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公开(公告)号:KR100471561B1
公开(公告)日:2005-03-08
申请号:KR1020010086692
申请日:2001-12-28
Applicant: 제일모직주식회사
IPC: C08L51/04
Abstract: 본 발명의 유리섬유 강화 스티렌계 열가소성 복합재료는 (A)스티렌계 그라프트 공중합체 5-65 중량부; (B) 스티렌계 공중합체 또는 이들 공중합체의 혼합물 5-65 중량부; (C) 비닐계 단량체와 N-치환 말레이미드 공중합체 5-65 중량부; (D) MMA를 도입한 고무변성 스티렌계 공중합체 1 내지 30 중량부; (E) 유리섬유 5-50 중량부; (F) 할로겐계 난연제 1-30 중량부; 및 (G) 삼산화안티몬 1-10 중량부로 이루어진다.
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公开(公告)号:KR1020040004774A
公开(公告)日:2004-01-16
申请号:KR1020020038802
申请日:2002-07-05
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08J2300/22 , C08K5/521 , C08K7/14 , C08K9/06 , C08K2003/3045 , C08L25/10 , C08L25/12 , C08L71/12 , C08L2205/02
Abstract: PURPOSE: A styrene-based thermoplastic resin composition is provided, to improve mechanical properties and flame retardancy and to reduce environmental pollution. CONSTITUTION: The resin composition comprises (A) 40-95 parts by weight of the rubber-modified styrene-based resin which comprises 20-100 wt% of a styrene-containing graft copolymer resin comprising 10-60 wt% of a rubber component and 40-90 wt% of a styrene-acrylonitrile copolymer resin and 0-80 wt% of a styrene-containing copolymer resin, and whose acrylonitrile content in the components except a rubber component is 18-50 wt%; (B) 0-60 parts by weight of a rubber-reinforced polystyrene resin; (C) 5-60 parts by weight of a polyphenylene ether-based resin; (D) 2-40 parts by weight of a styrene-acrylonitrile copolymer resin whose acrylonitrile content is 5-18 wt% based on 100 parts by weight of (A)+(B)+(C); (E) 5-40 parts by weight of a phosphoric ester compound based on 100 parts by weight of (A)+(B)+(C); (F) 0.3-50 parts by weight of a metal sulfate salt based on 100 parts by weight of (A)+(B)+(C); and (G) 10-100 parts by weight of glass fiber based on 100 parts by weight of (A)+(B)+(C).
Abstract translation: 目的:提供苯乙烯类热塑性树脂组合物,以改善机械性能和阻燃性,并减少环境污染。 构成:树脂组合物包含(A)40-95重量份的橡胶改性苯乙烯基树脂,其包含20-100重量%的含有10-60重量%橡胶组分的含苯乙烯的接枝共聚物树脂和 40-90重量%的苯乙烯 - 丙烯腈共聚物树脂和0-80重量%的含苯乙烯的共聚物树脂,其除橡胶组分以外的组分中的丙烯腈含量为18-50重量% (B)0-60重量份的橡胶增强聚苯乙烯树脂; (C)5-60重量份聚苯醚系树脂; (D)基于100重量份的(A)+(B)+(C),丙烯腈含量为5〜18重量%的苯乙烯 - 丙烯腈共聚物树脂2-40重量份; (E)基于100重量份的(A)+(B)+(C)的5-40重量份的磷酸酯化合物; (F)基于100重量份的(A)+(B)+(C),0.3-50重量份的金属硫酸盐; 和(G)基于100重量份的(A)+(B)+(C)的10-100重量份的玻璃纤维。
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公开(公告)号:KR1020030052525A
公开(公告)日:2003-06-27
申请号:KR1020010082516
申请日:2001-12-21
Applicant: 제일모직주식회사
IPC: C08L51/04
CPC classification number: C08L51/04 , C08J2300/22 , C08K7/14 , C08K9/06 , C08L25/12 , C08L2201/02 , C08L2205/02 , C08L2205/03
Abstract: PURPOSE: A flame retardant glass fiber-reinforced styrene-based thermoplastic composite material is provided, which is improved in the impact resistance and the mechanical strength. CONSTITUTION: The styrene-based thermoplastic composite material comprises (A) 1-50 parts by weight of a styrene-based graft copolymer obtained by graft polymerizing (A-1) 5-95 parts by weight of a monomer mixture comprising 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene or their mixture and 5-50 parts by weight of acrylonitrile, methacrylonitrile, alkyl methacrylate of C1-C8, alkyl acrylate of C1-C8, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixture, to (A2) 5-95 parts by weight of a polymer selected from the group consisting of butadiene rubber, acryl rubber, ethylene-propylene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, isoprene rubber, ethylene-propylene-diene terpolymer, polyorganosiloxane-polyalkyl(meth)acrylate rubber composite and their mixture; (B) 50-95 parts by weight of styrene-based copolymers or their mixture obtained by copolymerizing (B-1) 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene or their mixture and (B-2) 5-50 parts by weight of acrylonitrile, methacrylonitrile, alkyl methacrylate of C1-C8, alkyl acrylate of C1-C8, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixture; (C) 5-50 parts by weight of glass fiber treated with a silane-based coupling agent; and (D) 1-20 parts by weight of a graft copolymer obtained by graft polymerizing (D-1) 40-60 parts by weight of a monomer mixture comprising 10-40 wt% of styrene, α-methylstyrene, halogen or alkyl-substituted styrene or their mixture, 40-80 wt% of methacrylonitrile, alkyl methacrylate of C1-C8, alkyl acrylate of C1-C8 or their mixture, and 1-20 wt% of acrylonitrile, methacrylonitrile, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixture, to (D-2) 40-60 parts by weight of a polymer selected from the group consisting of butadiene rubber, acryl rubber, ethylene-propylene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, isoprene rubber, ethylene-propylene-diene terpolymer, polyorganosiloxane-polyalkyl(meth)acrylate rubber composite and their mixture.
