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    FABRICATION OF ISOLATED NANOSTRUCTURES AND/OR ARRAYS OF NANOSTRUCTURES
    51.
    发明申请
    FABRICATION OF ISOLATED NANOSTRUCTURES AND/OR ARRAYS OF NANOSTRUCTURES 审中-公开
    隔离纳米结构的制造和/或纳米结构的阵列

    公开(公告)号：WO2008018923A3

    公开(公告)日：2008-07-10

    申请号：PCT/US2007007101

    申请日：2007-03-22

    Applicant: HARVARD COLLEGE ,  XU QIAOBING ,  BAO JIMING ,  CAPASSO FEDERICO ,  WHITESIDES GEORGE M

    Inventor： XU QIAOBING ,  BAO JIMING ,  CAPASSO FEDERICO ,  WHITESIDES GEORGE M

    IPC: G02B5/18

    CPC classification number: B81C1/00031 ,  B08B17/065 ,  B82Y20/00 ,  B82Y30/00 ,  G01N21/658 ,  G02B2207/101

    Abstract: Methods for fabricating nanostructures and articles associated therewith are described. In some embodiments, an isolated nanostructure (e.g., a metal nanowire) or an array of nanostructures can be fabricated by depositing a material (e.g., a metal) on a surface having a plurality of protrusions or indentations. At least a portion of the deposited material may be embedded in an encapsulating material, and the encapsulating material can be cut, for instance, to form a thin slice that includes the deposited material at least partially embedded therein. In some instances, the slice can be positioned on a surface in a desired arrangement. The encapsulating material can be removed from the surface to form one or more isolated nanostructures of the deposited material. Advantageously, dimensions of the nanostructures can be controlled to, e.g., 15 run, to form nanostructures having a variety of shapes and geometries (e.g., wires, rings, and cylinders). Nanostructures can also be formed in a variety of materials, including metals, ceramics, and polymers. In addition, nanostructures can also be fabricated over large areas (e.g., greater than 1 mm 2 ). In some cases, these nanostructures are positioned in association with other components, e.g., to form a functional component of a device.

    Abstract translation: 描述了制造与其相关的纳米结构和制品的方法。 在一些实施方案中，可以通过在具有多个突起或凹陷的表面上沉积材料（例如金属）来制造分离的纳米结构（例如，金属纳米线）或纳米结构阵列。 沉积材料的至少一部分可以嵌入到封装材料中，并且可以切割封装材料，例如，以形成薄片，其包括至少部分地嵌入其中的沉积材料。 在一些情况下，切片可以以期望的布置位于表面上。 封装材料可以从表面去除以形成沉积材料的一个或多个分离的纳米结构。 有利地，纳米结构的尺寸可以被控制为例如15次，以形成具有各种形状和几何形状（例如，线，环和圆柱体）的纳米结构。 纳米结构也可以以各种材料形成，包括金属，陶瓷和聚合物。 此外，纳米结构也可以在大面积上制造（例如，大于1mm 2）。 在一些情况下，这些纳米结构与其它组分相关联地定位，例如以形成器件的功能组件。

    PATTERNING OF IONOTROPIC POLYMERS
    52.
    发明申请
    PATTERNING OF IONOTROPIC POLYMERS 审中-公开
    离子聚合物的构图

    公开(公告)号：WO2008051432A2

    公开(公告)日：2008-05-02

    申请号：PCT/US2007/022219

    申请日：2007-10-18

    Applicant: PRESIDENT AND FELLOWS OF HARVARD COLLEGE ,  LAHAV, Michal ,  WINKLEMAN, Adam ,  NAROVLYANSKY, Max ,  PEREZ-CASTILLEJOS, Raquel ,  WEISS, Emily, A. ,  RODRIGUEZ, Leonard, N. J. ,  WHITESIDES, George, M.

    Inventor： LAHAV, Michal ,  WINKLEMAN, Adam ,  NAROVLYANSKY, Max ,  PEREZ-CASTILLEJOS, Raquel ,  WEISS, Emily, A. ,  RODRIGUEZ, Leonard, N. J. ,  WHITESIDES, George, M.

