Processes for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil, and apparatuses for treating biomass-derived pyrolysis oil
    42.
    发明授权
    Processes for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil, and apparatuses for treating biomass-derived pyrolysis oil 有权
    用于洗涤废离子交换床和处理生物质衍生的热解油的方法,以及用于处理生物质衍生的热解油的装置

    公开(公告)号:US09192931B2

    公开(公告)日:2015-11-24

    申请号:US13436648

    申请日:2012-03-30

    Abstract: Processes and apparatuses for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil are provided herein. An exemplary process for washing a spent ion exchange bed employed in purification of biomass-derived pyrolysis oil includes the step of providing a ion-depleted pyrolysis oil stream having an original oxygen content. The ion-depleted pyrolysis oil stream is partially hydrotreated to reduce the oxygen content thereof, thereby producing a partially hydrotreated pyrolysis oil stream having a residual oxygen content that is less than the original oxygen content. At least a portion of the partially hydrotreated pyrolysis oil stream is passed through the spent ion exchange bed. Water is passed through the spent ion exchange bed after passing at least the portion of the partially hydrotreated pyrolysis oil stream therethrough.

    Abstract translation: 本文提供了用于洗涤废离子交换床和处理生物质衍生的热解油的方法和设备。 用于净化生物质衍生的热解油所用的废离子交换床的示例性方法包括提供具有原始氧含量的离子贫化裂解油流的步骤。 部分加氢处理离子贫化热解油料流以降低其氧含量,由此产生部分加氢处理的裂解油料流,其残余氧含量小于原始氧含量。 部分加氢处理的热解油流中的至少一部分通过废离子交换床。 在通过部分加氢处理的热解油流的至少一部分之后,水通过废离子交换床。

    Process for the purification of virtually anhydrous organic liquids
    43.
    发明授权
    Process for the purification of virtually anhydrous organic liquids 失效
    净化几乎无水有机液体的方法

    公开(公告)号:US6123850A

    公开(公告)日:2000-09-26

    申请号:US078480

    申请日:1998-05-14

    CPC classification number: C07B63/02 B01J39/043

    Abstract: The subject matter of the present invention is a process for the purification of a virtually anhydrous organic liquid other than DMSO alone, in order to decrease its content of alkali and alkaline-earth metal and metal cations, characterized in that it consists essentially in placing this organic liquid in contact with one or more cation exchange resins and in then separating from the resin(s) the purified organic liquid, said resin or at least one of said resins being a sulphonic resin in --SO.sub.3 H or --SO.sub.3 NH.sub.4 form based on a polystyrene-divinylbenzene copolymer having a divinylbenzene content of from 50 to 60% by weight, without taking the sulphonic groups into account.

    Abstract translation: 本发明的主题是纯化除了单独的DMSO以外的几乎无水的有机液体的方法,以便降低其碱金属和碱土金属和金属阳离子的含量,其特征在于它主要包括将该 有机液体与一种或多种阳离子交换树脂接触,然后与树脂分离纯化的有机液体,所述树脂或至少一种所述树脂为基于聚苯乙烯的-SO 3 H或-SO 3 NH 4形式的磺酸树脂 二乙烯基苯共聚物,其二乙烯基苯含量为50至60重量%,而不考虑磺基。

    Mixed bed ion exchange resin system and method of preparation
    44.
    发明授权
    Mixed bed ion exchange resin system and method of preparation 有权
    混合离子交换树脂体系及其制备方法

    公开(公告)号:US06060526A

    公开(公告)日:2000-05-09

    申请号:US226824

    申请日:1999-01-07

    Inventor: Shintaro Tasaki

    CPC classification number: B01J39/043 B01J41/043 B01J41/14 B01J47/04

    Abstract: A method for preparing non-agglomerating mixed bed ion exchange resin systems without affecting the ion exchange kinetics of the anion exchange resin component of the mixed bed system is disclosed. Pretreatment of the anion exchange resin component with a sulfonated poly(vinylaromatic) polyelectrolyte is particularly effective in providing non-agglomerated mixed bed systems without affecting ion exchange kinetics. Treatment levels of 10 to 800 milligrams per liter of anion exchange resin with sulfonated poly(vinylaromatic) polyelectrolyte having number average molecular weight from 5,000 to 1,000,000 are particularly preferred.