Abstract translation: 目的:提供一种阻燃玻璃纤维增强苯乙烯基热塑性复合材料,其耐冲击性和机械强度得到改善。 构成:苯乙烯类热塑性复合材料包含(A)1-50重量份通过接枝聚合得到的苯乙烯基接枝共聚物(A-1)5-95重量份的包含50-95重量份的单体混合物 的苯乙烯,α-甲基苯乙烯,卤素或烷基取代的苯乙烯或它们的混合物和5-50重量份的丙烯腈,甲基丙烯腈,C1-C8的甲基丙烯酸烷基酯,C1-C8的丙烯酸烷基酯,马来酸酐,C1-C4 烷基或苯基N-取代的马来酰亚胺或其混合物,与(A2)5-95重量份选自丁二烯橡胶,丙烯酸橡胶,乙烯 - 丙烯橡胶,苯乙烯 - 丁二烯橡胶,丙烯腈 - 丁二烯橡胶 ,异戊二烯橡胶,乙烯 - 丙烯 - 二烯三元共聚物,聚有机硅氧烷 - (甲基)丙烯酸烷基酯橡胶复合材料及其混合物; (B)50-95重量份苯乙烯基共聚物或其通过共聚合(B-1)50-95重量份苯乙烯,α-甲基苯乙烯,卤素或烷基取代的苯乙烯或其混合物得到的混合物,和(B -2)5-50重量份的丙烯腈,甲基丙烯腈,C1-C8的甲基丙烯酸烷基酯,C1-C8的丙烯酸烷基酯,马来酸酐,C1-C4烷基或苯基N-取代的马来酰亚胺或它们的混合物; (C)5-50重量份用硅烷系偶联剂处理的玻璃纤维; 和(D)1-20重量份通过接枝聚合(D-1)获得的接枝共聚物40-60重量份的包含10-40重量%苯乙烯,α-甲基苯乙烯,卤素或烷基 - 取代苯乙烯或其混合物,40-80重量%的甲基丙烯腈,C1-C8的甲基丙烯酸烷基酯,C1-C8的丙烯酸烷基酯或它们的混合物,以及1-20重量%的丙烯腈,甲基丙烯腈,马来酸酐,C 1 -C 4烷基或 苯基N-取代马来酰亚胺或其混合物与(D-2)40-60重量份选自丁二烯橡胶,丙烯酸橡胶,乙烯 - 丙烯橡胶,苯乙烯 - 丁二烯橡胶,丙烯腈 - 丁二烯橡胶 ,异戊二烯橡胶,乙烯 - 丙烯 - 二烯三元共聚物,聚有机硅氧烷 - (甲基)丙烯酸烷基酯橡胶复合物及其混合物。
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公开(公告)号:KR101134012B1
公开(公告)日:2012-04-05
申请号:KR1020080135170
申请日:2008-12-29
Applicant: 제일모직주식회사
CPC classification number: C08L69/00 , C08K5/523 , C08L21/00 , C08L67/02 , C08L2666/02
Abstract: 본 발명의 열가소성 수지 조성물은 (A) 고무 변성 방향족 비닐계 공중합체 수지 5~40 중량%; (B) 폴리카보네이트 수지 30~90 중량%; 및 (C) 비결정성 폴리에스테르 수지 1~50 중량%로 이루어지는 기초수지 100중량부에 (D) 방향족 인산에스테르계 화합물 5~30 중량부;로 구성되는 것을 특징으로 한다. 상기 본 발명에 따른 열가소성 수지 조성물은 유동성이 증가되고, 우수한 난연 성능, 내충격성, 내열성, 내화학성을 갖는다.
