Capped particles comprising multi-block copolymers for use in lubricants
    531.
    发明授权
    Capped particles comprising multi-block copolymers for use in lubricants 有权
    包含用于润滑剂的多嵌段共聚物的包覆颗粒

    公开(公告)号:US08609247B2

    公开(公告)日:2013-12-17

    申请号:US13239924

    申请日:2011-09-22

    Applicant: Shimon Mizrahi

    Inventor: Shimon Mizrahi

    Abstract: The present invention relates to additives for use in lubricant compositions to processes for producing the additives, and to the use of the additives in lubricants and in systems that are lubricated. More specifically, the additive includes a capped particle comprising: (i) one or more inorganic core particles; and (ii) one or more multi-block copolymers attached to the inorganic particles. The multi-block copolymer includes at least one nonpolar polymer block interposed between two polar polymer blocks. One polar polymer block is attached to the core particle, and at least a portion of the another polar polymer block is not directly attached to the core particle. When used in a lubricant to lubricate a metallic surface of a workpiece, the capped particle preferably adheres to the metallic surface of the workpiece.

    Abstract translation: 本发明涉及润滑剂组合物中用于制备添加剂的方法的添加剂,以及在润滑剂和润滑系统中使用添加剂。 更具体地,添加剂包括封端颗粒,其包含:(i)一种或多种无机芯颗粒; 和(ii)连接到无机颗粒上的一种或多种多嵌段共聚物。 多嵌段共聚物包括插入在两个极性聚合物嵌段之间的至少一个非极性聚合物嵌段。 一个极性聚合物嵌段连接到核心颗粒上,另外极性聚合物嵌段的至少一部分不直接连接到芯颗粒上。 当用于润滑剂以润滑工件的金属表面时,被覆盖的颗粒优选地粘附到工件的金属表面。

    PROCESS FOR PREPARATION OF HIGH MOLECULAR WEIGHT MOLYBDENUM SUCCINIMIDE COMPLEXES
    534.
    发明申请
    PROCESS FOR PREPARATION OF HIGH MOLECULAR WEIGHT MOLYBDENUM SUCCINIMIDE COMPLEXES 有权
    高分子量钼多糖复合物的制备方法

    公开(公告)号:US20120190864A1

    公开(公告)日:2012-07-26

    申请号:US13011520

    申请日:2011-01-21

    Abstract: Disclosed is a process for preparing a molybdated succinimide complex, the process comprising: (a) reacting an alkyl or alkenyl mono- or bis-succinimide of a polyamine of formula I or formula II or mixtures thereof: wherein R is an alkyl or alkenyl group having a number average molecular weight of about 500 to about 5,000, R′ is a straight or branched-chain alkylene group having 2 to 3 carbon atoms, x is 2 to 11, and y is 1 to 10, with an α,β-unsaturated mono-carboxylic acid or carboxylic acid ester, in a charge mole ratio of the α,β-unsaturated mono-carboxylic acid or carboxylic acid ester to the succinimide of formula I or formula II or mixtures thereof of greater than 1.05:1 to about 6:1, and wherein the reaction temperature is in the range of from greater than 80° C. to no greater than about 150° C.; and (b) reacting the succinimide product of step (a) with an acidic molybdenum compound to provide the molybdated succinimide complex, wherein the molybdated succinimide complex is a liquid at room temperature.

    Abstract translation: 公开了一种制备钼酸化琥珀酰亚胺复合物的方法,该方法包括:(a)使式I或式II的多胺或其混合物的烷基或烯基单 - 或二 - 琥珀酰亚胺反应:其中R是烷基或链烯基 数均分子量为约500〜约5000,R'为碳原子数2〜3的直链或支链亚烷基,x为2〜11,y为1〜10,α,bgr; - 不饱和单羧酸或羧酸酯,以α,bgr-不饱和单羧酸或羧酸酯与式I或式II的琥珀酰亚胺或其混合物的摩尔比大于1.05:1 至约6:1,并且其中反应温度在大于80℃至不大于约150℃的范围内。 和(b)使步骤(a)的琥珀酰亚胺产物与酸性钼化合物反应以提供钼酸化琥珀酰亚胺配合物,其中钼酸化琥珀酰亚胺络合物在室温下为液体。

    CAPPED PARTICLES FOR USE IN LUBRICANTS
    538.
    发明申请
    CAPPED PARTICLES FOR USE IN LUBRICANTS 有权
    用于润滑剂的填充颗粒

    公开(公告)号:US20100004147A1

    公开(公告)日:2010-01-07

    申请号:US12492234

    申请日:2009-06-26

    Applicant: Shimon Mizrahi

    Inventor: Shimon Mizrahi

    Abstract: The present invention relates to additives for use in lubricant compositions to processes for producing the additives, and to the use of the additives in lubricants and in systems that are lubricated. More specifically, the additive includes a capped particle comprising: (i) one or more core particles wherein the core particle is an inorganic particle having a dimension less than about 5 μm; and (ii) one or more multi-block copolymers attached to the inorganic particles, wherein the multi-block copolymer comprises a) at least one nonpolar polymer block; b) at least one first polar polymer block; and c) at least one second polar polymer block; wherein the nonpolar polymer block is interposed between the first polar polymer block and the second polar polymer block, the first polar polymer block is attached to the core particle, and at least a portion of the second polar polymer block is not attached to the core particle. When used in a lubricant to lubricate a metallic surface of a workpiece, the capped particle preferably adhere to the metallic surface of the workpiece.

    Abstract translation: 本发明涉及润滑剂组合物中用于制备添加剂的方法的添加剂,以及在润滑剂和润滑系统中使用添加剂。 更具体地说,该添加剂包括一种封盖颗粒,其包括:(i)一种或多种芯颗粒,其中芯颗粒是尺寸小于约5μm的无机颗粒; 和(ii)连接到无机颗粒上的一种或多种多嵌段共聚物,其中所述多嵌段共聚物包含a)至少一种非极性聚合物嵌段; b)至少一个第一极性聚合物嵌段; 和c)至少一个第二极性聚合物嵌段; 其中所述非极性聚合物嵌段介于所述第一极性聚合物嵌段和所述第二极性聚合物嵌段之间,所述第一极性聚合物嵌段连接到所述芯颗粒,并且所述第二极性聚合物嵌段的至少一部分不附着于所述芯颗粒 。 当用于润滑剂以润滑工件的金属表面时,被覆盖的颗粒优选地粘附到工件的金属表面。

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