PROCEDE DE FABRICATION DU 1-CHLORO-2,2,DIFLUOROETHANE
    44.
    发明公开
    PROCEDE DE FABRICATION DU 1-CHLORO-2,2,DIFLUOROETHANE 审中-公开
    工艺生产1-氯-2,2-二氟乙烷

    公开(公告)号:EP3077351A1

    公开(公告)日:2016-10-12

    申请号:EP14821753.2

    申请日:2014-11-28

    Applicant: Arkema France

    Abstract: The present invention relates to the field of saturated fluorohydrocarbons. The subject matter thereof is more particularly the production of 1‑chloro-2,2‑difluoroethane from 1,1,2‑trichloroethane and/or 1,2‑dichloroethylene. The present invention provides a process for producing 1‑chloro-2,2-difluoroethane from 1,1,2-trichloroethane and/or 1,2‑dichloroethylene comprising (i) at least one step during which the 1,1,2‑trichloroethane and/or the 1,2‑dichloroethylene reacts or react with hydrofluoric acid in the gas phase, optionally in the presence of an oxidizing agent, in the presence or in the absence of a fluorination catalyst, to give a stream comprising 1‑chloro-2,2-difluoroethane, hydrochloric acid, hydrofluoric acid and at least one C compound(s) chosen from 1‑chloro-2‑fluoroethylenes (cis and trans), 1,2‑dichloro-2-fluoroethane and, optionally, unreacted 1,1,2‑trichloroethane and/or 1,2‑dichloroethylene.

    COMPOSITION COMPRENANT HF ET E-3,3,3-TRIFLUORO-1-CHLOROPROPENE
    45.
    发明公开
    COMPOSITION COMPRENANT HF ET E-3,3,3-TRIFLUORO-1-CHLOROPROPENE 审中-公开
    用HF和E-3,3,3-三氟-1-氯丙烯组成

    公开(公告)号:EP2976294A1

    公开(公告)日:2016-01-27

    申请号:EP14711821.0

    申请日:2014-02-21

    Applicant: Arkema France

    CPC classification number: C07C21/18 C01B7/191 C09K3/30 C09K5/044

    Abstract: The invention relates to an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene and optionally one or more (hydro)halogen-carbon compounds comprising between 1 and 3 carbon atoms. The invention also relates to a preferred azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene, and optionally one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-tetrafluoropropane.

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