Benzhydrylamine cpds prepn - by treating di-benzylammonium salts with non-nitrogenous bases

    公开(公告)号:DE2456738A1

    公开(公告)日:1976-08-12

    申请号:DE2456738

    申请日:1974-11-30

    Applicant: BASF AG

    Abstract: Benzhydrylamine cpds. of formula (I): (where R1 and R2 are aliphatic or aromatic residues or NR1R2 is a heterocyclic ring; and each X (same or different) NR1R2 is a heterocyclic ring; and each X (same or different is H or halogen), e.g. N,N-dimethyl-2', 3-dichloro-2-methylbenzhydrylamine (which is claimed as a new cpd.) are prepd. by reacting dibenzylammonium salts of formula (II): (where Y is the anion of a mineral acid) with a nitrogen-free free basic alkali (ne earth) cpd. in the presence of water and/or organic solvent. (I) are inters for dyes, adjuvants and pesticides. Thus, treatment with strong oxidising agents gives halo-substd. aroylbenzoic can be obtained. Simple and economical process giving (I) in good yields and purity from readily available starting materials.

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