고무 변성 방향족 비닐계 공중합체 수지, 폴리카보네이트 수지, 폴리에스테르 수지, 방향족 인산에스테르계 화합물, 고유동성, 내화학성-
公开(公告)号:KR1020110112673A
公开(公告)日:2011-10-13
申请号:KR1020100031920
申请日:2010-04-07
Applicant: 제일모직주식회사
Abstract: 본 발명은 (A) 고유동 폴리카보네이트 수지 0.1 내지 50 중량%; (B) 폴리카보네이트 수지 30 내지 90 중량%; (C) 고무변성 스티렌계 공중합체 5 내지 40 중량%; 및 (D) 플루오르계 수지 0.1 내지 5 중량%;로 이루어지는 기초수지 100 중량부에 (E) 방향족 인산에스테르계 화합물 5 내지 30 중량부;를 포함하고, 유동 지수가 60 g/10min(220℃/10kg) 이상인 것을 특징으로 하는 고유동 난연성 열가소성 수지 조성물을 제공한다. 본 발명의 난연성 열가소성 수지 조성물은 내충격성 및 유동성이 모두 우수하다.
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公开(公告)号:KR101066929B1
公开(公告)日:2011-09-22
申请号:KR1020080136111
申请日:2008-12-29
Applicant: 제일모직주식회사
Abstract: 본 발명에 따른 내스크래치성이 우수한 난연성 열가소성 수지 조성물은 (A) 폴리카보네이트 수지 40 내지 90 중량% 및 (B) (메타)아크릴레이트계 수지 10 내지 60 중량%로 이루어지는 기초수지 100 중량부, (C) 난연제 1 내지 50 중량부, (D) 폴리스티렌계 수지 1 내지 30 중량부 및 (E) 페놀 수지 1 내지 20 중량부를 포함한다. 상기 열가소성 수지 조성물은 우수한 난연성과 내스크래치성을 가지며, 충격강도가 뛰어나다.
폴리카보네이트 수지, (메타)아크릴레이트계 수지, 폴리스티렌계 수지, 페놀 수지, 내스크래치성, 난연성-
公开(公告)号:KR1020100077267A
公开(公告)日:2010-07-08
申请号:KR1020080135170
申请日:2008-12-29
Applicant: 제일모직주식회사
CPC classification number: C08L69/00 , C08K5/523 , C08L21/00 , C08L67/02 , C08L2666/02
Abstract: PURPOSE: A flameproof thermoplastic resin composition is provided to be environment-friendly used without containing halogen and to obtain excellent flame retardant property, shock resistance, heat resistance, and chemical resistance by increasing mobility. CONSTITUTION: A flameproof thermoplastic resin composition is comprised of 100.0 parts by weight of a base resin and 5-30 parts by weight of an aromatic phosphate ester compound. The base resin includes 5-40 weight% of a rubber-modified aromatic vinyl copolymer resin, 30-90 weight% of a polycarbonate resin, and 1-50 weight% of an amorphous polymer resin. The rubber-modified aromatic vinyl copolymer resin includes 10-60 weight% of a rubber elastomer, 20-80 weight% of aromatic vinyl monomer, and 5-45 weight% of a monomer which is capable of being copolymerized with the aromatic vinyl monomer.
Abstract translation: 目的:提供一种防火热塑性树脂组合物,在环境友好的情况下使用而不含卤素,并通过增加流动性获得优异的阻燃性,抗冲击性,耐热性和耐化学性。 构成:防火热塑性树脂组合物由100.0重量份基础树脂和5-30重量份芳族磷酸酯化合物组成。 基础树脂包括5-40重量%的橡胶改性的芳族乙烯基共聚物树脂,30-90重量%的聚碳酸酯树脂和1-50重量%的无定形聚合物树脂。 橡胶改性的芳族乙烯基共聚物树脂包括10-60重量%的橡胶弹性体,20-80重量%的芳族乙烯基单体和5-45重量%的能够与芳族乙烯基单体共聚的单体。
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公开(公告)号:KR1020100074965A
公开(公告)日:2010-07-02
申请号:KR1020080133535
申请日:2008-12-24
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame-retarding scratch-resistant thermoplastic resin composition is provided to prevent the degradation of the coloring ability, and to reduce the difference of the refractive index between polycarbonate and an acrylic resin. CONSTITUTION: A flame-retarding scratch-resistant thermoplastic resin composition contains the following: 100 parts of base resin by weight; 0.1~6 parts of fatty acid carboxylic acid amide compound by weight; 1~50 parts of flame retardant by weight; and 1~30 parts of reinforcing agent. The base resin includes 40~80 parts of polycarbonate resin by weight, 1~50 parts of modified (meth)acrylic copolymer resin by weight, and 0.1~50 parts of aromatic vinyl resin by weight. The refractive index of the modified (meth)acrylic copolymer resin is 1.495~1.590.
