公开(公告)号：US11680161B2

公开(公告)日：2023-06-20

申请号：US16762645

申请日：2018-11-12

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Nils Wittenberg ,  Gisbert Michels ,  Tobias Schulz ,  Wolfgang Fischer ,  Lena Grassberger

IPC: C08F6/22 ,  C08K3/32 ,  C08L55/02 ,  C08L25/12 ,  C08K5/00 ,  C08L51/04 ,  C08F279/02 ,  C08L51/00 ,  C08K3/26 ,  C08K5/092

CPC classification number: C08L25/12 ,  C08F6/22 ,  C08F279/02 ,  C08K5/0083 ,  C08L51/003 ,  C08L51/04 ,  C08L55/02 ,  C08K5/092 ,  C08K2003/262 ,  C08K2003/321 ,  C08K2003/324 ,  C08K2003/329 ,  C08F6/22 ,  C08L55/02 ,  C08L25/12 ,  C08L55/02 ,  C08L69/00 ,  C08L55/02 ,  C08L25/12

Abstract: The present invention relates to a process for producing a thermoplastic molding composition and articles made thereof having improved surface quality, in particular improved surface quality after exposure to warm-humid environmental conditions. The thermoplastic molding composition comprises a thermoplastic polymer A, a graft copolymer B obtained by emulsion graft polymerization and optionally a further polymer component P, as well as optional further components/additives K, wherein at least one crystallization additive C, selected from phosphate compounds having 1 to 25 phosphate units, organic acids and salts thereof, is added during or after the preparation of the graft copolymer B.

公开(公告)号：US11655359B2

公开(公告)日：2023-05-23

申请号：US16483966

申请日：2018-01-31

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert Niessner ,  Gisbert Michels ,  Shridhar Madhav ,  Kirit Gevaria ,  Kashyap Raval

IPC: C08L25/12 ,  C08L55/02 ,  C08L23/08 ,  C08K5/11 ,  C08K5/5435 ,  C08J7/043 ,  B05D3/12 ,  C08J3/20 ,  C08L33/18

CPC classification number: C08L25/12 ,  B05D3/12 ,  C08J3/203 ,  C08J7/043 ,  C08K5/11 ,  C08K5/5435 ,  C08L33/18 ,  C08L55/02 ,  C08J2325/12 ,  C08J2333/20 ,  C08J2455/02 ,  C08J2483/04 ,  C08L2205/03 ,  C08L2207/324 ,  C08L25/12 ,  C08L55/02 ,  C08K5/11 ,  C08K5/5435 ,  C08L25/12 ,  C08L55/02 ,  C08L23/0869

Abstract: The invention relates to a polymer composition (P), comprising at least one acrylonitrile-butadiene-styrene copolymer (A) (ABS copolymer (A)), characterized in that the polymer composition (P) has a surface energy of >38 dyne/cm. The invention further relates to a process for painting a surface of a polymer moulded article comprising the polymer composition (P), wherein no pre-treatment of the surface of the polymer moulded article, such as primer coating, is required prior to the application of the paint.

公开(公告)号：US20230013793A1

公开(公告)日：2023-01-19

申请号：US17785182

申请日：2020-12-16

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Gisbert MICHELS ,  Roman HONEKER ,  Shridhar MADHAV ,  Kirit GEVARIA ,  Pankaj BHARADWAJ ,  Prabhat SINGH

IPC: C08F2/22 ,  C08F253/00 ,  C08F4/40 ,  C08F279/04 ,  C08L25/12 ,  C08L55/02

Abstract: An emulsion polymerization process for preparation of ABS graft copolymer latex having reduced residual monomer content, wherein a grafting step c) comprises the steps: c1): feeding of 10 to 45 wt.-% of styrene and acrylonitrile in one portion to agglomerated butadiene rubber latex and addition of redox system initiator, then polymerization; c2): feeding remaining monomers in portions or continuously and further addition of redox system initiator; c3): addition of inorganic free radical initiator and continuation of polymerization, leads to ABS graft copolymers and thermoplastic molding compositions which can be used in the automotive industry.

公开(公告)号：US11549008B2

公开(公告)日：2023-01-10

申请号：US16627447

申请日：2018-07-03

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Felix Rattay

IPC: C08L25/12 ,  C08L51/04 ,  C08K5/00 ,  C08K3/22 ,  C08K5/3432

Abstract: Thermoplastic resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one pigment B, (c) at least one hindered amine UV light stabilizer C, and (d) optionally further polymer additives D, other than components B and C, wherein the UV stabilizing component(s) present in the thermoplastic resin are only hindered amine UV light stabilizer(s) C.

公开(公告)号：US20230002608A1

公开(公告)日：2023-01-05

申请号：US17781603

申请日：2020-12-02

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Nils WITTENBERG ,  Norbert NIESSNER ,  Michiel VERSWYVEL

IPC: C08L55/02 ,  C08L53/02 ,  C08L51/04 ,  C08L25/12

Abstract: The invention relates to thermoplastic molding compositions (T) comprising 10 to 99% by weight, based on the total weight of the molding composition (T), of at least one type of recycled polymer material (A), containing 20 to 100% by weight, based on recycled material (A), of recycled acrylonitrile-butadiene-styrene copolymer (A1); up to 80% by weight of at least one recycled styrene-acrylonitrile copolymer (A2); up to 10% by weight of recycled polymeric impurities (A3), different from (A1) and (A2); 0.1 to 30% by weight, based on the total weight of the molding composition (T), of at least one graft copolymer (B), different from (A); 0.1 to 18% by weight, based on the molding composition (T), of block copolymer (C); and optionally up to 89.8% by weight of further polymer component (D), different from (A), (B) and (C); optionally up to 30% by weight of filler and/or reinforcing agent (E); and optionally up to 30% by weight of further additive (F).

