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公开(公告)号：KR101577431B1
公开(公告)日：2015-12-21
申请号：KR1020130162692
申请日：2013-12-24
Applicant: 한국화학연구원
Abstract: 본발명은다공성무기결정체합성용액의제조방법및 이를이용한다공성무기결정체제조방법에관한것으로, 구체적으로는알루미늄원료, 유기주형체및 물을혼합하여 1 내지 5시간동안교반하는단계(단계 1); 상기단계 1의혼합용액내로인 원료를 0.1 내지 1 ml/min의속도로첨가하면서교반하는단계(단계 2);를포함하며, 2알루미늄원료 : x인원료 : 2유기주형체 : zHO의몰비로혼합되고, 이때, x=1 내지 3, z=10 내지 300인것을특징으로하는투명하고균일한다공성무기결정체합성용액의제조방법을제공한다. 본발명에따른다공성무기결정체합성용액제조방법은특정조성인전구체들의혼합순서, 시간등을특정함으로써혼합용액상의원료물질들이완전히용해되거나또는과포화되어입자형태를띄지않거나입자가형성되더라도그 크기가매우작다. 따라서제조되는다공성무기결정체합성용액이투명하고균일하다. 또한, 본발명은다공성카본을상기투명하고균일한다공성무기결정체합성용액에침지시킴으로써나노크기의다공성무기결정체를균일하게형성할수 있는효과가있다.
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公开(公告)号：KR101511232B1
公开(公告)日：2015-04-17
申请号：KR1020140008231
申请日：2014-01-23
Applicant: 한국화학연구원
CPC classification number: B01D61/005 , B01D69/10 , B01D69/12 , B01D71/82 , C02F1/445
Abstract: 본발명은다공성지지체층; 상기다공성지지체일면에물리적또는화학적으로고정되고, 이온교환수지(Ion exchange resin), 금속산화물을포함하는불용성염(Insoluble salt) 및고분자전해질(Polyelectrolyte)로이루어지는군으로부터선택되는 1 종이상의삼투압을유발하는유도물질을포함하는유도물질층; 및상기유도물질층상에코팅된활성층;을포함하는것을특징으로하는유도물질내재형정삼투분리막을제공한다. 본발명에따르면, 삼투압을발생시키는유도물질이막에내장되어있으므로, 종래의방식과같이분리막을투과한투과용액이유도물질과혼합되지않아이를분리해내기위한유도용액재생장치를설치하지않을수 있다. 따라서공정상경제성이향상될수 있는효과가있다.
Abstract translation: 本发明提供一种其中具有诱导剂的正向渗透膜，其由多孔支撑体层构成; 诱导剂层物理或化学地固定在多孔支撑体层的一个表面上并含有一种或多种用于诱导渗透的诱导剂，所述诱导剂选自由用于诱导渗透的聚合物涂覆的颗粒，聚合物型离子液体， 离子交换树脂，包含金属氧化物的不溶性盐和聚电解质; 以及涂覆在诱导剂层上的活性层。 根据本发明，由于在膜中内部提供用于诱导渗透的诱导剂，因此以常规方法渗透通过膜的渗透溶液不与诱导剂混合，从而不需要提供诱导溶液再现装置 用于分离渗透的溶液。 因此，有可能提高过程的经济效益。
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公开(公告)号：KR1020150014718A
公开(公告)日：2015-02-09
申请号：KR1020130090301
申请日：2013-07-30
Applicant: 한국화학연구원
CPC classification number: B01D69/08 , B01D67/00 , B01D69/088 , B01D71/02
Abstract: 본 발명은 제1 세라믹 입자를 포함하는 제1 용액을 제조하는 단계(단계 1); 제2 세라믹 입자를 포함하는 제2 용액을 제조하는 단계(단계 2); 상기 단계 1 및 2에서 제조된 용액들과, 내부응고제를 삼중노즐을 통해 외부응고조로 동시에 방사하여 중공사막 전구체를 제조하는 단계(단계 3); 및 상기 단계 3에서 제조된 중공사막 전구체를 열수처리 및 소결시키는 단계(단계 4);를 포함하는 다공성 중공사막의 제조방법을 제공한다. 본 발명에 따른 다공성 중공사막의 제조방법은 세라믹 전구체를 사용하여 연속적인 습식 방사를 통한 상전이 공정을 통해 제조함으로써, 제조공정을 단일화시켜 중공사막의 생산 속도가 느린 문제점을 해결하여 대량생산이 가능한 효과가 있으며, 본 발명에 따른 제조방법으로 제조된 다공성 중공사막은 분리활성층의 치밀한 기공으로 배제율이 높고, 지지층으로 인해 우수한 기계적 강도를 가지는 효과가 있다.
