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公开(公告)号：KR101443209B1
公开(公告)日：2014-09-22
申请号：KR1020130097074
申请日：2013-08-16
Applicant: 한국에너지기술연구원
IPC: H01M8/18
CPC classification number: Y02E60/528 , H01M8/18
Abstract: The present invention relates to a redox flow battery, and more particularly, provides a redox flow battery including: a stack in which positive electrode cells, separators, and negative electrode cells are repeatedly stacked from bipolar plates, and a bipolar plate, a collector, and an end plate are sequentially disposed on an outer side of each of the outermost positive electrode cell and the outermost negative electrode cell; a positive electrode electrolyte tank that stores positive electrode electrolyte to be supplied to the positive electrode cells; and a negative electrode electrolyte tank that stores negative electrode electrolyte to be supplied to the negative electrode cells. The positive and negative electrode electrolyte tanks include: an outflow pipe arrangement for transferring electrolyte to the stack; an inflow pipe arrangement for receiving the electrolyte from the stack; and an electrolyte injection hole for injecting electrolyte, introduced into the positive and negative electrode electrolyte tanks, to the inside of the redox flow battery. Thus, electrolyte after redox is uniformly injected into an electrolyte tank is thus efficiently mixed with electrolyte remaining the electrolyte tank and is then returned to a stack, to prevent charging capacity and energy efficiency from being reduced by overvoltage, thereby improving a battery performance.
Abstract translation: 氧化还原液流电池技术领域本发明涉及一种氧化还原液流电池，更具体地说，提供了一种氧化还原液电池，包括：其中正极电池，隔板和负极电池从双极板反复堆叠的叠层，以及双极板，集电体， 并且端板依次设置在最外侧正极电池单元和最外侧负极单元的外侧上; 正极电解槽，其储存供给正极单元的正极电解液; 以及负极电解槽，其储存供给负极单元的负极电解液。 正极和负极电解质罐包括：用于将电解质转移到堆叠的流出管装置; 用于从堆叠中接收电解质的流入管装置; 以及用于将引入正极和负极电解质槽的电解质注入氧化还原液流电池内部的电解液注入孔。 因此，将氧化还原后的电解质均匀地注入到电解槽中，由此与电解液保持电解质槽有效地混合，然后返回堆叠，以防止充电能力和能量效率被过电压降低，从而提高电池性能。
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公开(公告)号：KR101423944B1
公开(公告)日：2014-08-14
申请号：KR1020120123761
申请日：2012-11-02
Applicant: 한국에너지기술연구원
IPC: H01M4/583 , H01M4/1393 , H01M10/052
CPC classification number: C01B31/10 , C01B32/336 , H01M4/0471 , H01M4/587 , H01M10/052 , Y10T29/49108
Abstract: 본 발명은 카바이드 유도 탄소 기반 음극 활물질 제조방법에 관한 것으로, 카바이드 유도 탄소를 제조하는 단계; 및 상기 카바이드 유도 탄소의 기공을 확장하는 단계를 포함한다.
이때, 기공을 확장하는 단계는 제조된 카바이드 유도 탄소를 공기 중에서 가열하는 활성화 공정으로 수행되는 것이 좋다.
본 발명은, 제조 단계에서 활성화 공정을 부가함으로써, 카바이드 유도 탄소 내에 형성된 기공을 확장할 수 있는 효과가 있다.
또한, 기공이 확장된 카바이드 유도 탄소를 음극활물질로 적용함으로써 충방전 효율이 향상된 리튬 이차전지를 제조할 수 있는 효과가 있다.-
公开(公告)号：KR101394255B1
公开(公告)日：2014-05-13
申请号：KR1020120148047
申请日：2012-12-18
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/528 , H01M8/18 , H01M8/04 , H01M8/24
Abstract: The present invention relates to a redox flow battery and an operating method, and according to the present invention, a catholyte tank and an anolyte tank are located higher than the position on which a stack is placed; a part of an electrolyte inside the stack is collected to be stored in an electrolyte tank, thereby preventing a countercurrent and self-discharge of the electrolyte during non-operation; and especially, nitrogen is flowed into the redox flow battery to prevent a drying phenomenon of a separation membrane induced by electrolyte insufficiency, thereby obtaining the effect of preventing a decrease in durability of the redox flow battery.
Abstract translation: 本发明涉及一种氧化还原液流电池及其操作方法，根据本发明，阴极电解液罐和阳极电解液罐的位置高于放置叠层的位置; 将堆叠内的电解质的一部分收集储存在电解槽中，从而防止电解液在不操作时的逆流和自放电; 特别是氮气流入氧化还原液电池中，以防止由电解质不足引起的分离膜的干燥现象，从而获得防止氧化还原液流电池的耐久性降低的效果。
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公开(公告)号：KR101353961B1
公开(公告)日：2014-01-23
申请号：KR1020120124318
申请日：2012-11-05
Applicant: 한국에너지기술연구원
IPC: H01M8/18
CPC classification number: Y02E60/528 , H01M8/18
Abstract: The present invention relates to a stack structure of an electrochemical flow cell and a redox flow battery including the same and, more specifically, to a a stack structure of an electrochemical flow cell and a redox flow battery including a frame which includes an instrument for both connecting and disconnecting and a manifold complex built up with a plurality of manifold unit modules which includes a felt electrode ensconced on the frame. Since adjusting the surface area of voltage and current according to the number of manifold unit module is possible, a user is able to secure the power output desired for the specifications and individual split and merge is easy so that a simple modification or replacement of partial unit modules is possible.
