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    Process for producing fibres, film, casings and other products from modified soluble cellose
    43.
    发明申请
    Process for producing fibres, film, casings and other products from modified soluble cellose 审中-公开
    由改性可溶性纤维素生产纤维，薄膜，肠衣等产品的方法

    公开(公告)号：US20040051200A1

    公开(公告)日：2004-03-18

    申请号：US10380388

    申请日：2003-09-05

    Inventor： Henryk Struszczyk ,  Dariusz Wawro ,  Alojzy Urbanowski ,  Wlodzimierz Mikolajczyk ,  Pawel Strarostka

    IPC: D01D001/10 ,  D01D005/06 ,  D01D005/12 ,  D01D010/06 ,  D01F002/02 ,  B29C047/14 ,  B29C047/20

    CPC classification number: D01F2/02 ,  A22C13/0013 ,  C08L1/02 ,  C08L1/06 ,  D01D1/02

    Abstract: Process for producing fibres, film, casings and other products from modified soluble cellulose wherein the initial cellulose is hydrothermally treated at a temperature in the 100-200null C. range, under a pressure in the range from about 0.1 to 1.5 Mpa in a water/cellulose ration on a weight basis of at least 1:1 in the presence of a complex activator composed of Lewis acids and/or bases and/or their salts in an amount of at least 0.0001% by weight calculated on cellulose. The obtained modified cellulose pulp after, a possible purification, is in a dry or never dried condition, dissolved in an aqueous solution of alkali metal hydroxides. The dissolving is carried out at a temperature not lower than 0null C. for 1-120 minutes to obtain a homogenous spinning solution with the cellulose concentration at least 1% by weight. The alkaline cellulose solution is filtered, deaerated and coagulated by contacting it with water or aqueous acidic solutions. The produced fibres, film, casings and other products are washed with water to a neutral reaction and finished in a standard way.

    Abstract translation: 从改性可溶性纤维素生产纤维，薄膜，肠衣和其他产品的方法，其中将初始纤维素在100-200℃范围内的水温下在约0.1-1.5Mpa的压力下在水中进行水热处理 在由路易斯酸和/或碱和/或其盐组成的复合活化剂存在下，以纤维素计算的至少0.0001重量％的量，基于重量计至少1:1的纤维素比例。 得到的改性纤维素纸浆可以进行纯化后处于干燥或从未干燥的条件下，溶解在碱金属氢氧化物的水溶液中。 溶解在不低于0℃的温度下进行1-120分钟，得到纤维素浓度至少为1重量％的均匀纺丝溶液。 将碱性纤维素溶液过滤，脱气并通过与水或酸性水溶液接触而凝结。 生产的纤维，薄膜，肠衣等产品用水洗涤至中性反应，并以标准方式完成。

    Fibrous composite cellulosic film and method
    44.
    发明授权
    Fibrous composite cellulosic film and method 失效
    纤维复合纤维素膜及方法

    公开(公告)号：US5747125A

    公开(公告)日：1998-05-05

    申请号：US684347

    申请日：1996-07-18

    Applicant: John Markulin

    Inventor： John Markulin

    IPC: C08J3/24 ,  A22C13/00 ,  B29C47/00 ,  B29K1/00 ,  B29L7/00 ,  C08J5/18 ,  C08K5/06 ,  C08L1/02 ,  C08L1/06 ,  C08L97/02 ,  D01D5/00

    CPC classification number: C08J5/18 ,  A22C13/0013 ,  C08J5/045 ,  C08L1/06 ,  C08J2301/02 ,  Y10T428/1324

    Abstract: A crosslinked cellulose composite film including a regenerated cellulose matrix containing a uniform dispersion of hemp fibers and a poly(ethylene oxide) plasticizer. A method for forming the film includes mixing a slurry of the hemp, poly(ethylene oxide) and a cellulose solvent with a cellulose solution, extruding the mixture, regenerating the cellulose from the solution to form the matrix containing hemp fibers, contacting with a crosslinking agent and then drying.

    Abstract translation: 一种交联纤维素复合膜，其包含含有大麻纤维均匀分散体和聚（环氧乙烷）增塑剂的再生纤维素基质。 形成膜的方法包括将大麻，聚（环氧乙烷）和纤维素溶剂的浆料与纤维素溶液混合，挤出混合物，从溶液中再生纤维素以形成含有大麻纤维的基质，与交联 代理然后干燥。

    Fine cellulose particles and process for production thereof
    46.
    发明授权
    Fine cellulose particles and process for production thereof 失效
    细纤维素颗粒及其生产方法

    公开(公告)号：US5244734A

    公开(公告)日：1993-09-14

    申请号：US145727

    申请日：1988-01-15

    Applicant: Shigeru Okuma ,  Kanji Yamagishi ,  Masami Hara ,  Keizo Suzuki ,  Toshihiro Yamamoto

    Inventor： Shigeru Okuma ,  Kanji Yamagishi ,  Masami Hara ,  Keizo Suzuki ,  Toshihiro Yamamoto

    IPC: C08B16/00 ,  C08J3/16 ,  C08L1/06

    CPC classification number: C08J3/16 ,  C08B16/00 ,  C08L1/06 ,  C08J2301/06 ,  Y10T428/2982 ,  Y10T428/2998

    Abstract: A process for producing fine cellulose particles, which comprises(1) mixing viscose with a water-soluble anionic polymeric compound or polyethylene glycol or its derivative to form a dispersion of fine particles of viscose,(2) (i) heating the dispersion or mixing it with a coagulating agent to thereby coagulate the viscose in the dispersion, and thereafter neutralizing it with an acid to form fine particles of cellulose, or (ii) coagulating and neutralizing the dispersion with an acid to form fine particles of cellulose, and(3) thereafter, separating the fine particles of cellulose from the mother liquor. The fine cellulose particles(a) are composed substantially of II-type cellulose,(b) have a crystallinity, of 5 to 35% by weight,(c) are composed substantially of particles of not more than 20 micrometers, and(d) have a sharp particle size distribution.

