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    48.
    发明专利
    未知

    公开(公告)号：DE1105176B

    公开(公告)日：1961-04-20

    申请号：DEF0025730

    申请日：1958-05-10

    Applicant: HOECHST AG

    Inventor： ORTHNER DR LUDWIG ,  LANDAUER DR FRANZ ,  REUTER DR MARTIN ,  HERZBERG DR HORST

    IPC: C08F6/12 ,  C08F8/20 ,  C08F8/34

    Abstract: Chlorinated or sulphochlorinated solid homopolymers or copolymers of aliphatic olefines are isolated from their solutions by introducing the solution into hot water at 40 DEG -100 DEG C. in the presence of a water-insoluble solid inorganic compound of a metal or semi-metal of Group II-V of the Periodic Table, which compound has a large surface area, is at most faintly coloured and is preferably capable of swelling in water, and in the presence of an organic surface-active compound containing no saltforming carboxyl groups, while continuously distilling off the solvent and discharging the precipitated chlorinated or sulphochlorinated polyolefine immediately after its precipitation from the zone of precipitation. The polymers may be polyethylene, polypropylene, polybutylene or polypentene or copolymers of ethylene, propylene, butylene or pentene, e.g. ethylenepropylene, ethylene-butene or ethylene-propylene-butene copolymers, and may be made by the high or low pressure polymerization process. The inorganic compound may be an oxide, hydroxide, carbonate, sulphate or silicate, for example, magnesium carbonate, aluminium hydroxide, aluminium oxide, aluminium silicate or hydrosilicate, bentonite, barium sulphate, silicon dioxide, silica gel, lead oxide, attapulgite, antimony oxide or titanium dioxide. The organic surface-active agent may be dibutyl-naphthalene or dodecyl-benzene sulphonic acids, dodecyl-benzyl-dimethyl-ammonium chloride, an alkyl sulphonate, octadecenyl-trimethyl ammonium chloride, didodecyl-dimethyl ammonium chloride, anoleyl-or dodecyl-aminoacetate, oleyl-b -hydroxyethane sulphonic acid, oleyl-methyltaurine, or hydroxyethylated alkyl phenols, e.g. diisobutyl phenol, octyl phenol, nonyl phenol, triisobutyl-b -naphthol, or other hydroxyethylated compounds such as hydroxyethylated naphthol sorbitol monolaurate, oleyl alcohol, oleic acid, octyl alcohol, castor oil, wax alcohols, sorbitol monostearate, or the hydroxyethylated compound obtained from the amide of hydrogenated tallow fatty acid. The original solution may be in halogenated aliphatic hydrocarbons such as methylene chloride, chloroform, 1,2-dichlorethane or carbon tetrachloride. Agitation, such as stirring, is used to remove the precipitated polymer from the zone of precipitation. The chlorinated or sulphochlorinated polymers may afterwards be vulcanized at raised temperatures and pressures in the presence of stearic acid, litharge and mercaptobenzthiazole. Specifications 418,069, 542,414 and 811,848 are referred to.

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