剂。