Abstract:
The invention relates to a multi-phase polymer composition comprising a comb copolymer (A) which forms a continuous acrylate phase and a discontinuous hydrocarbon phase, and at least one hydrocarbon compound (B) which is soluble in the hydrocarbon phase of the comb polymer (A). The invention also relates to an adhesive mass comprising the claimed multi-phase polymer composition and to the use of the adhesive mass for sticking objects, in particular objects with non-polar surfaces.
Abstract:
The invention relates to a method for producing polyacrylate adhesive compounds with a narrow molar mass distribution by means of a radical polymerization and a subsequent decolorization of colored reaction products resulting from the method. The invention also relates to products produced using said adhesive compounds.
Abstract:
The invention relates to a UV-cross-linked, polyacrylate-based adhesive mass that has high adhesive force and high cohesion and that can be produced by means of a hot-melt process with subsequent cross-linking. This is achieved by providing an adhesive mass that can be obtained by cross-linking a composition, which comprises at least one poly(meth)acrylate having a weight-average molar mass M w of at least 100,000 g/mol and at least one polyfunctional α-cleaver and is characterized in that the composition contains at least one adhesive-force-increasing resin having a weight average molar mass M w of at most 30,000 g/mol, which resin can be obtained by polymerizing a monomer composition M1, comprising at least one compound according to formula (I) H 2 C=C(R 1 )(COOR 2 ), wherein R 1 represents a hydrogen atom or a methyl group and R 2 represents a hydrogen atom or a functionalized or non-functionalized C 1 -C 20 alkyl group.
Abstract:
The invention relates to a process for producing crosslinked polymers, a crosslinked polymer that can be produced by the process, an adhesive tape, and a backing for adhesive tapes, where these comprise said crosslinked polymer, a hot-melt adhesive and the use of a compound. According to at least one embodiment of the process, a polymer which comprises at least one carboxy group, more particularly a polyacrylate, is at least to some extent crosslinked via reaction with an at least doubly epoxidized crosslinking agent. The at least doubly epoxidized crosslinking agent is selected from a group comprising fatty acids, fatty acid esters, fatty alcohols, esters of fatty alcohols and combinations thereof.
Abstract:
Acrylate-based oligomers having double-bond end-group-functionalization are produced by means of free-radical polymerization where, in a first step, a monomer mixture of an acrylate component and of an aromatic component is reacted with use of a difunctional regulator, the quantity of the regulator being selected in such a way that the ratio of molar quantity of monomer mixture to that of regulator is from 100:20 to 100:0.5 and the polymerization is conducted until monomer conversion reaches at least 96%. In a second step, the resultant macromolecules are reacted, in the reactor in which the polymerization was conducted, with at least one compound Z which has a functional group and has an ethylenic double bond, and at least that portion of the compound Z that contains the ethylenic double bond becomes linked to the macromolecules via reaction of one of the functional groups of the difunctional regulator with the functional group of the compound Z.