PRODUCTION OF ORGANOPOLYSILOXANE HAVING SACCHARIDE RESIDUE

    公开(公告)号:JPS6268820A

    公开(公告)日:1987-03-28

    申请号:JP20732685

    申请日:1985-09-19

    Applicant: KAO CORP

    Abstract: PURPOSE:To obtain the titled excellent compound without limiting the service temperature, by reacting a primary amino group-containing organopolysiloxane with a lactonic compound in which aldonic acid or uronic acid is cyclodehydrated in the molecule thereof. CONSTITUTION:(A) An organopolysiloxane containing at least one primary amino group in one molecule is reacted with (B) a lactonic compound in which aldonic acid or uronic acid is cyclodehydrated in the molecule thereof at the above-mentioned amino group to afford the aimed compound containing at least one saccharide residue in one molecule.

    PRODUCTION OF N-MERCAPTOALKYL SUGAR AMIDE

    公开(公告)号:JPS6263598A

    公开(公告)日:1987-03-20

    申请号:JP20289985

    申请日:1985-09-13

    Applicant: KAO CORP

    Abstract: PURPOSE:To readily obtain the titled water-soluble and odorless compound useful as a reducing agent for the first permanent waving solution, etc., by reacting a sugar lactone compound with an aminoalkanethiol. CONSTITUTION:(A) A sugar lactone compound, preferably obtained by intramolecularly dehydrocyclizing aldonic acid or uronic acid derived from reducing monosaccharides or reducing disaccharides is reacted with (B) an aminoalkanethiol, preferably expressed by the formula H2N-R-SH (R is 1-18C alkylene or substituted alkylene) to afford the aimed compound.

    N-MERCAPTOALKYLGLUCONAMIDE
    43.
    发明专利

    公开(公告)号:JPS61260058A

    公开(公告)日:1986-11-18

    申请号:JP10115485

    申请日:1985-05-13

    Applicant: KAO CORP

    Abstract: NEW MATERIAL:A compound expressed by formula I (n is an integer 1-3). EXAMPLE:N-(2-Mercaptoethyl)gluconamide. USE:A water-soluble and odorless reducing agent for the first agent in cold permanent wave and polymerization degree regulator in radical polymerization. PREPARATION:A glucone-delta-lactone expressed by formula II is mixed or suspended in an aminoalkanethiol expressed by formula III in a solvent, e.g. methanol, and heated while refluxing and stirring. Alternatively, the aminoalkanethiol is first dissolved in the solvent, and the glucono-delta-lactone is then added to the reaction system is portions to afford the aimed compound expressed by formula I.

    AEROSOL DEVICE
    44.
    发明专利

    公开(公告)号:JPH09290879A

    公开(公告)日:1997-11-11

    申请号:JP10716096

    申请日:1996-04-26

    Abstract: PROBLEM TO BE SOLVED: To provide an aerosol device which is convenient to use wherein the spraying direction of content can be kept constant. SOLUTION: An aerosol device comprising an aerosol container 4 with a valve 3 mounted and a push button 9 having a stem fitting part 12 to be fitted into a stem 7 of the valve 3 includes a guide 18 being a guide means for vertically guiding the stem fitting part 12 formed inside the push button 9.

    AEROSOL DEVICE
    45.
    发明专利

    公开(公告)号:JPH09290878A

    公开(公告)日:1997-11-11

    申请号:JP10715996

    申请日:1996-04-26

    Abstract: PROBLEM TO BE SOLVED: To provide an aerosol device which is convenient to use wherein the spraying direction of contents can be kept constant. SOLUTION: An aerosol device comprises an aerosol container 4 with a valve 3 mounted and a push button 9 to be fitted into a steam of the valve 3, wherein the push button 9 inserted into a cover 6 being a support member S1 fitted to the top of the aerosol container 4 is prevented from coming off by a flange 22 and a locking part 19 which are locking means.

