Piperidine compounds containing silane groups for use as stabilizers for
organic materials
    552.
    发明授权
    Piperidine compounds containing silane groups for use as stabilizers for organic materials 失效
    含有硅烷基的哌啶化合物用作有机材料的稳定剂

    公开(公告)号:US5418267A

    公开(公告)日:1995-05-23

    申请号:US234892

    申请日:1994-04-28

    Abstract: The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilizing an organic material against thermal, oxidative and light-induced degradation.

    Abstract translation: 本发明涉及式(I)的新型哌啶化合物,其中A为例如。 一组式为“IMAGE”,其中R4为例如。 氢或甲基,X3是例如。 -O-或-NH-和R5'是例如。 乙烯,丙烯或十亚甲基。 甲基,甲氧基,乙氧基或OH,R2和R3是例如。 甲基,m + n为例如。 1到40的数,n变化例如 从总和m + n的零到50%,X1是例如。 如对R 1所定义或是基团(CH 3)3 SiO-和X 2是例如。 氢,甲基,乙基,基团(CH 3)3 Si-或基团,当m + n为3〜10的数时,X1和X2一起也形成直接键。 式(I)的化合物有效地稳定有机材料以防止热,氧化和光诱导的降解。

    Novel light stabilizers for plastics
    558.
    发明授权
    Novel light stabilizers for plastics 失效
    用于塑料的新型光稳定剂

    公开(公告)号:US4256627A

    公开(公告)日:1981-03-17

    申请号:US956716

    申请日:1978-11-01

    CPC classification number: C08L101/00 C08L2201/08

    Abstract: Mixtures of a polymer which contains polyalkylpiperidines chemically bonded in any form and a metal compound MeL.sub.w, in which Me is a divalent or trivalent metal ion or a divalent oxo-metal ion or a divalent dialkyl-tin ion, L is the monovalent anion of a carboxylic acid, of a phosphinic acid or of a phosphonic acid monoester or of an enol and w is 2 or 3, are effective light stabilizers for plastics. The piperidine-containing polymers can be, for example, polyesters, polyamides, polyamines, polyaminotriazines or poly(meth)-acrylates. Examples of metal compounds MeL.sub.w are nickel oenanthate or nickel acetylacetonate. Plastics to be stabilized are in particular the polyolefins.

    Abstract translation: 含有以任何形式化学键合的聚烷基哌啶和金属化合物MeLw的聚合物的混合物,其中Me是二价或三价金属离子或二价氧代金属离子或二价二烷基锡离子,L是一价阴离子 次膦酸或膦酸单酯或烯醇和w的羧酸为2或3,是塑料的有效光稳定剂。 含哌啶的聚合物可以是例如聚酯,聚酰胺,聚胺,聚氨基三嗪或聚(甲基)丙烯酸酯。 金属化合物MeLw的实例是乙酸鲸蜡酸镍或乙酰丙酮酸镍。 待稳定的塑料尤其是聚烯烃。

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