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公开(公告)号:HU202060B
公开(公告)日:1991-02-28
申请号:HU316287
申请日:1987-07-10
Applicant: RHONE POULENC CHIMIE
Inventor: GIRARDEAU YVETTE , RUFFO GEORGES , SEGAUD CHRISTIAN
IPC: A01N25/30 , C07F9/09 , C07F9/12 , B01J13/00 , C09K23/00 , C09K23/14 , C09K23/42 , A01N57/02 , B01F17/14
Abstract: 1. A process for the preparation of surface active compositions by phosphatation by phosphoric anhydride of at least one polyoxyalkylenated derivative R1 -OR-OH (formula (V)), in which formula : O-R represents a succession of identical or different C2 -C4 oxyalkylenated units, in which the number of units can range from 1 to 80, R1 is a C8 -C20 straight or branched chain alkyl or alkenyl radical or an aryl radical of formula (III) see diagramm : EP0252824,P16,F1 in which : m is an integer of 1, 2 or 3 p is an integer of 1 or 2 R3 is a hydrogen atom or a C1 -C4 alkyl radical, and R2 is a C4 -C12 alkyl radical or a radical of the following formula : see diagramm : EP0252824,P16,F2 wherein : R4 represents a hydrogen atom or a C1 -C4 alkyl or phenyl radical ; and optionally neutralisation of the acid functions, the process being characterised in that the phosphatation operation is carried out in two steps : a phosphatation step in the true sense which is effected by continuously introducing phosphoric anhydride into a medium which is subjected to turbulent agitation conditions, the medium being formed by said polyoxyalkylenated derivative containing water in a sufficient amount to initiate the phosphatation reaction, at a temperature of the order of 35 to 40 degrees C at the beginning of the reaction, said temperature being maintained at a temperature lower than or equal to 45 degrees C until the end of the operation of introducing the phosphoric anhydride, the total amount of phosphoric anhydride used corresponding to a polyoxyalkylenated derivative/P2 O5 molar ratio equal to 3 +- 0.3, followed by a step for maturing of the reaction medium obtained, said step being carried out under turbulent agitation conditions at a temperature of between 40 and 60 degrees C.
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公开(公告)号:ES2013639B3
公开(公告)日:1990-05-16
申请号:ES87401564
申请日:1987-07-03
Applicant: RHONE-POULENC CHIMIE
Inventor: GIRARDEAU YVETTE , RUFFO GEORGES , SEGAUD CHRISTIAN
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公开(公告)号:BR8905084A
公开(公告)日:1990-05-15
申请号:BR8905084
申请日:1989-10-06
Applicant: RHONE POULENC CHIMIE
Inventor: SEGAUD CHRISTIAN
IPC: B01J13/00 , C01F17/00 , C09K23/00 , C10M173/02 , C10M169/04 , C10M103/06 , C10M145/12
Abstract: Novel aqueous lubricant dispersions contain at least one rare earth halide, e.g., cerium trifluoride, and at least one polymeric dispersing agent therefor, such at least one dispersing agent including: (a) a copolymer of an ethylenically unsaturated carboxylic acid or derivative thereof with an alpha -olefin comonomer and/or a vinyl comonomer; (b) a homopolymer or copolymer of an ethylenically unsaturated carboxylic acid or derivative thereof; (c) a copolymer of at least one ethylenically unsaturated carboxylic acid and at least one ethylenically unsaturated sulfonic acid comonomer; and/or (d) a polymer of an alkylene oxide of an (arylalkyl)phenol, or phosphated or sulfated derivative thereof.
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公开(公告)号:NO894162D0
公开(公告)日:1989-10-19
申请号:NO894162
申请日:1989-10-19
Applicant: RHONE POULENC CHIMIE
Inventor: SEGAUD CHRISTIAN
IPC: B01J13/00 , C01F17/00 , C10M141/02 , C10M141/08 , C10M141/10 , C10M161/00 , C10N10/06 , C10N30/06 , C10M163/00
Abstract: Novel lubricant compositions contain at least one rare earth halide, e.g., cerium trifluoride, and at least one surfactant including a hydrophobic moiety and a hydrophilic moiety, such hydrophilic moiety comprising ethylene oxide and/or propylene oxide units and, optionally, hydrophilic functional groups, dispersed in an oily medium compatible therewith.
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公开(公告)号:CA1334274C
公开(公告)日:1995-02-07
申请号:CA598577
申请日:1989-05-03
Applicant: RHONE POULENC CHIMIE
Inventor: GIRARDEAU YVETTE , RUFFO GEORGES , SEGAUD CHRISTIAN
IPC: A61K8/72 , A01N25/30 , A61K8/04 , A61K8/06 , A61K8/39 , A61K47/24 , B01J13/00 , C07F9/09 , C08G65/26 , C08G65/32 , C08G65/327 , C09K23/00 , C09K23/14 , C09K23/42 , B01F17/42
Abstract: L'invention concerne des compositions tensioactives constituées d'esters phosphoriques de di et/ou tri(phényl-1 éthyl) phénols portant des motifs polyoxyéthylénés et polyoxypropylénés statistiquement répartis et terminés par un motif oxyéthyléné. Elles sont obtenues par phosphatation desdits di et/ou tri(phényl-1 éthyl) phénols polyoxyalcoylénés. Elles peuvent être utilisées pour la formulation de matières actives insolubles dans l'eau, notamment phytosanitaires, sous forme de dispersions aqueuses fluides, granulés ou poudres mouillables.