Abstract translation: 本发明涉及一种多孔中空纤维膜的制备方法，包括：制备包含第一陶瓷颗粒的第一溶液（步骤1）的步骤; 制备包括第二陶瓷颗粒的第二溶液的步骤（步骤2）; 同时将在步骤1和2中制备的溶液和通过三重喷嘴的内部凝结剂同时喷射到外部凝结剂槽的步骤，并制备中空纤维膜前体（步骤3）。 以及通过加热水分处理在步骤3中制备的中空纤维膜前体并烧结它的步骤（步骤4）。 根据本发明，多孔中空纤维膜的制造方法使用陶瓷前体和通过连续湿纺法的相变过程，统一制造工序，解决制造速度低的问题，从而使批量生产成为可能。 通过本发明的制备方法制备的多孔中空纤维膜由于分离活化层的紧密孔和由于支撑层引起的优异的机械强度而具有高消除率。
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公开(公告)号：KR1020140035665A
公开(公告)日：2014-03-24
申请号：KR1020120102197
申请日：2012-09-14
Applicant: 한국화학연구원
CPC classification number: B01D63/02 , B01D61/147 , B01D69/08 , B01D71/06 , B01D2257/2066 , C01B7/19 , Y02C20/30
Abstract: A purpose of the present invention is to provide a device for enriching and recovering the fluorinated gas using a separating membrane, and a method to enrich and recover fluorinated gas using the device. The device for enriching the fluorinated gas comprises a gas supplying unit which supplies mixed gas including fluorinated gas; an enriching unit which has one or more separating membrane modules separating the fluorinated gas from the mixed gas by having an inlet through which mixed gas is injected from the supplying unit, the separating membrane separating the fluorinated gas, a penetration hole through which non-fluorinated gas separated from the fluorinated gas by the separating membrane is discharged, and an outlet through which the fluorinated gas is discharged; a decompression pump providing driving power which penetrates the non-fluorinated gas from the separating membrane module, but the pump is connected with the penetration hole of the separating membrane module; and a discharging flux control unit connected with the outlet of the separating membrane module and controlling the flux of the fluorinated gas discharged from the separating membrane module. The device for recovering the fluorinated gas comprises a separating membrane module in the same structure as that of the device for enriching the fluorinated gas. According to the present invention, the fluorinated gas can be enriched and recovered efficiently by recovering lost fluorinated gas through the recovering device. [Reference numerals] (200) Enriching section; (400) Recovering section; (AA) Mass flow controller; (BB) Vacuum pump
Abstract translation: 本发明的目的是提供一种使用分离膜富集和回收氟化气体的装置，以及使用该装置富集和回收氟化气体的方法。 用于富集氟化气体的装置包括供给包括氟化气体的混合气体的气体供给单元; 富集单元，其具有一个或多个分离膜组件，该分离膜组件通过具有从供给单元注入混合气体的入口，分离氟化气体的分离膜，将非氟化的 通过分离膜从氟化气体分离的气体被排出，并且排出氟化气体的出口; 提供驱动力的减压泵，其从分离膜组件穿透非氟化气体，但是泵与分离膜组件的穿透孔连接; 以及放电通量控制单元，与分离膜组件的出口连接并控制从分离膜组件排出的氟化气体的通量。 用于回收氟化气体的装置包括与用于富集氟化气体的装置相同结构的分离膜组件。 根据本发明，可以通过回收装置回收失去的氟化气体来有效地富集和回收氟化气体。 （附图标记）（200）富集部; （400）收回科; （AA）质量流量控制器; （BB）真空泵
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55.发明公开다공성 알루미늄계 중공사막의 제조방법 및 이에 따라 제조되는 선택 투과성과 기계적 강도가 향상된 직선형의 다공성 알루미늄계 중공사막 有权基于铝的多孔中空纤维膜的制备方法以及直径为多孔铝基的中空纤维膜改进了选择性渗透性和机械强度
公开(公告)号：KR1020130140396A
公开(公告)日：2013-12-24
申请号：KR1020120063753
申请日：2012-06-14
Applicant: 한국화학연구원
CPC classification number: B01D69/08 , B01D71/025 , B01D2325/20 , B01D2325/24 , D01D5/24 , D01F1/08
Abstract: The present invention relates to a manufacturing method of a porous aluminum-based hollow fiber membrane, and a linear porous aluminum-based hollow fiber membrane which has improved selective permeability and mechanical strength manufactured by the same and, more particularly, to a manufacturing method of a porous aluminum-based hollow fiber membrane which comprises: a step of manufacturing an aluminum precursor liquid by dissolving an aluminum precursor in the solvent (step 1); a step of manufacturing a spinning solution by adding a polymer resin in the aluminum precursor liquid of the step 1 (step 2); a step of manufacturing a hollow fiber membrane by dipping the spinning solution of the step 2 to coagulant after extruding through a nozzle (step 3); a step of heat treating the manufactured hollow fiber membrane of the step 3 (step 4); a step of sintering the heat treated hollow fiber membrane of the step 4 in a heating furnace by rotating (step 5); and a linear porous aluminum-based hollow fiber membrane manufactured by the same. The manufacturing method of a porous aluminum-based hollow fiber membrane is capable of mass-producing the hollow fiber membrane in which the unit price for producing is cheap by having a simple process; improving the heat-resisting property, the durability, the chemical-proof property, the mechanical strength, and high selective permeability by sintering with rotating inside a tube furnace; manufacturing linear porous aluminum-based hollow fiber membrane which has large valid membrane area per unit volume which is favorable to membrane modularization thereby efficiently using in a water treatment area which needs severe operation condition.
