公开(公告)号：KR1020130101936A

公开(公告)日：2013-09-16

申请号：KR1020120023063

申请日：2012-03-06

Applicant: 삼성전자주식회사

Inventor： 권순철 ,  서정길 ,  권혁재 ,  이현철

IPC: B01J20/04 ,  B01J20/284 ,  B01J20/28 ,  B01D53/62

CPC classification number: B01J20/3078 ,  B01D53/02 ,  B01D2251/302 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/402 ,  B01D2253/112 ,  B01D2253/1124 ,  B01D2253/25 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/80 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/28004 ,  B01J20/28083 ,  B01J20/28097 ,  B01J20/3204 ,  B01J20/3236 ,  Y02C10/08 ,  Y10T428/2982

Abstract: PURPOSE: A carbon dioxide adsorbent is provided to be able to be operated at a high temperature, to have an excellent capture capacity of carbon dioxide, and therefore, to be able to be usefully used in adsorption of pre-combustion carbon dioxide as well as carbon dioxide generated in combustion. CONSTITUTION: A carbon dioxide adsorbent (10) includes a porous inorganic oxide (1) having multiple mesopores (5), and active compounds combined to the surface of the mesopores. The active compounds are selected from alkali metal-containing compounds, alkali earth metal-containing compounds and a combination thereof. The mesopore has an average pore diameter of 2-50 nm. The porous inorganic oxide is selected from silica, alumina, titania, zirconia, tin oxide, cobalt oxide, zinc oxide, indium oxide, nickel oxide, hafnium oxide, vanadium oxide and a combination thereof. A manufacturing method of the carbon dioxide adsorbent comprises a step of providing an acidic aqueous solution; a step of adding an inorganic oxide precursor to the acidic aqueous solution to hydrate; a step of adding an active compound precursor selected from alkali metal-containing compounds, alkali earth metal-containing compounds, and a combination thereof and drying; and a step of plasticizing the dried product.

Abstract translation: 目的：提供二氧化碳吸附剂以能够在高温下运行，具有优异的二氧化碳捕集能力，因此能够有效地用于预燃二氧化碳的吸附以及 燃烧中产生的二氧化碳。 构成：二氧化碳吸附剂（10）包括具有多个介孔（5）的多孔无机氧化物（1）和与介孔表面结合的活性化合物。 活性化合物选自含碱金属的化合物，含碱土金属的化合物及其组合。 中孔的平均孔径为2-50nm。 多孔无机氧化物选自二氧化硅，氧化铝，二氧化钛，氧化锆，氧化锡，氧化钴，氧化锌，氧化铟，氧化镍，氧化铪，氧化钒及其组合。 二氧化碳吸附剂的制造方法包括提供酸性水溶液的工序; 向酸性水溶液中添加无机氧化物前体进行水合的工序; 添加选自碱金属化合物，含碱土金属的化合物及其组合的活性化合物前体的干燥步骤; 以及使干燥产品增塑的步骤。