    Abstract translation: 公开了一种在不影响混床系统的阴离子交换树脂组分的离子交换动力学的情况下制备非附聚混合床离子交换树脂体系的方法。 用磺化聚(乙烯基芳族)聚电解质预处理阴离子交换树脂组分对于提供非聚集的混合床体系而不影响离子交换动力学是特别有效的。 具有数均分子量为5,000至1,000,000的具有磺化聚(乙烯基芳族)聚电解质的每升阴离子交换树脂10至800毫克的处理水平是特别优选的。

    Metathetic process utilizing a cation exchanger
    45.
    发明授权
    Metathetic process utilizing a cation exchanger 失效
    利用阳离子交换剂的变形过程

    公开(公告)号:US5976379A

    公开(公告)日:1999-11-02

    申请号:US43912

    申请日:1998-06-02

    Inventor: Aharon Meir Eyal

    CPC classification number: B01J47/00 B01J39/00 B01J39/043

    Abstract: Disclosed is a metathetic process of the type M'X+M"=M'Y+M"X, where M' dirs from M" and the reagents and the products are water-soluble salts, comprising the steps of (a) transferring a solution of M"Y through at least one column containing cation exchanger beads loaded with M' cations, obtained in step (b) hereinafter, whereby cation exchange takes place to form a solution of M'Y and cation exchanger beads loaded with M", and (b) transferring a solution of M'X through said column containing cation exchanger beads loaded with M" obtained in step (a) above.

    Abstract translation: PCT No.PCT / GB96 / 02377。 371日期1998年6月2日 102(e)1998年6月2日PCT PCT 1996年9月26日PCT公布。 出版物WO97 / 13580 日期1997年4月17日公开是M'X + M“= M'Y + M'X型的复分解过程,其中M'与M”不同,试剂和产物是水溶性盐, 包括以下步骤:(a)通过至少一个含有阳离子交换剂珠的负载M'阳离子的载体转移M'Y的溶液,步骤(b)获得的阳离子交换剂珠在下文步骤(b)中获得,由此进行阳离子交换以形成M' Y和负载有M“的阳离子交换剂珠粒,和(b)通过载有上述步骤(a)中获得的M”的含有阳离子交换剂珠粒的M'X的溶液转移。

    Removal of low level ethylene oxide contaminants by treatment of
contaminated gases with cationic exchange resins at gas-solid interface
reaction conditions
    46.
    发明授权
    Removal of low level ethylene oxide contaminants by treatment of contaminated gases with cationic exchange resins at gas-solid interface reaction conditions 失效
    通过在气 - 固界面反应条件下用阳离子交换树脂处理污染气体来除去低水平的环氧乙烷污染物

    公开(公告)号:US4828810A

    公开(公告)日:1989-05-09

    申请号:US50469

    申请日:1987-05-18

    CPC classification number: B01D53/72 B01J39/043

    Abstract: A method of removing low levels of ethylene oxide (1% by volume or less) from ethylene oxide contaminated gases is provided. The removal is effected by contacting the ethylene oxide with a solid, cationic ion exchange resin at conditions such that the quantity of water present in the reaction zone is at a level such that the reaction of the ethylene oxide with resin occurs at a gas-solid interface to form an ethylene oxide derivative polymer which is bound to said resin.

    Abstract translation: 提供了从环氧乙烷污染气体中除去低含量环氧乙烷(1体积%以下)的方法。 通过使环氧乙烷与固体的阳离子交换树脂接触,使得存在于反应区中的水的量处于使得环氧乙烷与树脂的反应以气 - 固 界面形成与所述树脂结合的环氧乙烷衍生物聚合物。

    System and method for demineralizing water
    47.
    发明授权
    System and method for demineralizing water 失效
    软水脱水系统及方法

    公开(公告)号:US4820421A

    公开(公告)日:1989-04-11

    申请号:US45079

    申请日:1987-05-01

    CPC classification number: B01J39/043

    Abstract: Water is demineralized by passage through a water demineralization system. The water demineralization system comprises a series of at least three ion exchange resin zones. The sequential series comprises a strong acid cation (SAC) resin zone, a first anion resin zone, and a weak acid cation (WAC) resin zone. The SAC resin zone comprises a SAC resin for removing cations from the water, the first anion resin zone comprises an anion resin for removing anions from the water, and the WAC resin zone comprises a WAC resin for removing cations from water without substantially splitting any salts present in the water. Means for connecting each resin zone in the series are provided so that water can pass sequentially through the system. A method is also provided for regenerating the WAC resin from sodium and ammonium exhaustants. This method comprises contacting the WAC resin with an aqueous solution of a regenerant that is substantially devoid of sulfur and halogen groups. The regenerant is selected from the group consisting of (a) organic acids, (b) inorganic acids, (c) amine salts of (a) and (b), (d) amines, and (e) combinations thereof.