Abstract translation: 本发明涉及一种多孔铝基中空纤维膜的制造方法以及具有提高的选择渗透性和机械强度的线状多孔铝基中空纤维膜，更具体地说，涉及一种制造方法 一种多孔铝基中空纤维膜，包括：通过将铝前体溶解在溶剂中来制造铝前体液体的步骤（步骤1）; 通过在步骤1（步骤2）的铝前体液中添加聚合物树脂制造纺丝溶液的步骤; 通过在通过喷嘴挤出之后将步骤2的纺丝溶液浸入凝结剂中制造中空纤维膜的步骤（步骤3）; 对步骤3中制造的中空纤维膜进行热处理的步骤（步骤4）; 在加热炉中通过旋转烧结步骤4的热处理中空纤维膜的步骤（步骤5）; 以及由其制造的线状多孔铝基中空纤维膜。 多孔铝基中空纤维膜的制造方法能够通过简单的工序大量生产生产单价便宜的中空纤维膜; 通过在炉管内旋转烧结来提高耐热性，耐久性，耐化学性，机械强度和高选择性渗透性; 制造线性多孔铝基中空纤维膜，其每单位体积的有效膜面积大，有利于膜模块化，从而在需要严格的操作条件的水处理区域中有效地使用。
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Patent Agency Ranking
公开(公告)号：KR1020130081859A
公开(公告)日：2013-07-18
申请号：KR1020120002928
申请日：2012-01-10
Applicant: 한국화학연구원
CPC classification number: C08B11/18
Abstract: PURPOSE: A novel manufacturing method of Butylmethyl cellulose is provided to be wisely used to the separation membrane and film for water treatment by using methyl cellulose to reduce the manufacturing time and the manufacturing cost, prevent environmental contamination due to by-product, and improve the manufacturing process. CONSTITUTION: A manufacturing method of Butylmethyl cellulose adds methyl cellulose of chemical formula 2, butyric acid and organic solvent of chemical formula 3 to the chemical formula 1 for obtaining the mixture by stirring it. (Step 1) The intended compound is dried to be obtained after the compound manufactured in the step 1 is primary washed with organic solvent and secondary washed with water. (Step 2) [Equation 1] (R is H or CH3 when the R is not H or CH3 at the same time in the chemical formula 2. R is H, CH_3 or C_6H_5CO in the chemical formula 1. The reaction ratio of methyl cellulose: butyric acid of the step 1 is 1: 1-2. Organic solvent of the step 1 is more than one selected from the group of pyridine, quinoline, furan, pyran and thiophene. The step 1 is performed in 120-150 °C. The step 1 is performed in 2-4 hours. Organic solvent of the step 2 is selected from the group of methanol, ethanol, propanol and butanol.
