Abstract:
The invention relates to an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, Z-3,3,3-trifluoro-1-chloropropene and one or more (hydro)halocarbon compounds including 1 to 3 carbon atoms. The (hydro)halocarbon compounds are preferably selected among tetrachlorofluoropropanes, trichlorodifluoropropanes, dichlorotrifluoropropanes, chlorotetrafluoropropanes, pentafluoropropanes, dichlorodifluoropropenes, chlorotrifluoropropenes and tetrafluoropropenes.
Abstract:
The present invention relates to the field of saturated fluorohydrocarbons. The subject matter thereof is more particularly the production of 1‑chloro-2,2‑difluoroethane from 1,1,2‑trichloroethane and/or 1,2‑dichloroethylene. The present invention provides a process for producing 1‑chloro-2,2-difluoroethane from 1,1,2-trichloroethane and/or 1,2‑dichloroethylene comprising (i) at least one step during which the 1,1,2‑trichloroethane and/or the 1,2‑dichloroethylene reacts or react with hydrofluoric acid in the gas phase, optionally in the presence of an oxidizing agent, in the presence or in the absence of a fluorination catalyst, to give a stream comprising 1‑chloro-2,2-difluoroethane, hydrochloric acid, hydrofluoric acid and at least one C compound(s) chosen from 1‑chloro-2‑fluoroethylenes (cis and trans), 1,2‑dichloro-2-fluoroethane and, optionally, unreacted 1,1,2‑trichloroethane and/or 1,2‑dichloroethylene.
Abstract:
The invention relates to an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene and optionally one or more (hydro)halogen-carbon compounds comprising between 1 and 3 carbon atoms. The invention also relates to a preferred azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene, and optionally one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-tetrafluoropropane.
Abstract:
Process of catalytic fluorination in liquid phase of product 1, 1, 1, 2, 3-pentachloropropane or/and 1,1,2,2,3- pentachloropropane into product 2-chloro-3, 3, 3-trifluoropropene in présence of a catalyst.
Abstract:
The invention relates to a method of producing 1,1-difluoroethane by liquid-phase fluorination of 1,2-dichloroethane using hydrofluoric acid, in the presence of a Lewis acid catalyst and a FeCl3 co-catalyst. The invention also relates to a method of producing 1,1-difluoroethylene, employing the aforementioned method.
Abstract:
The invention relates to a method for producing a fluorinated compound, comprising: the provision of a gaseous flow comprising hydrofluoric acid; the provision of at least one liquid flow of a chlorinated compound and the vapourisation thereof by mixing with said gaseous flow, the resulting mixture being a gaseous mixture; and the catalytic reaction of the chlorinated compound with hydrofluoric acid in a gaseous phase and the collection of a product flow. The invention also relates to a facility for carrying out said method.
Abstract:
The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene, comprising the following steps: (a) catalytic reaction of 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane with HF into product 2-chloro-3,3,3-trifluoropropene; (b) catalytic reaction of the thus-obtained 2-chloro-3,3,3-trifluoropropene into 2,3,3,3-tetrafluoropropene.
Abstract:
The invention relates to a reinforced fluoropolymer plate comprising a fluoropolymer layer on one of the faces thereof and a carbon fibre sheet on the other face of same, whereby at least part of the carbon fibre sheet is impregnated with flouropolymer. The invention also relates to an acid-corrosion-resistant chemical reactor comprising said plates, the production methods thereof and the uses of same in processes in superacid media.