    Abstract translation: 水通过水脱矿质系统脱矿质。 水脱矿质系统包括一系列至少三个离子交换树脂区。 顺序系列包括强酸阳离子(SAC)树脂区,第一阴离子树脂区和弱酸阳离子(WAC)树脂区。 SAC树脂区域包括用于从水中除去阳离子的SAC树脂,第一阴离子树脂区域包括用于从水中除去阴离子的阴离子树脂,WAC树脂区域包括WAC树脂,用于从水中除去阳离子而基本上不分裂任何盐 在水中存在。 提供用于连接串联中的每个树脂区的装置,使得水可以顺序地通过系统。 还提供了从钠和铵排出物再生WAC树脂的方法。 该方法包括使WAC树脂与基本上不含硫和卤素基团的再生剂的水溶液接触。 再生剂选自(a)有机酸,(b)无机酸,(c)(a)和(b)的胺盐,(d)胺和(e)它们的组合。

    Apparatus for treating wash water from the manufacture of terephthalic
acid
    49.
    发明授权
    Apparatus for treating wash water from the manufacture of terephthalic acid 失效
    用于从制造对苯二甲酸处理洗涤水的设备

    公开(公告)号:US4675108A

    公开(公告)日:1987-06-23

    申请号:US748755

    申请日:1985-06-26

    Abstract: A process for treating wash water from the manufacture of terephthalic acid, wherein the wash water includes terephthalic acid, metal catalyst, and organic acid byproducts. The process includes the steps of passing the wash water through a filter medium to remove undissolved terephthalic acid solids, passing the filtered water through a cation exchange resin in hydrogen ion form to remove the metal catalysts, and passing the water through an anion exchange resin to remove dissolved terephthalic acid and dissolved organic acid byproducts. The treated water and certain components removed from the wash water are recovered and reused in the manufacture of additional terephthalic acid. An apparatus in which the process is practiced is also described and, after a quantity of wash water has been treated, the apparatus is regenerated with regenerants that are also recovered and reused in the manufacture of additional terephthalic acid.

    Abstract translation: 一种从对苯二甲酸的制造处理洗涤水的方法,其中洗涤水包括对苯二甲酸,金属催化剂和有机酸副产物。 该方法包括以下步骤:将洗涤水通过过滤介质以除去未溶解的对苯二甲酸固体,使过滤的水通过氢离子形式的阳离子交换树脂以除去金属催化剂,并将水通过阴离子交换树脂 去除溶解的对苯二甲酸和溶解的有机酸副产物。 将处理过的水和从洗涤水中除去的某些组分回收并重新用于制造额外的对苯二甲酸。 还描述了其中实施该方法的装置,并且在已经处理了一定数量的洗涤水之后,该设备用再生剂再生,再生剂也被回收并重新用于制造额外的对苯二甲酸。

    Bleed-off elimination system and method
    50.
    发明授权
    Bleed-off elimination system and method 失效
    排污系统和方法

    公开(公告)号:US4532045A

    公开(公告)日:1985-07-30

    申请号:US396042

    申请日:1982-07-07

    Abstract: A heat exchange system and process for reducing bleed-off are disclosed employing a weak acid cation exchange resin for treating the aqueous liquid coolant. In one such system and process, the aqueous coolant is treated with a weak acid ion exchange resin to remove alkaline salts therefrom without removing salts of strong acids; suspended solids are removed from the circulating aqueous coolant; and an effective amount of additive selected from the group consisting of scale inhibitors, corrosion inhibitors, microbiocides, and mixtures thereof is introduced into the circulating aqueous coolant so that bleed-off from said system is substantially reduced.

    Abstract translation: 公开了一种用于减少渗漏的热交换系统和方法,其使用弱酸阳离子交换树脂来处理含水液体冷却剂。 在一种这样的系统和方法中,用弱酸离子交换树脂处理含水冷却剂以从其中除去碱性盐而不除去强酸的盐; 从循环的含水冷却剂中除去悬浮固体; 并且将有效量的选自防垢剂,腐蚀抑制剂,杀微生物剂及其混合物的添加剂引入循环的含水冷却剂中,使得从所述系统泄漏的实质上减少。

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