Abstract translation: 目的:提供阻燃耐刮擦热塑性树脂组合物,以防止着色能力的降低,并减少聚碳酸酯和丙烯酸树脂之间的折射率差异。 构成:阻燃耐刮擦热塑性树脂组合物含有以下物质:100重量份的基础树脂; 按重量计0.1〜6份脂肪酸羧酸酰胺化合物; 1〜50份重量的阻燃剂; 和1〜30份增强剂。 基础树脂包括40〜80重量份的聚碳酸酯树脂,1〜50重量份的改性(甲基)丙烯酸共聚物树脂,和0.1〜50重量份的芳族乙烯基树脂。 改性(甲基)丙烯酸共聚物树脂的折射率为1.495〜1.590。
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公开(公告)号:KR1020100070000A
公开(公告)日:2010-06-25
申请号:KR1020080128585
申请日:2008-12-17
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame-retardant thermoplastic resin composition is provided to improve the flame retardant, the scratch resistance, the impact strength, and the transparency of the composition. CONSTITUTION: A flame-retardant thermoplastic resin composition contains the following: 100 parts of base resin by weigh formed with 50~90wt% of rubber-modified aromatic vinyl group copolymer resin, and 10~50wt% of (meth)acrylate resin; 0.1~20 parts of (meth)acrylate-based polymer bead by weight; 1~30 parts of halogen based compound by weight; and 0.1~15 parts of flame-retardant adjuvant by weight. The rubber-modified aromatic vinyl group copolymer resin is formed with 10~40wt% of aromatic vinyl group graft copolymer resin, and 60~90wt% of aromatic vinyl group copolymer resin.
Abstract translation: 目的:提供阻燃热塑性树脂组合物,以改善组合物的阻燃性,耐擦伤性,冲击强度和透明度。 构成:阻燃性热塑性树脂组合物含有:由50〜90重量%的橡胶改性芳香族乙烯基共聚树脂构成的100重量份的基础树脂和10〜50重量%的(甲基)丙烯酸酯树脂; 0.1〜20份(甲基)丙烯酸酯类聚合物珠粒; 1〜30份重量的卤素类化合物; 和0.1〜15份阻燃助剂。 橡胶改性芳族乙烯基共聚物树脂由10〜40wt%的芳香族乙烯基接枝共聚物树脂和60〜90wt%的芳香族乙烯基共聚物树脂形成。
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公开(公告)号:KR1020100069998A
公开(公告)日:2010-06-25
申请号:KR1020080128582
申请日:2008-12-17
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame-retardant thermoplastic resin composition is provided to improve the fire retardant property without using the high contents of fire retardants, and to improve the heat resistance the impact strength of the composition. CONSTITUTION: A flame-retardant thermoplastic resin composition with the improved scratch resistance contains the following: 100 parts of base resin by weight formed with 50~90wt% of polycarbonate resin, and 10~50wt% of (meth)acrylate-based resin; 1~50 parts of flame retardant by weight; and 0.1~20 parts of cross-linked (meth)acrylate polymer bead by weight. The (meth)acrylate-based resin is a copolymer including 50~100wt% of alkyl (meth)acrylate with the carbon number of 1~4, and 0.5~50wt% of monomer capable of interpolymerizing with the alkyl (meth)acrylate.
Abstract translation: 目的:提供阻燃热塑性树脂组合物以提高阻燃性能,而不使用高含量的阻燃剂,并提高组合物的抗冲击强度。 构成:具有改善的耐刮擦性的阻燃热塑性树脂组合物包含:100重量份由50〜90重量%的聚碳酸酯树脂形成的基础树脂和10〜50重量%的(甲基)丙烯酸酯类树脂; 1〜50份重量的阻燃剂; 和0.1〜20份交联的(甲基)丙烯酸酯聚合物珠粒。 (甲基)丙烯酸酯系树脂是包含50〜100重量%的碳原子数为1〜4的(甲基)丙烯酸烷基酯和能够与(甲基)丙烯酸烷基酯共聚的单体的0.5〜50重量%的共聚物。
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