Abstract:
Included are segmented polyurethane elastic fibers or spandex fibers, capable of bonding to polymer fiber such as nylon or polyamide fibers, in addition to bonding to itself, for apparel textile applications. More particularly the invention relates to bicomponent spandex fibers, with a heat resistant core and a heat sensitive sheath, spun from polymer solutions. The nylon fabrics containing such spandex fibers have enhanced stretch performance and improved surface appearance after heat treatment to activate the fusing and bonding between nylon fibers and spandex fibers.
Abstract:
The invention relates to a thermosiphon esterifier design comprising a riser baffle in the vapor separator. Advantageously, the thermosiphon esterifier design can provide an economic benefit as compared with traditional thermosiphon esterifier designs. Methods of using the thermosiphon esterifier design in a system for the production of polyethylene terephthalate are also described.
Abstract:
Disclosed are process controls for controlling the continuous preparation of nylon salt solution. The process controls include feed forward controls. A model is generated to achieve a target pH and/or salt concentration. Feed rates are set for each of a dicarboxylic acid monomer, a diamine monomer, and/or water to a single continuous stirred tank reactor. The dicarboxylic acid is metered, based on weight, from a loss-in-weight feeder to the reactor. The nylon salt solution is formed continuously and has low variability from a target pH and/or a target salt solution concentration. The nylon salt solution is transferred directly to a storage tank, without further monomer addition, pH adjustment, or salt solution adjustment after exiting the continuous stirred tank reactor.
Abstract:
The present invention relates to methods, systems, and apparatus for making polyamides having at least two heat-transfer media. The method includes heating a first flowable heat-transfer medium, to provide a heated first flowable heat-transfer medium. The method includes transferring heat from the heated first flowable heat-transfer medium to a second flowable heat-transfer medium, to provide a heated second flowable heat-transfer medium. The method also includes transferring heat from the heated second flowable heat-transfer medium to at least one polyamide-containing component of a polyamide synthesis system.
Abstract:
Process for producing compounds comprising nitrile functionsThe present invention relates to a process for producing compounds comprising at least one nitrile function by hydrocyanation of a compound comprising at least one non-conjugated unsaturation.The invention proposes a process for producing compounds comprising at least one nitrile function by hydrocyanation of an organic compound comprising at least one non-conjugated unsaturation, comprising from 2 to 20 carbon atoms, by reaction with hydrogen cyanide in the presence of a catalytic system comprising a complex of nickel having the oxidation state of zero with at least one organophosphorus ligand chosen from the group comprising organophosphites, organophosphonites, organophosphinites and organosphosphines and a cocatalyst of the Lewis acid type.
Abstract:
This document describes biochemical pathways for producing 2,4-pentadienoyl-CoA by forming one or two terminal functional groups, comprised of carboxyl or hydroxyl group, in a C5 backbone substrate such as glutaryl-CoA, glutaryl-[acp] or glutarate methyl ester. 2,4-pentadienoyl-CoA can be enzymatically converted to 1,3-butadiene.
Abstract:
This document describes biochemical pathways for producing glutaric acid, 5-aminopentanoic acid, 5-hydroxypentanoic acid, cadaverine or 1,5-pentanediol by forming one or two terminal functional groups, comprised of carboxyl, amine or hydroxyl group, in a C5 backbone substrate such as malonyl-CoA or malonyl-[acp].
Abstract:
Included herein is an articles and methods including a core spun yarn. The core spun yarn includes a sheath of hard fibers and two sets of elastic fibers wherein the sets of elastic fibers have different properties. The properties may differ in one or more ways such as having a different denier, composition or draft. One or both of the sets of elastic fibers can be precovered.
Abstract:
The invention provides methods useful in the industrial scale process for hydrocyanation of butadiene to adiponitrile for recycle of unwanted byproduct 2-methyl-3-butenenitrile (2M3BN) by conversion to process intermediate pentenenitrile. The invention provides a process for generating catalysts useful for carrying out the hydrocyanation of butadiene to adiponitrile, the process comprising contacting the 2M3BN and a solution of a nickel-ligand catalyst in cis-2-pentenenitrile (cis-2PN), trans-2-pentenenitrile (trans-2PN), or a mixture thereof. The improved methods of the invention can provide improved catalyst solubility for bidentate ligands without a requirement for a Lewis acid catalyst promoter such as zinc chloride to be present.
Abstract:
Disclosed is a process for isomerizing cis-2-pentenenitrile to 3-pentenenitrile in the presence of a non-aluminium metal oxide catalyst, wherein: (a) the metal in the catalyst has an oxidation state in the range from +1 to +4; (b) the metal has a cation radius in the range from 0.35 to 1.0 Å; (c) the metal of the catalyst has a polarising power, C/r, is in the range from 2 to >8, wherein C is the charge of the metal and r is the ionic radius in Å; (d) the bond network of the catalyst has a % ionicity of >20; (e) the metal oxide has an acidity strength in the range from strong to very weak; and (f) the metal oxide has a basicity (nucleophilicity) strength of weak to strong.