公开(公告)号：US20220332872A1

公开(公告)日：2022-10-20

申请号：US17633725

申请日：2020-08-20

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Gisbert MICHELS ,  Janna MICHAELIS DE VASCONCELLOS ,  Shridhar MADHAV ,  Kirit GEVARIA ,  Pratik BHAVSAR ,  SangJun AHN

IPC: C08F257/02 ,  C08L9/10 ,  C08F2/22 ,  C08F265/08 ,  C08F6/22

Abstract: A thermoplastic molding composition comprising (A) 15 to 45 wt.-% graft copolymer (A) obtained by emulsion polymerization of styrene and acrylonitrile in presence of an agglomerated butadiene rubber latex (A1) with D50 of 150 to 800 nm; (B) 40 to 75 wt.-% copolymer (B) of styrene and acrylonitrile having a weight ratio of 80:20 to 65:35 and Mw of 150,000 to 300,000 g/mol, (C) 2.0 to 5.0 wt.-% elastomeric block copolymer (C) made from 15 to 65 wt.-% diene, and 35 to 85% by weight vinylaromatic monomer; (D) 2.0 to 5.0 wt.-% titanium dioxide pigment D comprising at least 95 wt.-% titanium dioxide and 1.7 to 3.3 wt.-% alumina; and (E) 0 to 7.0 wt.-% of at least one additive/processing aid (E) different from (D); having a high chemical resistance, high color and thermal stability and low tendency to delamination. This can be used for sheet extrusion and thermoforming, in particular as inner liner for a cooling apparatus.

公开(公告)号：US20220168948A1

公开(公告)日：2022-06-02

申请号：US17277486

申请日：2019-09-18

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Bianca WILHELMUS ,  Norbert NIESSNER

IPC: B29C64/153 ,  B33Y70/00

Abstract: The present invention relates to a process for producing a three-dimensional component by means of selective laser sintering (SLS), wherein a processing temperature Tx is established in a build chamber, and a powder layer consisting of a thermoplastic polymer powder is provided in the build chamber. The thermoplastic polymer powder comprises a blend of a semicrystalline polymer, an amorphous polymer and a polymeric compatibilizer. The polymer powder is then melted in a spatially resolved manner by means of a directed beam of electromagnetic radiation, wherein binding of the regions of the melted and resolidified polymer layer by layer in multiple steps affords a three-dimensional component. In the process of the invention, the temperature in the build chamber during the performance of the individual steps varies by not more than +/−10% from the processing temperature Tx set. In addition, the processing temperature Tx differs by not more than +/−20 K from the processing temperature Tx(A) of a polymer powder comprising the corresponding semicrystalline polymer as the sole polymeric component.

公开(公告)号：US11274198B2

公开(公告)日：2022-03-15

申请号：US16632914

申请日：2018-07-25

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Norbert Niessner ,  Hans-Werner Schmidt ,  Tristan Kolb ,  Sascha Ehlert ,  Stephan Foerster

IPC: C08L25/08 ,  C08K3/013 ,  C08F212/08 ,  C08F220/18 ,  C08F220/44 ,  C08F222/06 ,  C08K3/22 ,  C08K5/00 ,  C08L67/00 ,  C08L83/04 ,  C08L83/10 ,  B82Y30/00 ,  B82Y40/00

Abstract: A scratch-resistant thermoplastic polymer composition (P) comprising 40 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 20 wt.-% of at least one inorganic metal compound nanoparticle, and optionally at least one polymeric compatibilizing agent, at least one modified polysiloxane compound, at least one colorant, dye or pigment, and/or at least one further additive has improved scratch properties.

公开(公告)号：US11225571B2

公开(公告)日：2022-01-18

申请号：US16633362

申请日：2018-07-25

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Norbert Niessner ,  Eike Jahnke ,  Hans-Werner Schmidt ,  Tristan Kolb

IPC: C08L25/14 ,  C08L23/08 ,  C08L25/12 ,  C08L91/06 ,  C08L25/16 ,  C08K3/32 ,  C08K3/013

Abstract: Thermoplastic polymer compositions (P) comprising 90 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 10 wt.-% of at least one copolymer at least comprising repeating units derived from at least one α-olefin monomer and at least one vinyl-aromatic monomer, at least one inorganic phosphate compound, at least one polyolefin wax and optionally at least one colorant, dye or pigment, and/or at least one further additive show improved properties with respect to residual gloss after abrasion combined with improved melt flow characteristics while heat resistance is not affected.

公开(公告)号：US11220598B2

公开(公告)日：2022-01-11

申请号：US16461974

申请日：2017-11-15

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran

IPC: C08L53/02 ,  C08F297/04 ,  C08G83/00 ,  C08L25/14

Abstract: Polymer composition comprising (a) 33 to 52 wt.-% star-shaped block copolymers (a) comprising terminal vinylaromatic polymer blocks S1 and S2, and random styrene/butadiene copolymer blocks (B/S); and (b) 48 to 67 wt.-% SMMA copolymers (b). Moldings and shaped articles produced thereof have a high clarity and toughness and can be used in the household, appliance and healthcare sector.