    HAIR COSMETIC
    46.
    发明专利

    公开(公告)号:JPH0859441A

    公开(公告)日:1996-03-05

    申请号:JP21427894

    申请日:1994-08-15

    Applicant: KAO CORP

    Abstract: PURPOSE: To obtain a hair cosmetic containing an amphiphilic siloxane derivative having a specific hydrophobia group and hydrophilic group and a skin film-forming resin, having excellent set retaining force and good feeling after setting and not damaging hair. CONSTITUTION: This hair cosmetic is obtained by including 0.01-10wt.% of a siloxane derivative of formula I [at lease one of R to R is formula II (Q is a 3-20C divalent hydrocarbon; R and R are each H or 1-5C hydrocarbon, with the proviso that at least one of R and R is H) and the remainder is a 1-30C hydrocarbon or the formula XR (X is a divalent hydrocarbon; R is a 1-30C hydrocarbon); (1), (m) and (n) are each 0-2000; etc.] and 0.01-20wt.% (as a solid content) of a film-forming resin (e.g. an amphoteric polymer, an anionic polymer or a cationic polymer) and dissolving or dispersing these components into a solvent comprising water, a lower alcohol or a mixed solvent of water with the lower alcohol according to ordinary method. The hair cosmetic can improve combing and brushing properties and prevent loosening of hair due to drying of hair and provide gloss and smooth touch feeling to hair after using.

    HAIR COSMETIC
    47.
    发明专利

    公开(公告)号:JPH0859440A

    公开(公告)日:1996-03-05

    申请号:JP21427794

    申请日:1994-08-15

    Applicant: KAO CORP

    Abstract: PURPOSE: To obtain a hair cosmetic capable of finishing so as to firmly fix hair style and providing gloss to hair and providing moist feeling and smooth touch feeling to hair, capable of preventing hair from drying also after passage of time and not drying hair. CONSTITUTION: This hair cosmetic contains (A) a siloxane derivative of formula I [at least one among R to R is formula II (Q is a 3 2C divalent hydrocarbon group; R and R are each 11 or a 1-5C hydrocarbon group, with the proviso that either one thereof is H) and the reinainder is a l-30C straight-chain, a branched chain or a cyclic hydrocarbon group and X-R X is a divalent hydrocarbon group containing an ether bond and/or an ester bond; R is a 1-30C straight-chain, branched chain or cyclic hydrocarbon group); (l), (m) and (n) are each 0-2000; when one of R to R is formula II and the remainder is methyl and when Q in formula II is trimethylene, R and R are each simultaneously H], e.g. a compound of formula III or formula IV and (B) a siloxane derivative other than the component A, e.g.,dimethylpolysiloxane or polyether modified silicone.

    HAIR COSMETIC
    49.
    发明专利

    公开(公告)号:JPH0769842A

    公开(公告)日:1995-03-14

    申请号:JP21639193

    申请日:1993-08-31

    Applicant: KAO CORP

    Inventor: MITA KATSUMI

    Abstract: PURPOSE:To prepare a hair cosmetic preventing excessive evaporation of water when blowing hot air on hair with a dryer, suppressing damage with a brush, providing hair with luster and a moist feeling, having dry touch, capable of retaining a set style. CONSTITUTION:This hair cosmetic comprises (A) a betaine, preferably glycine betaine and (B) a film-forming resin in the ratio of 0.01-10wt.%, preferably 0.5-3wt.% of the component A and 0.01-20wt.%, preferably 0.5-5wt.% of the component B. The component B is not particularly limited so long as the component B is stuck to hair to form a coating film. An amphoteric polymer, an anionic polymer, a cationic polymer, a nonionic polymer and a water-soluble synthetic polymer can be used as the component B. An hydroxypropyl acrylate/ butylaminoethyl methacrylate/acrylic acid octyl amide copolymer, methyl vinyl ether/maleic anhydride alkyl half ester copolymer, etc., may be cited as the component B.

    HAIR COSMETIC
    50.
    发明专利

    公开(公告)号:JPH0597636A

    公开(公告)日:1993-04-20

    申请号:JP25919791

    申请日:1991-10-07

    Applicant: KAO CORP

    Abstract: PURPOSE:To obtain a hair cosmetic, having an average particle diameter of mist as small as 2-70mum and good setting properties and excellent in touch of use. CONSTITUTION:A hair cosmetic containing a film-forming acrylic polymer, having 10,000-50,000 average molecular weight and selected from the group of (a) (meth)acrylic acid-(meth)acrylic acid ester copolymers, (b) reactional products of dialkylaminoethyl (meth)acrylate-alkyl (meth) acrylate copolymers with monochloroacetic acid and (c) four-component copolymers of (meth) acrylamide-based monomer-alkyl (meth)acrylate-based monomer-(meth) acrylamide-based and/or (meth)acrylic acid ester-based monomer having tertiary amino group-hydroxy group or methoxy group-substituted alkyl (meth)acrylate- based monomer. This hair cosmetic uses a spray container without employing a propellant.

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