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公开(公告)号:DE68902215D1
公开(公告)日:1992-08-27
申请号:DE68902215
申请日:1989-10-16
Applicant: RHONE POULENC CHIMIE
Inventor: SEGAUD CHRISTIAN
IPC: B01J13/00 , C01F17/00 , C10M141/02 , C10M141/08 , C10M141/10 , C10M161/00 , C10N10/06 , C10N30/06
Abstract: Novel lubricant compositions contain at least one rare earth halide, e.g., cerium trifluoride, and at least one surfactant including a hydrophobic moiety and a hydrophilic moiety, such hydrophilic moiety comprising ethylene oxide and/or propylene oxide units and, optionally, hydrophilic functional groups, dispersed in an oily medium compatible therewith.
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公开(公告)号:ZA8907657B
公开(公告)日:1990-07-25
申请号:ZA8907657
申请日:1989-10-09
Applicant: RHONE POULENC CHIMIE
Inventor: SEGAUD CHRISTIAN , CHRISTIAN SEGAUD
CPC classification number: B01F17/0057 , B01F17/0028 , B01F17/005 , B01F17/0064 , B01F17/0085 , C10M103/00 , C10M129/08 , C10M145/10 , C10M145/26 , C10M145/36 , C10M149/06 , C10M149/08 , C10M151/02 , C10M151/04 , C10M153/04 , C10M155/02 , C10M173/02 , C10M2201/00 , C10M2201/003 , C10M2201/02 , C10M2201/0403 , C10M2201/0433 , C10M2201/061 , C10M2201/16 , C10M2201/18 , C10M2207/022 , C10M2207/023 , C10M2209/08 , C10M2209/082 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/106 , C10M2209/108 , C10M2215/102 , C10M2217/024 , C10M2217/026 , C10M2217/06 , C10M2221/00 , C10M2221/02 , C10M2221/04 , C10M2221/041 , C10M2221/043 , C10M2225/00 , C10M2225/02 , C10M2225/04 , C10M2225/041 , C10M2229/02 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10M2229/051 , C10M2229/052 , C10M2229/053 , C10M2229/054 , C10N2250/02
Abstract: Novel aqueous lubricant dispersions contain at least one rare earth halide, e.g., cerium trifluoride, and at least one polymeric dispersing agent therefor, such at least one dispersing agent including: (a) a copolymer of an ethylenically unsaturated carboxylic acid or derivative thereof with an alpha -olefin comonomer and/or a vinyl comonomer; (b) a homopolymer or copolymer of an ethylenically unsaturated carboxylic acid or derivative thereof; (c) a copolymer of at least one ethylenically unsaturated carboxylic acid and at least one ethylenically unsaturated sulfonic acid comonomer; and/or (d) a polymer of an alkylene oxide of an (arylalkyl)phenol, or phosphated or sulfated derivative thereof.
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公开(公告)号:FR2610171B1
公开(公告)日:1990-06-22
申请号:FR8701126
申请日:1987-01-30
Applicant: RHONE POULENC CHIMIE
Inventor: GIRARDEAU YVETTE , SCHUPPISER JEAN-LUC , SEGAUD CHRISTIAN
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公开(公告)号:FR2638168A1
公开(公告)日:1990-04-27
申请号:FR8813796
申请日:1988-10-21
Applicant: RHONE POULENC CHIMIE
Inventor: SEGAUD CHRISTIAN
IPC: B01J13/00 , C01F17/00 , C10M141/02 , C10M141/08 , C10M141/10 , C10M161/00 , C10N10/06 , C10N30/06
Abstract: Novel lubricant compositions contain at least one rare earth halide, e.g., cerium trifluoride, and at least one surfactant including a hydrophobic moiety and a hydrophilic moiety, such hydrophilic moiety comprising ethylene oxide and/or propylene oxide units and, optionally, hydrophilic functional groups, dispersed in an oily medium compatible therewith.
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公开(公告)号:DE3761877D1
公开(公告)日:1990-04-19
申请号:DE3761877
申请日:1987-07-03
Applicant: RHONE POULENC CHIMIE
Inventor: GIRARDEAU YVETTE , RUFFO GEORGES , SEGAUD CHRISTIAN
Abstract: 1. A process for the preparation of surface active compositions by phosphatation by phosphoric anhydride of at least one polyoxyalkylenated derivative R1 -OR-OH (formula (V)), in which formula : O-R represents a succession of identical or different C2 -C4 oxyalkylenated units, in which the number of units can range from 1 to 80, R1 is a C8 -C20 straight or branched chain alkyl or alkenyl radical or an aryl radical of formula (III) see diagramm : EP0252824,P16,F1 in which : m is an integer of 1, 2 or 3 p is an integer of 1 or 2 R3 is a hydrogen atom or a C1 -C4 alkyl radical, and R2 is a C4 -C12 alkyl radical or a radical of the following formula : see diagramm : EP0252824,P16,F2 wherein : R4 represents a hydrogen atom or a C1 -C4 alkyl or phenyl radical ; and optionally neutralisation of the acid functions, the process being characterised in that the phosphatation operation is carried out in two steps : a phosphatation step in the true sense which is effected by continuously introducing phosphoric anhydride into a medium which is subjected to turbulent agitation conditions, the medium being formed by said polyoxyalkylenated derivative containing water in a sufficient amount to initiate the phosphatation reaction, at a temperature of the order of 35 to 40 degrees C at the beginning of the reaction, said temperature being maintained at a temperature lower than or equal to 45 degrees C until the end of the operation of introducing the phosphoric anhydride, the total amount of phosphoric anhydride used corresponding to a polyoxyalkylenated derivative/P2 O5 molar ratio equal to 3 +- 0.3, followed by a step for maturing of the reaction medium obtained, said step being carried out under turbulent agitation conditions at a temperature of between 40 and 60 degrees C.
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