    IPC: G03F7/00

    CPC classification number: G03F7/0002 ,  B82Y10/00 ,  B82Y40/00 ,  Y10T428/24479

    Abstract: In one aspect, methods of patterning of thin films of an ionotropic polymer (e.g., poly(acrylic acid)) are provided. These processes can create micron or sub-micron-scale patterns of ionotropic polymers such as cation crosslinked poly(acrylic acid) (CCL- PAA). In one embodiment, patterning may be performed within microfluidic channels by flowing a solution of crosslinking agent (e.g., metal cations such as Ag + , Ca 2+ , Pd 2+ , Al 3+ , La 3+ , and Ti 4+ ) that can crosslink a portion of an ionotropic polymer in contact with the solution. In another embodiment, methods of patterning ionotropic polymers involve photolithography. Upon patterning a positive photoresist (e.g., diazonaphthoquinone- novolac resin) on a film of CCL-PAA, the exposed regions of CCL-PAA can be etched by an aqueous solution. Advantageously, the patterned, crosslinked polymer may also serve as both a reactant and a matrix for subsequent chemistry. For example, in some embodiments, the initial crosslinking cation can be exchanged for a second cation that could not be patterned photolithographically. Patterned films of CCL-PAA can also be used to host and template the reduction of metallic cations to metallic nanoparticles, and to fabricate porous, low-k dielectric substrates.

    Abstract translation: 一方面，提供了离子型聚合物（例如聚（丙烯酸））的薄膜图案化方法。 这些方法可以产生离子型聚合物如阳离子交联的聚（丙烯酸）（CCL-PAA）的微米级或亚微米级的图案。 在一个实施方案中，可以通过使交联剂溶液（例如，金属阳离子如Ag 2+，Ca 2+，Pd 2+， 2+，3+，3+，3+，和3++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ 与溶液接触。 在另一个实施方案中，构图离子型聚合物的方法涉及光刻。 在CCL-PAA膜上形成正性光致抗蚀剂（例如重氮萘酚 - 酚醛清漆树脂）之后，CCL-PAA的曝光区域可以通过水溶液进行蚀刻。 有利地，图案化的交联聚合物也可以用作反应物和用于后续化学的基质。 例如，在一些实施方案中，可以将初始交联阳离子交换为不能光刻图案化的第二阳离子。 CCL-PAA的图案化膜也可用于将金属阳离子还原为金属纳米颗粒，并制备多孔，低k电介质基底。

    MICROFLUIDIC DEVICES FOR MULTIPLEXED ELECTROCHEMICAL DETECTION
    60.
    发明申请
    MICROFLUIDIC DEVICES FOR MULTIPLEXED ELECTROCHEMICAL DETECTION 审中-公开
    用于多重电化学检测的微流体装置

    公开(公告)号：WO2013036617A1

    公开(公告)日：2013-03-14

    申请号：PCT/US2012/053930

    申请日：2012-09-06

    Applicant: PRESIDENT AND FELLOWS OF HARVARD COLLEGE ,  WHITESIDES, George, M. ,  LI, Xiujun ,  DEISS, Frederique ,  NIE, Zhihong ,  LIU, Xinyu

    Inventor： WHITESIDES, George, M. ,  LI, Xiujun ,  DEISS, Frederique ,  NIE, Zhihong ,  LIU, Xinyu

    IPC: B01L3/00

    CPC classification number: G01N27/416 ,  B01L3/502707 ,  B01L3/502738 ,  B01L2300/0645 ,  B01L2300/0825 ,  G01N27/3272

    Abstract: The multiplexed electrochemical microfluidic paper-based analytical device comprises multiple detection zones for the detection of multiple biochemical analytes from one single sample. Cavity valves integrated on the device will deliver the sample to different detection zones. These analytes include, but are not limited to, urea, creatinine, creatine, glucose, lactate, ethanol, uric acid, cholesterol, pyruvate, creatinine, β-hydroxybutyrate, alanine aminotrasferase, aspartate aminotransferase, alkaline phosphatase, and acetylcholinesterase (or its inhibitors). This system will provide a simple and low-cost POC approach to obtain quantitative and multiple biological information from one sample (e.g. one drop of blood).

    Abstract translation: 复用的电化学微流体纸基分析装置包括多个检测区域，用于检测来自一个单个样品的多种生化分析物。 集成在设备上的腔阀将样品传送到不同的检测区域。 这些分析物包括但不限于尿素，肌酸酐，肌酸，葡萄糖，乳酸，乙醇，尿酸，胆固醇，丙酮酸，肌酸酐，β-羟基丁酸，丙氨酸氨基转酪酶，天冬氨酸氨基转移酶，碱性磷酸酶和乙酰胆碱酯酶（或其抑制剂 ）。 该系统将提供简单且低成本的POC方法，从一个样品（例如一滴血液）获得定量和多种生物信息。

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