Abstract:
A self-lubricating solid coating that contains three layers of lubricants is disclosed. The solid lubricant may be prepared from chromium silicide or chromium carbide; disulfide and diselenide of tungsten, molybdenum, niobium, or tantalum; and silver or gold. This material combination provides superior wear and friction reduction over the temperature range applied. In this invention, chromium silicide or chromium carbide is a hard lubricant with a low wear property to protect the substrate metal; disulfide or diselenide is a soft lubricant with a very low coefficient of friction; and silver or gold with their high thermal conductivity are effective in conducting heat especially at high sliding velocities. Both silver and gold have a low friction coefficient with high oxidative stability. The use of this solid lubricant allows engine manufacturers to develop high temperature engine and partially or totally eliminate the use of liquid lubricants in engines, thus reducing the environmental pollution caused by liquid lubricants in various engines.
Abstract:
Elastic solids having reversible stress-induced fluidity are prepared, e.g., by combining liquid formulations with a crystalline mixed metal hydroxide conforming substantially to the formula Li.sub.m D.sub.d T(OH).sub.(m+2d+3+n.multidot.a) (A.sup.n).sub.a .multidot.xH.sub.2 O where m is amount of Li, d is amount of divalent metal D, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n and a is the amount of A, and xH.sub.2 O represents excess waters of hydration, if any. These make useful coatings. The instantly reversible fluidization of these unique elastic solids may be expressed as: .sigma.=k.sub..alpha. .epsilon. when .epsilon. F, (this equation represents a generalized form for the usual theological equations); for a cycle of .epsilon., -xF
Abstract:
Alkenylsuccinic acid half-amides of the formulae ##STR1## are used in water-containing and/or oil-containing formulations or metalworking liquids as anticorrosive agents and emulsifiers. In said formulae: A=C.sub.6 -C.sub.30 alkenyl, R=H or R.sup.1, R.sup.1 =--R.sub.2 --O--(CH.sub.2 CHR.sup.3 --O).sub.n H, R.sup.2 =C.sub.1 -C.sub.1 -C.sub.10 alkylene, R.sup.3 =--H or --CH.sub.3, n=0 to 50 and Me.sup..sym. is an alkali metal ion, a proton or an ammonium ion of the formula HN.sup..sym. R.sup.4 R.sup.5 R.sup.6, R.sup.4, R.sup.5 and R.sup.6, which are identical or different, being hydrogen, C.sub.1 -C.sub.6 alkyl or hydroxyalkyl or Me.sup..sym. is a mixture of an alkali metal ion and an ammonium ion of the above-mentioned formula.
Abstract:
A rock bit grease composition is prepared by combining synthetic polymer lubricant basestocks comprising a first ethylene-alphaolefin polymer having an average molecular weight in the range of from 3,500 to 4,000, and a polyisobutylene polymer to form a first master. A metal complex soap base thickener is prepared by combining a synthetic polymer lubricant basestocks comprising a second ethylene-alphaolefin having an average molecular weight in the range of from 400 to 800, with an alkali-metal or alkaline-earth metal hydroxide, and at least one fatty acid. A preferred fatty acid is a blend of a first fatty acid having in the range of from 15 to 20 carbon atoms, and a second fatty acid having in the range of from 5 to 12 carbon atoms. The first master and metal complex soap base thickener are mixed together in desired proportions. Boron nitride extreme pressure agent, molybdenum disulfide lubricant additive, and copper powder anti-seize agent are added to the mixture to produce a grease composition having a Brookfield viscosity at 120.degree. C. in the range of from 600 to 750 centipoise, that is not harmful to elastomeric rock bit seals and boots, and that is free of metal lubricant additives that are toxic to humans and/or hazardous to the environment.
Abstract:
A lubricant and surface conditioner for formed metal surfaces, particularly beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. An aqueous composition for forming the conditioner by contact with metal surfaces includes a water-soluble organic material selected from a phosphate ester, alcohol, fatty acid including mono-, di-, tri-, and polyacids; fatty acid derivatives such as salts, hydroxy acids, amides, esters, ethers and derivatives thereof; and mixtures thereof and at least one of the elements selected from zirconium, titanium, cerium, aluminum, iron, tin, vanadium, tantalum, niobium, molybdenum, tungsten, and hafnium in metallic or ionic form. In order to avoid formation of sludge in the aqueous lubricant and surface conditioner forming composition, the composition should contain as little as possible of materials containing phenanthrene rings, such as conventional surfactants made by ethoxylating rosin. In order to assure the minimization of such surfactants in the aqueous lubricant and surface conditioner forming composition, surfactants containing phenanthrene rings should also be avoided or minimized in earlier cleaning stages.
Abstract:
A a process for making a lubricious composition useful for preventing seizing of threaded fasteners in application to the threaded surface(s) thereof, comprising: (a) forming metal wire by drawing of metal source material through a wire drawing die; (b) lubricating the wire drawing die with an oil lubricant in forming the metal wire, to produce as a by-product thereof a metal flake/oil mixture; (c) separating the metal flake/oil mixture to recover a metal flake/oil suspension; and (d) formulating the metal flake/oil suspension in a metal flake-containing lubricant composition. The invention in another aspect relates to a product of such process. In a specific compositional aspect, the invention relates to a composition comprising an oil-based vehicle, 15%-35% by weight particulate metal (e.g., microscopic flake aluminum), based on the total weight of the composition, and 10%-30% by weight graphite, based on the total weight of the composition.
Abstract:
A lubricant and surface conditioner for formed metal surfaces, particularly aluminum and tin beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. The conditioner includes a water-soluble organic material selected from amine oxides and quaternary ammonium salts, fluozirconate, fluohafnate, or fluotitanate ion, and preferably also phosphate and nitrate ions. Good resistance to damaging the friction reducing effect by overheating and to staining of the domes of treated containers during pasteurization can be achieved.
Abstract:
A graphite-free lubricating oil which comprises a base oil having dispersed therein 10 to 40% by weight of a carbohydrate and/or a derivative thereof whose particle size ranges from 10 to 150 .mu.m, 2 to 20% by weight of a film-boosting agent and 0.1 to 20% by weight of a dispersant. Moreover, the lubricating oil is free of black-colored substances such as graphite. Therefore, the oil permits the improvement of working surroundings and exhibits excellent properties such as formability through forging almost comparable to or even greater than that of the commercially available graphite-in-oil type lubricating oils. The lubricating oil can be used instead of the graphite-containing lubricating oils for warm forging, hot forging, rolling, tube-manufacturing, drawing and extrusion in place of the graphite-containing lubricating oils and ensures the improvement in the working surroundings and excellent lubricity.
Abstract:
Disclosed are high performance grease compositions containing methylfluoroalkylsiloxanes and solid thickeners containing fluorinated polymers.
Abstract:
A lubricant and surface conditioner for formed metal surfaces, particularly beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. The conditioner includes a water-soluble organic material selected from a phosphate ester, alcohol, fatty acid including mono-, di-, tri-, and polyacids; fatty acid derivatives such as salts, hydroxy acids, amides, esters, ethers and derivatives thereof; and mixtures thereof.