Abstract:
Process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55°C; optionally, ii) pre-polymerizing with one or more olefins of formula CH2=CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins producing said porous propylene (co)polymer.
Abstract:
A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.
Abstract:
Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I), in which R2-R8 groups, equal or different to each other, are selected from hydrogen, halogen and C1 -C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N, and Si and R9 groups are selected from C1 -C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, O, P, S, N, and Si.
Abstract:
Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R 12 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, with the proviso that R groups cannot be hydrogen and that the carboxylate groups are in trans configuration with respect to each other.
Abstract:
Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R 4 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which may be linked to form a saturated or unsaturated mono or polycycle and R 5 groups are selected from C 1 -C 15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si.
Abstract:
Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R 1 to R 4 groups, equal to or different from each other, are hydrogen, C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and S i ,, R 6 group is selected from C 1 -C 15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R 5 is selected from phenyl groups mono or poly substituted with halogens, said groups R 1 -R 4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.