公开(公告)号：ZA201802651B

公开(公告)日：2021-09-29

申请号：ZA201802651

申请日：2018-04-20

Applicant: SENNICS CO LTD

Inventor： GUO XIANGYUN ,  XING JINGUO ,  RUAN XIAOMIN ,  CHEN XINMIN

Abstract: A preparation method for an aryl substituted p-phenylenediamine substance is provided. A structural formula of the aryl substituted p-phenylenediamine substance is shown as Formula (I'), where R" is phenyl or o-methylphenyl, and R' is the same as or different from R"; and the preparation method comprises that: a raw material A and a raw material B are reacted in the presence of a hydrogen acceptor and a catalyst to form the aryl substituted p-phenylenediamine substance, the raw material A having a structure shown as Formula (I), the raw material B being cyclohexanone and/or o-methylcyclohexanone and the hydrogen acceptor being a hydrogen acceptor capable of accepting hydrogen for conversion into the raw material B. The raw materials are low in cost and readily available, and use of a large amount of water for posttreatment of reaction is avoided. A reaction condition is relatively mild, and corrosion to reaction equipment is avoided.

公开(公告)号：CL2020003201A1

公开(公告)日：2021-04-30

申请号：CL2020003201

申请日：2020-12-10

Applicant: SENNICS CO LTD

Inventor： GAO YANG ,  ZOU BIAO

IPC: C07C211/54 ,  C08K5/17 ,  C08L21/00

Abstract: Se proporciona un antidegradante de caucho novedoso y de acción prolongada, así como una composición de caucho que lo comprende para neumáticos. El antidegradante comprende al menos dos compuestos, cada uno de los cuales se selecciona de un compuesto de Fórmula I, II, III-a o III-b: y cada uno de los compuestos tiene fórmulas diferentes a los demás, y no pueden ser compuestos de Fórmula III-a y III-b al mismo tiempo cuando el antidegradante consta de sólo 2 compuestos. El antidegradante se usa para proporcionar una composición de caucho con una resistencia mejorada a largo plazo al envejecimiento termo-oxidativo y al envejecimiento por ozono.

公开(公告)号：RS61329B1

公开(公告)日：2021-02-26

申请号：RSP20201591

申请日：2016-01-11

Applicant: SENNICS CO LTD

Inventor： GUO XIANGYUN ,  XING JINGUO ,  RUAN XIAOMIN ,  CHEN XINMIN

IPC: C07C209/68 ,  C07C209/60 ,  C07C211/54

公开(公告)号：CA3002688C

公开(公告)日：2021-01-26

申请号：CA3002688

申请日：2016-01-11

Applicant: SENNICS CO LTD

Inventor： GUO XIANGYUN ,  XING JINGUO ,  RUAN XIAOMIN ,  CHEN XINMIN

IPC: C07C211/55 ,  C07C209/60

Abstract: A preparation method for an aryl substituted p-phenylenediamine substance is provided. A structural formula of the aryl substituted p-phenylenediamine substance is shown as Formula (I'), where R" is phenyl or o-methylphenyl, and R' is the same as or different from R"; and the preparation method comprises that: a raw material A and a raw material B are reacted in the presence of a hydrogen acceptor and a catalyst to form the aryl substituted p-phenylenediamine substance, the raw material A having a structure shown as Formula (I), the raw material B being cyclohexanone and/or o-methylcyclohexanone and the hydrogen acceptor being a hydrogen acceptor capable of accepting hydrogen for conversion into the raw material B. According to the preparation method, the raw materials are low in cost and readily available, and use of a large amount of water for posttreatment of reaction is avoided. Moreover, a reaction condition is relatively mild, and corrosion to reaction equipment is avoided. Therefore, the preparation method is environment-friendly and less in pollution, and may achieve better economic benefits.

公开(公告)号：PT3366666T

公开(公告)日：2021-01-14

申请号：PT16856546

申请日：2016-01-11

Applicant: SENNICS CO LTD

IPC: C07C211/55 ,  C07C209/60

公开(公告)号：AU2016343321B2

公开(公告)日：2019-03-14

申请号：AU2016343321

申请日：2016-01-11

Applicant: SENNICS CO LTD

Inventor： GUO XIANGYUN ,  XING JINGUO ,  RUAN XIAOMIN ,  CHEN XINMIN

IPC: C07C211/55 ,  C07C209/60

Abstract: A preparation method for an aryl-substituted p-phenylenediamine substance is provided. The structural formula of the aryl-substituted p-phenylenediamine substance is as follows, wherein R'' is phenyl or o-methylphenyl, and R' and R'' are identical or different. The preparation method comprises: raw material A and raw material B reacting under the action of a hydrogen acceptor and a catalyst to form an aryl-substituted p-phenylenediamine substance. The structural formula of raw material A is as follows; raw material B is cyclohexanone and/or o-methylcyclohexanone; and the hydrogen acceptor is a hydrogen acceptor that can be hydroconverted into raw material B. The preparation method uses inexpensive and readily available raw materials, and does not need a large amount of water in the post-treatment of the reaction. The reaction has mild conditions and does not corrode reaction devices. Therefore, the preparation method is environmentally friendly, has less pollution and can help gain more economic benefit.

