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    41.
    发明专利
    未知

    公开(公告)号：DE1768428A1

    公开(公告)日：1971-08-05

    申请号：DE1768428

    申请日：1968-05-14

    Applicant: GEN ELECTRIC

    Inventor： BERGER ABE

    IPC: C07F7/08

    Abstract: 1,239,954. Organosilicon hydrides. GENERAL ELECTRIC CO. 31 May, 1968 [1 June, 1967], No. 26258/68. Addition to 1,099,072. Heading C3S. Organosilicon hydrides are prepared by reacting an alkali metal hydride with an organohalosilane of the formula R a SiH b X 4-a-b or a bis-(halosilyl) hydrocarbon ofthe formula X 3-c-d H c R d SiR 1 SiR e H f -X 3-e-f in the presence of an alkyl aluminium halide. In the formulµ, R is a monovalent hydrocarbon or halohydrocarbon radical other than the radicals having at least 3 carbon atoms specified in the parent Specification, R 1 is a divalent hydrocarbon radical, X is halogen, a is. 1 to 3, b, c, d, e and f are each 0 to 2, a+b is 1 to 3, c+d is 0 to 2 and e+f is 0 to 2. Specified R radicals are Me, Et, vinyl, propenyl and allyl. The examples describe the preparation of 1,8-bis-(silyl) octane, 1,2-bis-(silyl) ethane, methyl silane, 1,4-bis- (dimethylsilyl) benzene and 1,4-bis-(silyl) butane.

    47.
    发明专利
    未知

    公开(公告)号：DE1935884A1

    公开(公告)日：1970-01-22

    申请号：DE1935884

    申请日：1969-07-15

    Applicant: GEN ELECTRIC

    Inventor： BERGER ABE ,  G SELIN TERRY

    IPC: C07F7/08 ,  C07F7/10 ,  C07F7/18 ,  C08G77/26 ,  C08L83/04 ,  C08L83/08 ,  C09G1/16 ,  C09J183/04 ,  D06M15/356

    Abstract: 1282472 Cyanoalkoxy- and aminoalkoxyalkenyl silanes; siloxane compositions. GENERAL ELECTRIC CO 16 July 1969 [17 July 1968] 35866/69 Headings C3S and C3T [Also in Divisions C2 C4 and D1] The invention comprises cyanoalkoxyalkenyl and aminoalkoxyalkenyl silanes of the formulae wherein one of A and A 1 is hydrogen and the other is R 3-a X a Si-, a is 0, 1, 2 or 3, X denotes C 1-8 alkoxy, mononuclear aryloxy, di-(C 1-8 alkyl)-amino or di-(C 1-8 alkyl)-aminoxy, R denotes C 1-8 alkyl, C 5-7 cycloalkyl, mononuclear or binuclear aryl or aryl substituted C 1-8 alkyl, R 1 denotes hydrogen, C 1-8 alkyl, C 5-7 cycloalkyl, mononuclear or binuclear aryl, mononuclear aryl substituted C 1-8 alkyl, or two such R 1 radicals attached to a single carbon atom form with it a C 5-7 cycloalkyl radical, b is 1, 2, 3 or 4, one of A 11 and A 111 is hydrogen and the other is R 11 3-a X 1 a Si-, X 1 denotes X or halogen, C 1-8 acyloxy, oximino, isonitrile isocyanato, isothiocyanato, C 1-8 mercaptoalkyl, or di- C 1-8 alkyl) phospheno, R 11 denotes R or a halogenated derivative of R and R 111 denotes R 1 or a halogenated derivative of R 1 . Aminoalkoxyalkenyl silanes of the above general formula are obtained from corresponding cyanoalkoxyalkenyl silanes of the second general formula by hydrogenation at 20 to 4000 p.s.i. and 30‹ to 150‹ C. in presence of a nickel or cobalt catalyst. Cyanoalkoxyalkenyl silanes of the above general formula are obtained by reacting an appropriate acetylenic nitrile, e.g. a compound having the formula with a silane of the formula R 11 3-a X 1 a SiH. The hydrolysable group X 1 in the products may be subsequently converted to other hydrolysable X 1 groups. Thus, halogen atoms may be converted to alkoxy groups by reaction with alkyl orthoformates. In examples the preparation is described of 3- methyl - 3 - (2 - cyanoethoxy) - 1- trimethoxysilylbutene-1, 3 - methyl - 3 - (3- aminopropoxy) - 1 - trimethoxysilylbutene - 1, 3 - (2 - cyanoethoxy) - 1- and 2 - trichlorosilylpropene - 1, 3 - (2 - cyanoethoxy) - 1 - trimethoxysilylpropene - 1, 3 - (2 - cyanoethoxy) - 2- trimethoxysilylpropene - 1, 3 - (3 - aminopropoxy) - 1 - trimethoxysilylpropene - 1, 3 - (2- cyanoethoxy) - 1 - trichlorosilylhexene - 1, 3 - (2- cyanoethoxy) - 1 - trimethoxysilylhexene - 1 and 3 - (2 - cyanoethoxy) - 2 - trimethoxysilylhexene -1. In further examples, (3) an adhesive composition is prepared from 3-methyl-3-(3-aminopropoxy)- 1 - trimethoxysilylbutene - 1, an isoparaffin boiling at 150‹ to 180‹ C., and a silanol chainstopped fluid of the formula and is used to bond glass to glass, metal to metal, metal to glass and paper to metal; (4) a composition as in (3) is put up as an aerosol with the further addition of dichlorodifluoromethane, and is sprayed on to cotton fabric to impart water repellency thereto; and (5) a copolymer is prepared from 3-methyl-3-(3-aminopropoxy)- 1 - trimethylsilylbutene - 1, gamma - aminopropyltrimethoxysilane, a chain-stopped polydimethylsiloxane of the formula and water; this is then converted to the partial acetic acid salt and the latter is incorporated into a polish emulsion also containing a methyl silicone oil, sorbitan monooleate emulsifier, mineral spirits, kerosene, water and aluminium silicate to give a detergent-resistant cleaner/ polish suitable for car bodywork. Uses.-As ingredients in detergent-resistant, slip-resistant and non-wicking silicone furniture polishes, for imparting water-repellency to cloth, and for room temperature vulcanizable silicone compositions.

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