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41.发明专利
公开(公告)号：MX9503583A
公开(公告)日：1997-05-31
申请号：MX9503583
申请日：1995-08-21
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: La energía requerida para lograr una conversion dada en la desintegracion térmica o pirolisis de hidrocarburos, es reducida mediante el contacto o tratamiento de los tubos de horno de desintegracion térmica o pirolisis, con una composicion que comprende estaño y silicio.
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42.发明专利
公开(公告)号：SG34254A1
公开(公告)日：1996-12-06
申请号：SG1995001161
申请日：1995-08-18
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , MURTHA TIMOTHY P , HARPER TIMOTHY P , DEGRAFFENRIED JAMES P , SCHARRE MARK D , GREENWOOD GIL J
Abstract: For a given percentage decomposition, the decomposition temperature of an organosilicon compound is reduced by admixing with the organosilicon compound a decomposition promoting organotin compound. The amount of decomposition promoting organotin compound admixed with the organosilicon compound is sufficient to effectively lower the decomposition temperature of the organosilicon required for a given percentage decomposition.
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公开(公告)号：SG32454A1
公开(公告)日：1996-08-13
申请号：SG1995001133
申请日：1995-08-17
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
IPC: C10G75/04
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公开(公告)号：CA2155984A1
公开(公告)日：1996-02-26
申请号：CA2155984
申请日：1995-08-14
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: The incremental yield of hydrocarbons having five or more carbon atoms in a cracked product from a thermal cracking process is increased by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.
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45.发明专利
公开(公告)号：CA2155044A1
公开(公告)日：1996-02-26
申请号：CA2155044
申请日：1995-07-31
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: Spalling of coke produced during the thermal cracking of hydrocarbon is promoted by contacting or treating the tubes of a thermal cracking furnace with a composition having an absence of silicon and comprising tin.
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Patent Agency Ranking
公开(公告)号：CA2102061A1
公开(公告)日：1994-07-14
申请号：CA2102061
申请日：1993-10-29
Applicant: PHILLIPS PETROLEUM CO
Inventor： BROWN RONALD E , SASAKI KAZUHIKO J , REED LARRY E
Abstract: A liquid tin-containing antifoulant composition is injected into a metal-walled thermal cracking reactor tube, concurrently with the injection of a gaseous stream (preferably a steam-diluted C₂-C₄ alkane stream), through a nozzle of an injection quill which is positioned in the center region of the reactor tube substantially parallel to the flow of the gaseous stream.A liquid tin-containing antifoulant is injected into a metal-walled thermal cracking reactor tube through a nozzle of an injection quill at a temperature of about 1000-1300°F while a gaseous stream (preferably a steam-diluted C₂-C₄ alkane stream) flows through the reactor tube, followed by raising the temperature to about 1400-1800°F. Preferably, the metal walls of the reactor tube are treated with steam after the antifoulant injection at about 1000-1300°F but before the antifoulant injection at about 1400-1800°F.
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公开(公告)号：CA1228566A
公开(公告)日：1987-10-27
申请号：CA477727
申请日：1985-03-28
Applicant: PHILLIPS PETROLEUM CO
Inventor： PORTER RANDALL A , REED LARRY E
Abstract: The formation of carbon on metals exposed to hydrocarbon in a thermal cracking process is reduced by contacting such metals with an antifoulant selected from the group consisting of a combination of tin and phosphorus, a combination of phosphorus and antimony and a combination of tin, antimony and phosphorus.
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公开(公告)号：AT218608T
公开(公告)日：2002-06-15
申请号：AT96104603
申请日：1996-03-22
Applicant: PHILLIPS PETROLEUM CO
Inventor： BROWN RONALD E , HARPER TIMOTHY P , REED LARRY E , SCHARRE MARK D , GREENWOOD GIL J
Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.
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公开(公告)号：DE69523105D1
公开(公告)日：2001-11-15
申请号：DE69523105
申请日：1995-08-24
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: For a given percentage decomposition, the decomposition temperature of an organosilicon compound is reduced by admixing with the organosilicon compound a decomposition promoting organotin compound. The amount of decomposition promoting organotin compound admixed with the organosilicon compound is sufficient to effectively lower the decomposition temperature of the organosilicon required for a given percentage decomposition.
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公开(公告)号：DE69512729D1
公开(公告)日：1999-11-18
申请号：DE69512729
申请日：1995-08-24
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: A novel method for treating the radiant tubes of a fired pyrolysis heater with an antifoulant composition for inhibiting the formation and deposition of coke thereon. Such novel method includes introducing the antifoulant into the crossover conduit between the convection tubes and radiant tubes of the fired pyrolysis heater.
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