Abstract translation: 本发明涉及一种电化学流动池和包含该电池的氧化还原液流电池的堆叠结构，更具体地说，涉及一种电化学流动池和包括框架的氧化还原液流电池的堆叠结构，该框架包括用于两个连接 以及与多个歧管单元模块构成的歧管复合体，其包括被固定在框架上的毡电极。 由于可以根据歧管单元模块的数量调整电压和电流的表面积，所以用户能够确保规格所需的功率输出，并且易于分离和合并，从而简单地修改或更换部分单元 模块是可能的。
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公开(公告)号：KR101291753B1
公开(公告)日：2013-07-31
申请号：KR1020120094334
申请日：2012-08-28
Applicant: 한국에너지기술연구원
CPC classification number: H01M8/188 , H01M8/0258 , H01M8/026 , H01M8/20 , H01M8/241 , H01M8/2483 , H01M8/2484 , Y02E60/528
Abstract: PURPOSE: A manifold for redox flow batteries is provided to prevent the flow of liquid electrolyte existing in a stack or pipe when the operation of a pump is stopped, thereby inhibiting the generation of shunt current. CONSTITUTION: A manifold for redox flow batteries comprises a first electrode electrolyte inlet (140) and a first electrode electrolyte outlet (141) for flowing in and out of the first electrode electrolyte; a first electrode electrolyte reaction part (120) formed inside; a supply path (160) for supplying the first electrode electrolyte injected from the first electrode electrolyte inlet to the first electrode electrolyte reaction part; an exhaust flow path (161) for transferring and discharging the first electrode electrolyte to the first electrode electrolyte outlet; and a second electrode electrolyte inlet (150) and a second electrode electrolyte outlet (151) for transferring a second electrode electrolyte.
Abstract translation: 目的：提供氧化还原液流电池的歧管，以防止泵的运行停止时存在于堆叠或管道中的液体电解质的流动，从而抑制分流电流的产生。 构成：用于氧化还原液流电池的歧管包括用于流入和流出第一电极电解质的第一电极电解质入口（140）和第一电极电解质出口（141） 在内部形成的第一电极电解质反应部（120） 用于将从第一电极电解质入口注入的第一电极电解质供应到第一电极电解质反应部分的供给路径（160） 用于将第一电极电解质转移和排出到第一电极电解质出口的排气流路（161） 和用于转移第二电极电解质的第二电极电解质入口（150）和第二电极电解质出口（151）。
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Patent Agency Ranking
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公开(公告)号：KR101760078B1
公开(公告)日：2017-07-21
申请号：KR1020150121151
申请日：2015-08-27
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/528
Abstract: 본발명은레독스흐름전지에관한것으로써, 특히, 스택의전단과후단사이에서전해액이주입되어, 스택전체에전해액을균일하게이송시킬수 있어서, 스택중앙부의압력강하를줄일수 있게되어, 과전압과과전류발생을최소화할수 있는레독스흐름전지에관한것이다.
Abstract translation: 作为本发明涉及的氧化还原液流电池，特别地，将电解液的前端和后端的堆叠之间注入，根据sikilsu电解质均匀地传递到整个堆栈，能够减少叠层的压降中央部，过电压和 本发明涉及一种氧化还原液流电池，可以最小化过电流发生。
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58.发明公开
公开(公告)号：KR1020170056941A
公开(公告)日：2017-05-24
申请号：KR1020150160433
申请日：2015-11-16
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/528
Abstract: 본발명은다공성고분자기재; 및상기다공성고분자기재의기공에함입된고분자전해질을포함하는레독스흐름전지용바나듐이온저투과성음이온이온교환막에있어서, 상기다공성고분자기재는공극부피가 70∼80%, 기공사이즈가 0.2∼0.6㎛, 두께가 70∼80㎛인다공성폴리비닐리덴플로라이드(polyvinylidene floride, PVDF) 막이며, 상기고분자전해질은, 양이온기를가지는 4가암모늄염의전해질단량체, 아크릴아미드계가교제및 개시제를포함하는용액을상기다공성고분자기재에함침시킨후 가교중합하여형성되는것을특징으로하는레독스흐름전지용바나듐이온저투과성음이온이온교환막에관한것으로서, 본발명에의한레독스흐름전지용바나듐이온저투과성음이온이온교환막은레독스흐름전지에있어서양극전해질및 음극전해질간에일어나는바나듐이온의크로스오버를최소화하여나피온(Nafion) 등과같은기존의상용이온교환막에비해에너지효율및 내구성이현저히개선된성능을가지는레독스흐름전지의제조에유용하게사용될수 있다.
