公开(公告)号：DE944251C

公开(公告)日：1956-06-14

申请号：DEB0021045

申请日：1952-07-04

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  PASEDACH DR HEINRICH ,  SEEFELDER DR MATTHIAS

IPC: C07D213/08 ,  C07D213/09 ,  C07D213/14

公开(公告)号：DE942990C

公开(公告)日：1956-05-09

申请号：DEB0020040

申请日：1952-04-19

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  FRIEDERICH DR HERBERT ,  WAIBEL DR HELMUT

IPC: C07D213/06 ,  C07D213/133

公开(公告)号：DE915568C

公开(公告)日：1954-07-26

申请号：DEB0007567

申请日：1941-11-08

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  KROEPER DR HUGO

公开(公告)号：DE909339C

公开(公告)日：1954-04-15

申请号：DEB0007126

申请日：1943-09-22

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  PASEDACH DR HEINRICH

IPC: C07C49/17

公开(公告)号：DE805642C

公开(公告)日：1951-05-25

申请号：DEP0011825

申请日：1948-10-02

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  SCHWECKENDIEK DR WALTER ,  MAGIN AUGUST ,  KLAGER DR KARL

IPC: C07C2/42 ,  C07C2/48

公开(公告)号：DE1232974B

公开(公告)日：1967-01-26

申请号：DEB0080829

申请日：1965-03-05

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  MAGIN AUGUST

IPC: C07C37/11

公开(公告)号：DE1173458B

公开(公告)日：1964-07-09

申请号：DEB0062191

申请日：1961-04-19

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  MAGIN AUGUST

IPC: C07C69/34 ,  C07C69/52

Abstract: The invention consists of a process for producing a mixture of esters of aliphatic unsaturated dicarboxylic acids, wherein the acid contains 6 to 12 carbon atoms and the alcohol is a C1-C18 alkanol, a C5-C12 cycloalkanol, or a C7 to C10 arylalkanol, by passing acetylene or methylacetylene into the anhydrous alcohol, at 30 to 120 DEG C., or at most containing 5% water, and simultaneously introducing nickel tetracarbonyl and less than the equivalent amount of nickel of an organic or inorganic non-oxidising acid, and discontinuing the supply of acetylene or methyl acetylene before the alkanol is completely used up. Up to 80% of the nickel tetracarbonyl may be replaced by free carbon monoxide. There may also be added to the reaction mixture ligand field complex formers, a large number of which is specified, a halide, or ligand field complex of copper, iron, cobalt, zinc, cadmium, mercury, tin or bismuth and one or more polymerisation inhibitors. The product may be hydrogenated and/or worked up for free acids. The examples relate to the use of ethanol, isopropanol, isobutanol, cyclohexanol.

公开(公告)号：DE1100634B

公开(公告)日：1961-03-02

申请号：DEB0024895

申请日：1953-03-24

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  PASEDACH DR HEINRICH ,  DREHER DR ERICH ,  AMAN DR MED AUGUST

IPC: C07D295/096

公开(公告)号：DE1076672B

公开(公告)日：1960-03-03

申请号：DEB0039244

申请日：1956-02-24

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  REICHENEDER DR FRANZ ,  STENGEL DR GUENTHER ,  ZIEGER DR ALBERT

公开(公告)号：DE1032217B

公开(公告)日：1958-06-19

申请号：DEB0042501

申请日：1956-11-16

Applicant: BASF AG

Inventor： REPPE DR WALTER ,  BAUR DR KARL ,  SCHWETER DR WALTER

IPC: B01D1/00 ,  B01D3/38 ,  B01J19/00 ,  C07C7/05 ,  C07C13/267