公开(公告)号：PE13732018A1

公开(公告)日：2018-08-28

申请号：PE0005642018

申请日：2016-01-11

Applicant: SENNICS CO LTD

Inventor： GUO XIANGYUN ,  XING JINGUO ,  RUAN XIAOMIN ,  CHEN XINMIN

IPC: C07C211/55 ,  C07C209/60

CPC classification number: C07C209/60 ,  C07C209/68 ,  C07C211/55 ,  C07C2523/38 ,  C07C2601/16 ,  C07C211/54

Abstract: SE REFIERE A UN METODO DE PREPARACION DE UNA SUSTANCIA DE P-FENILENDIAMINA SUSTITUIDA CON ARILO DE FORMULA (i) DONDE R'' ES FENILO U O-METILFENILO, Y R' ES EL MISMO O DIFERENTE A R''; EN DONDE DICHO METODO DE PREPARACION COMPRENDE: HACER REACCIONAR UNA MATERIA PRIMA A CON UNA MATERIA PRIMA B EN PRESENCIA DE UN ACEPTOR DE HIDROGENO Y UN CATALIZADOR PARA FORMAR LA SUSTANCIA DE P-FENILENDIAMINA SUSTITUIDA CON ARILO, LA MATERIA PRIMA A TIENE UNA ESTRUCTURA DE FORMULA (I), LA MATERIA PRIMA B ES CICLOHEXANONA U O-METILCICLOHEXANONA Y EL ACEPTOR DE HIDROGENO TIENE LA CAPACIDAD DE ACEPTAR HIDROGENO PARA LA CONVERSION A LA MATERIA PRIMA B

公开(公告)号：SG11201803239PA

公开(公告)日：2018-05-30

申请号：SG11201803239P

申请日：2016-01-11

Applicant: SENNICS CO LTD

Inventor： GUO XIANGYUN ,  XING JINGUO ,  RUAN XIAOMIN ,  CHEN XINMIN

IPC: C07C209/60 ,  C07C211/55

Abstract: A preparation method for an aryl substituted p-phenylenediamine substance is provided. A structural formula of the aryl substituted p-phenylenediamine substance is shown as Formula (I'), where R" is phenyl or o-methylphenyl, and R' is the same as or different from R"; and the preparation method comprises that: a raw material A and a raw material B are reacted in the presence of a hydrogen acceptor and a catalyst to form the aryl substituted p-phenylenediamine substance, the raw material A having a structure shown as Formula (I), the raw material B being cyclohexanone and/or o-methylcyclohexanone and the hydrogen acceptor being a hydrogen acceptor capable of accepting hydrogen for conversion into the raw material B. The raw materials are low in cost and readily available, and use of a large amount of water for posttreatment of reaction is avoided. A reaction condition is relatively mild, and corrosion to reaction equipment is avoided.

公开(公告)号：AU2016343321A1

公开(公告)日：2018-05-17

申请号：AU2016343321

申请日：2016-01-11

Applicant: SENNICS CO LTD

Inventor： GUO XIANGYUN ,  XING JINGUO ,  RUAN XIAOMIN ,  CHEN XINMIN

IPC: C07C211/55 ,  C07C209/60

Abstract: A preparation method for an aryl-substituted p-phenylenediamine substance is provided. The structural formula of the aryl-substituted p-phenylenediamine substance is as follows, wherein R'' is phenyl or o-methylphenyl, and R' and R'' are identical or different. The preparation method comprises: raw material A and raw material B reacting under the action of a hydrogen acceptor and a catalyst to form an aryl-substituted p-phenylenediamine substance. The structural formula of raw material A is as follows; raw material B is cyclohexanone and/or o-methylcyclohexanone; and the hydrogen acceptor is a hydrogen acceptor that can be hydroconverted into raw material B. The preparation method uses inexpensive and readily available raw materials, and does not need a large amount of water in the post-treatment of the reaction. The reaction has mild conditions and does not corrode reaction devices. Therefore, the preparation method is environmentally friendly, has less pollution and can help gain more economic benefit.

公开(公告)号：AU2015411254A1

公开(公告)日：2018-05-17

申请号：AU2015411254

申请日：2015-11-02

Applicant: SENNICS CO LTD

Inventor： CHEN XINMIN ,  WU LIBAO ,  SHI SONG ,  GAO SHANG

IPC: C07D277/72

Abstract: The present invention discloses a preparation method of 2-mercaptobenzothiazole, in which an aniline process is employed to react under the action of a catalyst to prepare 2-mercaptobenzothiazole, and the catalyst comprises imidazolium ionic liquid-supported sulfonic acids. The imidazolium ionic liquid-supported sulfonic acids are a type of acidic functionalized ionic liquids, and have the advantages of both solid acids and liquid acids. By employing the imidazolium ionic liquid-supported sulfonic acids as an active component of the catalyst, the present invention can significantly improve the conversion of raw materials and the yield of 2-mercaptobenzothiazole. At the same time, since 2-mercaptobenzothiazole has the characteristics of high catalytic activity, zero volatility, low corrosiveness, superior thermal stability, etc., the above preparation method also has comprehensive advantages of process simplicity, a low cost, a low tar yield, and high environmental friendliness.