Abstract translation: 目的：提供丁基甲基纤维素的新颖制造方法，通过使用甲基纤维素来降低制造时间和制造成本，防止副产物引起的环境污染，从而明确地用于分离膜和水处理膜，并改善 制造工艺。 构成：丁基甲基纤维素的制造方法将化学式2的甲基纤维素，化学式3的丁酸和有机溶剂加入到化学式1中，通过搅拌获得混合物。 （步骤1）将目的化合物干燥，得到步骤1中制造的化合物用有机溶剂进行一次洗涤，二次用水洗涤。 （步骤2）[方程式1]（化学式1中，当R不同时为H或CH3时，R为H或CH3。化学式1中R为H，CH 3或C 6 H 5 CO。 纤维素：步骤1的丁酸为1：1-2，步骤1的有机溶剂为选自吡啶，喹啉，呋喃，吡喃和噻吩中的多种，步骤1为120-150℃ C.步骤1在2-4小时内进行。步骤2的有机溶剂选自甲醇，乙醇，丙醇和丁醇。
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公开(公告)号：KR101275774B1
公开(公告)日：2013-06-17
申请号：KR1020110072527
申请日：2011-07-21
Applicant: 한국화학연구원
Abstract: 본 발명은 불화가스 분리농축장치 및 이를 이용한 불화가스의 분리농축방법에 관한 것으로, 상세하게는 불화가스를 포함하는 혼합가스가 공급되는 가스공급부; 상기 가스공급부로부터 공급되는 혼합가스의 유량을 제어하는 유입량제어부; 상기 유입량제어부를 통해 혼합가스가 주입되는 주입구, 불화가스가 분리된 비불화가스가 배출되는 투과구 및 분리된 불화가스가 배출되는 배출구를 구비하여 혼합가스로부터 불화가스를 분리하는 분리막 모듈이 1 또는 그 이상 직렬연결된 분리부; 상기 분리부의 투과구와 연결되되, 상기 분리부 내부를 감압시켜 분리막 모듈 내부로 가스가 주입 및 분리되는 구동력을 발생시키는 감압부; 및 상기 분리부의 배출구와 연결되되, 상기 분리부로부터 배출되는 불화가스의 유량을 제어하는 배출량제어부를 포함하는 불화가스 분리농축장치를 제공한다. 본 발명에 따른 불화가스 분리농축장치 및 이를 이용한 불화가스의 분리방법은 분리막을 이용하여 불화가스를 처리하는 종래의 가압방식보다 더욱 높은 불화가스 분리·농축 효율을 나타낼 수 있다. 또한, 불화가스의 분리가 수행되는 분리막 모듈의 압력을 일정하게 유지하여 대형화에 따른 효율저하 문제가 없으며, 가압부로 인하여 불화가스가 배출되는 공정에 악영향을 주는 문제를 방지할 수 있다.
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公开(公告)号：KR1020130011394A
公开(公告)日：2013-01-30
申请号：KR1020110072528
申请日：2011-07-21
Applicant: 한국화학연구원
CPC classification number: B01D63/02 , B01D53/228 , B01D2053/224 , B01D2258/0216 , Y02C20/30
Abstract: PURPOSE: A separating film module and a mixed gas separation and concentration device including the same are provided to minimize the pressure deviation inside the separating film module, thereby securing the high separation efficiency of fluorinated gas during the separation of the fluorinated gas by pressure reduction. CONSTITUTION: A separating film module is a hollow fiber membrane which includes a penetration part and an outlet. The separating film module includes the porous media(20) inside and is divided into multiple sections by the media. The divided sections have the same pressure by pores of the porous media, and the penetrated gas from the pores of the porous media is discharged through the outlet. The porous media is made of a plastic material which has excellent chemical resistance and mechanical strength against the fluorinated gas.
Abstract translation: 目的：提供一种分离膜组件和包括该分离膜组件的混合气体分离和浓缩装置，以使分离膜组件内的压力偏差最小化，由此通过减压在确定氟化气体分离期间的高分离效率。 构成：分离膜模块是包括穿透部分和出口的中空纤维膜。 分离膜模块包括内部的多孔介质（20），并通过介质分成多个部分。 分隔部分通过多孔介质的孔具有相同的压力，并且来自多孔介质的孔的穿透气体通过出口排出。 多孔介质由对氟化气体具有优异的耐化学性和机械强度的塑料材料制成。
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公开(公告)号：KR1020130011393A
公开(公告)日：2013-01-30
申请号：KR1020110072527
申请日：2011-07-21
Applicant: 한국화학연구원
CPC classification number: B01D63/02 , B01D53/228 , B01D69/08 , B01D71/02 , B01D71/06 , B01D2053/224 , B01D2258/0216 , Y02C20/30
Abstract: PURPOSE: A separation and concentration device for fluorinated gas and a separation and concentration method for fluorinated gas using the same are provided to achieve the high separation and concentration efficiency of fluorinated gas compared to the previous pressurizing method which processes fluorinated gas using a separation film and to maintain the constant pressure of a separation film module in which the separation of fluorinated gas is conducted, thereby preventing efficiency reduction due to a large size and preventing an adverse effect to a fluorinated gas discharge process due to a pressurizer. CONSTITUTION: A separation and concentration device for fluorinated gas comprises a gas supply unit(100), an inflow control unit(200), a separation unit(300), a pressure reducer(400), and a discharge quantity control unit(500). The inflow control unit controls the flow rate of mixed gas including fluorinated gas supplied from the gas supply unit. A separation film module comprises an inlet, a penetration part, and an outlet. The mixed gas is injected into the inlet through the inflow control unit. Non-fluorinated gas in which the fluorinated gas is separated is discharged through the penetration part. The separated fluorinated gas is discharged through the outlet. At least one separation film module which separates the fluorinated gas from the mixed gas is serially connected to the separation unit. The pressure reducer is connected to the penetration part of the separation unit. The pressure reducer reduces the pressure inside the separation unit and generates driving force by which gas is injected into the separation film module and separated. The discharge quantity control unit is connected to the outlet of the separation unit in order to control the flow rate of the fluorinated gas discharged from the separation unit.