    Abstract translation: 一种生产精细纤维素颗粒的方法，其包括（1）将粘胶与水溶性阴离子聚合物或聚乙二醇或其衍生物混合以形成粘胶细颗粒的分散体，（2）（i）加热分散体或混合 用凝结剂凝结分散体中的粘胶，然后用酸中和，形成纤维素微粒，或者（ii）用酸凝固和中和分散体，形成纤维素的微粒;（3） ）之后，从母液中分离纤维素的微粒。 微细纤维素颗粒（a）基本上由II型纤维素组成，（b）具有5-35重量％的结晶度，（c）基本上由不大于20微米的颗粒组成，和（d） 具有尖锐的粒度分布。

    Shaped article comprising a permanently plasticized cellulose hydrate composition and preparation thereof
    49.
    发明授权
    Shaped article comprising a permanently plasticized cellulose hydrate composition and preparation thereof 失效
    成型制品包括永久增塑的水合物水合物组合物及其制备

    公开(公告)号：US4253879A

    公开(公告)日：1981-03-03

    申请号：US856034

    申请日：1977-11-30

    Applicant: Klaus-Dieter Hammer ,  Gunter Gerigk ,  Wolf-Rainer Neeff ,  Max Bytzek

    Inventor： Klaus-Dieter Hammer ,  Gunter Gerigk ,  Wolf-Rainer Neeff ,  Max Bytzek

    IPC: C08L1/00 ,  A22C13/00 ,  B29C47/00 ,  B65D75/00 ,  C08L1/06 ,  C08L1/24

    CPC classification number: B65D75/00 ,  A22C13/0013 ,  B29C47/0021 ,  B29C47/0026 ,  B29C47/8895 ,  C08L1/06 ,  B29C47/0014 ,  Y10T428/1324

    Abstract: A shaped article, especially a tubing, is disclosed which comprises a plasticized cellulose hydrate composition comprising a cellulose hydrate and a plasticity enhancing amount of at least one substantially water insoluble plasticizing ester of an aliphatic monocarboxylic acid containing from about 9 to about 24 carbon atoms and a polyalcohol comprising at least two hydroxy groups at least one of which is esterified with said aliphatic monocarboxylic acid, and water and/or a plasticizer.Such shaped articles can be prepared by mixing a viscose solution with a liquid containing the plasticizing ester, introducing the resulting mixture into a precipitating bath and drying the precipitated shaped body. Tube-shaped articles are especially suited as sausage casings.

    Abstract translation: 公开了一种成型制品，特别是管材，其包含增塑的纤维素水合物组合物，其包含纤维素水合物和可塑性增强量的含有约9至约24个碳原子的脂族一元羧酸的至少一种基本上不溶于水的增塑酯， 包含至少两个羟基的多元醇，其中至少一个与所述脂族一元羧酸酯化，以及水和/或增塑剂。 这种成形制品可以通过将粘胶溶液与含有增塑酯的液体混合，将所得混合物引入沉淀浴中并干燥沉淀的成形体来制备。 管状物品特别适合作为香肠肠衣。

    Films from modified regenerated cellulose
    50.
    发明授权
    Films from modified regenerated cellulose 失效
    改性再生纤维素膜

    公开(公告)号：US4026718A

    公开(公告)日：1977-05-31

    申请号：US614025

    申请日：1975-09-16

    Applicant: Georges Cornille ,  Roland Jacobs ,  Walter Bontinck

    Inventor： Georges Cornille ,  Roland Jacobs ,  Walter Bontinck

    IPC: C08L1/00 ,  C08L1/06 ,  C08L1/24

    CPC classification number: C08L1/06

    Abstract: A modified regenerated cellulose film comprising regenerated cellulose and certain modified starches is clear and transparent and has substantially the same mechanical and optical properties as conventional unmodified regenerated cellulose films. The modified starches used are starches degraded by oxidation and/or hydrolysis, uncrosslinked ethers or esters of starch or of starches degraded by oxidation and/or hydrolysis or mixtures thereof. The amount of modified starch used represents 1 to 49% by weight, preferably 5 to 30% by weight, based on the total weight of cellulose and modified starch. Methods for the production of said modified regenerated cellulose film either by the viscose process or by the cuprammonium process are also described.

    Abstract translation: 包含再生纤维素和某些改性淀粉的改性再生纤维素膜是透明和透明的，并且具有与常规未改性的再生纤维素膜基本上相同的机械和光学性能。 所用的改性淀粉是通过氧化和/或水解降解的淀粉，淀粉的未交联的醚或酯或通过氧化和/或水解或其混合物降解的淀粉。 基于纤维素和改性淀粉的总重量，所使用的改性淀粉的量为1至49重量％，优选5至30重量％。 还描述了通过粘胶法或铜铵法生产所述改性再生纤维素膜的方法。

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