Abstract translation: 本发明涉及一种多孔聚合物基材; 而在氧化还原液流电池，钒离子，其包括：在所述多孔聚合物基体材料的孔中引入的聚合物电解质阴离子渗透离子交换膜，所述多孔聚合物基体材料为70-80％的孔体积，孔径0.2〜0.6㎛， 吲唑厚度70〜80㎛的微孔聚偏二氟乙烯（聚偏二氟化物类，PVDF）膜，聚合物电解质，所述电解质4中，具有阳离子的铵盐的单体，其中所述含丙烯酰胺溶液和引发剂的多孔边界共融 涉及一种氧化还原液流电池，钒离子低渗透性阴离子交换膜，其特征在于，形成与聚合物基底材料结合的交联的，氧化还原液流电池的钒离子根据本发明，所述低渗透性阴离子交换膜的氧化还原液流电池浸渍 钒离子在正极和负极电解质之间的交叉可以被最小化， Jonui比商用离子交换膜可以是在生产的能源效率和所述氧化还原液流电池具有显着提高的耐久性能是有用的。
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59.发明公开층간 간격이 넓어진 환원 그래핀 산화물의 제조방법과 그에 따라 제조된 환원 그래핀산화물 및 이를 포함하는 슈퍼커패시터 有权制备具有较宽层间距的还原氧化石墨烯的方法，由此制备的还原氧化石墨烯以及超级电容器
公开(公告)号：KR1020170054941A
公开(公告)日：2017-05-18
申请号：KR1020150157725
申请日：2015-11-10
Applicant: 한국에너지기술연구원
Abstract: 본발명은슈퍼커패시터의효율을향상시키기위하여층간간격이넓어진환원그래핀산화물의제조방법에관한것으로, 흑연산화물을준비하는단계; 상기흑연산화물을동결건조하는단계; 동결건조된흑연산화물에대하여초음파처리를수행하는단계; 초음파처리된흑연산화물을하이드라진으로환원하여환원그래핀산화물을형성하는단계; 및상기환원그래핀산화물을가열하는열처리단계를포함하는것을특징으로한다. 본발명은, 흑연산화물을동결건조하고초음파처리한뒤에화학적으로환원하고환원된뒤에는열처리를수행함으로써, 층간간격이넓어진환원그래핀산화물을제조할수 있는효과가있다. 또한, 공정비용이저렴한화학적환원공정을적용하면서도층간간격이넓은환원그래핀산화물을제조할수 있는제조공정으로그래핀산화물을제조하여활물질로사용함으로써, 공정비용대비효율이크게향상된슈퍼커패시터를제공할수 있는효과가있다.
Abstract translation: 本发明涉及石墨烯氧化物的还原的制造方法的步骤拓宽了层间间隔，以改善的超级电容器的效率，制备氧化石墨; 冻干氧化石墨; 对冻干石墨氧化物进行超声波处理; 将经超声波处理的氧化石墨还原成肼以形成还原的氧化石墨烯; 以及加热还原的氧化石墨烯的热处理步骤。 本发明中，通过冷冻干燥该氧化石墨并进行超声波处理handwie化学热处理然后进行还原和降低的，更广泛的层间距减少所以存在能够制造销氧化物的效果。 此外，可以处理成本通过同时施加还原工艺制造过程夹层间距可准备大量还原的石墨烯氧化物是在制备用作活性材料的销氧化物提供一种廉价的化学，该过程的成本效率大大提高超级电容器 有一个效果。
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公开(公告)号：KR101720105B1
公开(公告)日：2017-03-28
申请号：KR1020150064535
申请日：2015-05-08
Applicant: 한국에너지기술연구원
IPC: H01M10/0562 , H01M12/08
CPC classification number: Y02E60/128
Abstract: 본발명은질화처리된고체전해질, 이의제조방법및 이를포함하는하이브리드리튬전지에관한것으로, 더욱상세하게는반응로내에고체전해질을위치시키고상기반응로내의온도를승온시키는승온단계, 상기승온단계후 상기반응로내에질소함유가스를주입하고열처리하는질화처리단계, 및상기질화처리단계후 불활성가스를주입하여상온까지온도를하강시키는냉각단계를고체전해질의표면에질화처리함으로써화학적안정성을증가시킨질화처리된고체전해질, 이의제조방법, 및이를적용한하이브리드리튬전지에관한것이다.
Abstract translation: 本发明后一直以来，并且更具体地，对温度上升步骤，将所述固体电解质的温度升高步骤中，将温度在混合锂电池所提出的反应器内反应器中的温度，包括渗氮处理的固体电解质，它们的制造和这种方法 氮化注入和热处理含氮到反应器中的气体，和硝化由氮化工序的氮化处理，以在固体电解质的表面之后注入的惰性气体的温度降低至室温的冷却步骤增加的化学稳定性， 处理后的固体电解质，其制造方法以及使用其的混合锂电池。
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