Abstract translation: 目的：提供一种氟化气体的分离浓缩装置和使用该分离浓缩装置的氟化气体的分离和浓缩方法，以实现与先前使用分离膜处理氟化气体的加压方法相比，氟化气体的高分离和浓缩效率， 以保持进行氟化气体分离的分离膜组件的恒定压力，从而防止由于大尺寸而导致的效率降低，并且防止由于加压器引起的氟化气体排出过程的不利影响。 构成：氟化气体的分离浓缩装置包括气体供给单元（100），流入控制单元（200），分离单元（300），减压器（400）和排出量控制单元（500） 。 流入控制单元控制从气体供给单元供给的包含氟化气体的混合气体的流量。 分离膜模块包括入口，穿透部分和出口。 混合气体通过流入控制单元注入入口。 氟化气体分离的非氟化气体通过贯通部排出。 分离的氟化气体通过出口排出。 将氟化气体与混合气体分离的至少一个分离膜组件串联连接到分离单元。 减压器连接到分离单元的穿透部分。 减压器降低分离单元内的压力，并产生驱动力，气体被喷射到分离膜模块中并分离。 排出量控制单元连接到分离单元的出口，以便控制从分离单元排出的氟化气体的流量。
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公开(公告)号：KR1020110074201A
公开(公告)日：2011-06-30
申请号：KR1020090131104
申请日：2009-12-24
Applicant: 한국화학연구원
CPC classification number: B01D71/12 , B01D67/0006 , B01D2323/12 , B01D2325/20 , C02F1/001
Abstract: PURPOSE: An acetylation methylcellulose, and a manufacturing method of the same, a coating agent for the water treatment separation membrane including the same, and a manufacturing method of separation membrane for water treatment using the same are provided to manufacture the coating agent of the separation membraned which has superior mechanical strength by preventing the phenomenon that the decomposition occurs before melting occurs since having low melting point than natural polymer for the existing separation membrane of separation membrane material, and to have excellent profitability since the simplification of the manufacturing process is possible unlike the existing separation membrane material. CONSTITUTION: The manufacturing method of the acetylation methylcellulose includes the step of manufacturing solution by dissolving methylcellulose in the solvent containing more than one kind selected from the pyridine, and the acetone and their mixture, adding acetic anhydride in the solution and performing acetylation reaction and solidifying in the water. The rate of solvent and methylcellulose is 5 ~ 40 : 95 ~ 60 weight ratio. The amount of the acetic anhydride is 0.5 ~ 3 molar ratio per the methylcellulose unit. The acetylation reaction operates in 10 ~ 90°C. The acetylation methylcellulose has 160 ~ 180°C melting point.
Abstract translation: 目的：提供一种乙酰化甲基纤维素及其制造方法，包括其的水处理分离膜用涂布剂和使用其的水处理用分离膜的制造方法，制造分离用涂布剂 具有优异的机械强度的膜，其具有优异的机械强度，因为与分离膜材料的现有分离膜相比，熔点低于天然聚合物的熔点发生分解，并且由于制造过程的简化而具有优异的利润率，因此可能不同于 现有的分离膜材料。 构成：乙酰化甲基纤维素的制造方法包括通过将甲基纤维素溶解在含有多于一种选自吡啶和丙酮及其混合物的溶剂的溶剂中制备溶液的步骤，在溶液中加入乙酸酐并进行乙酰化反应和固化 在水里。 溶剂和甲基纤维素的比例为5〜40：95〜60重量比。 每个甲基纤维素单元的乙酸酐的量为0.5-3摩尔比。 乙酰化反应在10〜90℃下进行。 乙酰化甲基纤维素的熔点为160〜180℃。
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