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    PROCESS FOR THE PRODUCTION OF A POLYMER COMPRISING MONOMERIC UNITS OF ETHYLENE, AN -OLEFIN AND A VINYL NORBORNENE
    54.
    发明公开
    PROCESS FOR THE PRODUCTION OF A POLYMER COMPRISING MONOMERIC UNITS OF ETHYLENE, AN -OLEFIN AND A VINYL NORBORNENE 审中-公开
    PROCESS FOR由乙烯，α烯烃和乙烯基降冰片烯生产具有单体单元的聚合物

    公开(公告)号：EP3112385A1

    公开(公告)日：2017-01-04

    申请号：EP16173894.3

    申请日：2004-06-29

    Applicant: Arlanxeo Netherlands B.V.

    Inventor： VAN DOREMAELE, Gerardus Henricus Josephus ,  WINDMULLER, Jozef Hubert Peter

    IPC: C08F210/18 ,  C08F4/6592

    Abstract: The invention relates to a process for the preparation of a polymer comprising monomeric units of ethylene, an α-olefin and a vinyl norbornene applying as a catalyst system:
    a. a bridged or an unbridged group 4 metal containing an unbridged catalyst having a single cyclopentadienyl ligand and a mono substituted nitrogen ligand, wherein said catalyst is defined by the formula I:
    b. an aluminoxane activating compound,
    c. 0 - 0.20 mol per mol of the catalyst of a further activating compound,

    wherein Y is a substituted carbon or nitrogen atom. The invention further relates to a polymer obtainable with the process of the invention.

    Abstract translation: 本发明涉及一种用于乙烯的单体单元的聚合物的制备方法，在±烯烃和乙烯基降冰片烯作为施加的催化剂体系：一。 桥接的或未桥接的第4族金属在具有单个环戊二烯基配体和单substituiertem氮配体，未桥连的含催化剂worin所述催化剂是由式I定义：乙。 铝氧烷活化化合物，C。 0 - 每一个另外的活化化合物的催化剂的摩尔12:20摩尔，worin Y是碳原子或氮原子substituiertem。 本发明进一步涉及一种聚合物可获得的用本发明的过程。

    METAL COMPLEX COMPRISING AMIDINE AND SUBSTITUTED CYCLOPENTADIENYL LIGANDS
    60.
    发明公开
    METAL COMPLEX COMPRISING AMIDINE AND SUBSTITUTED CYCLOPENTADIENYL LIGANDS 审中-公开
    包含脒和取代的环戊二烯配体的金属络合物

    公开(公告)号：EP3194412A1

    公开(公告)日：2017-07-26

    申请号：EP15759472.2

    申请日：2015-09-08

    Applicant: Arlanxeo Netherlands B.V.

    Inventor： KARBAUM, Peter ,  SCOTT, Richard Thomas William ,  VAN DE MOOSDIJK, John

    IPC: C07F17/00 ,  C08F210/18 ,  C08F4/6592 ,  C08F10/02

    CPC classification number: C08F10/02 ,  C07F7/28 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/18 ,  C08F2420/04 ,  C08F4/6592 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/03 ,  C08F2500/17

    Abstract: A metal complex of the formula (1 ) CyLMZp(A)n (1 ), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, Cy is a cyclopentadienyl-type ligand substituted with at least one aliphatic C3-C20 hydrocarbyl group, which is bonded to the cyclopentadienyl-type ligand, in particular to its cyclopentadienyl ring, via a secondary, a tertiary or quaternary carbon atom and, L is an amidinate ligand of the formula (2), wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom and A is a neutral Lewis base ligand selected from the list consisting of ether, thioether, amine, tertiary phosphane, imine, nitrile and isonitrile,wherein the number of said metal ligands "n" is in the range of 0 to the amount that specifies the 18-electron rule.

    Abstract translation: 式（1）CyLMZp（A）n（1）的金属配合物，其中M是第4族金属Z是阴离子配体，p是1-2的数，优选2，Cy是环戊二烯基型配体取代的 与至少一个通过仲，叔或季碳原子键合到环戊二烯基型配体，特别是其环戊二烯基环上的脂族C 3 -C 20烃基和L是式（2）的脒盐配体 ），其中含脒配体通过亚胺氮原子与金属M共价键合，并且Sub1是包含Sub1与亚胺碳原子键合的14族原子的取代基，并且Sub2是包含以下杂原子的取代基： 其中Sub2与亚胺碳原子键合，并且A是选自醚，硫醚，胺，叔膦，亚胺，腈和异腈的中性路易斯碱配体，其中所述金属配体“ n“在0到amou的范围内 指定18电子规则的nt。

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