公开(公告)号：JP2009235121A

公开(公告)日：2009-10-15

申请号：JP2008079074

申请日：2008-03-25

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE

IPC: C09D17/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/36 ,  C09D11/38

Abstract: PROBLEM TO BE SOLVED: To provide a pigment dispersion excellent in fine pigment dispersibility and its stability, an ink composition and a colored curable composition prepared by using the pigment dispersion and having clear hue and high coloring power, a curable ink composition suitable for ink jet recording, and an inkjet recording method using the ink composition. SOLUTION: The pigment dispersion contains a pigment dispersing agent and a pigment. The dispersing agent is composed of a graft polymer having a branch part, which consists of a polymer having a partial structure selected from a urea bond, a urethane bond and an aliphatic amino group in a repeating unit, and a branch part, which consists of a polymer selected from an aliphatic polyester, a poly(meth)acrylate and a polyether, in a trunk part of a polyurethane/polyurea structure. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：为了提供颜料分散性和稳定性优异的颜料分散体，通过使用颜料分散体并且具有清晰的色调和高着色力制备的油墨组合物和着色固化性组合物，适合的可固化油墨组合物 用于喷墨记录，以及使用该油墨组合物的喷墨记录方法。 颜料分散体含有颜料分散剂和颜料。 分散剂由具有分支部分的接枝聚合物组成，该分支部分由具有选自重复单元中的脲键，氨基甲酸酯键和脂族氨基的部分结构的聚合物和分支部分组成，分支部分由 在聚氨酯/聚脲结构体的主干部分中选自脂族聚酯，聚（甲基）丙烯酸酯和聚醚的聚合物。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009233486A

公开(公告)日：2009-10-15

申请号：JP2008079073

申请日：2008-03-25

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE

IPC: B01F17/52 ,  B01F17/42 ,  B41J2/01 ,  B41M5/00 ,  C08G18/62 ,  C09B67/20 ,  C09D11/00 ,  C09D11/322 ,  C09D17/00

Abstract: PROBLEM TO BE SOLVED: To provide: a method of manufacturing a pigment dispersant having excellent dispersibility and dispersion stability of fine pigment; a pigment dispersed composition exhibiting excellent clear color tone and high coloring power; a curable composition for inkjet which has high sensitively and excellent blocking resistance; and an inkjet recording method. SOLUTION: In the manufacturing method of the pigment dispersant, at least the following (a), (b), and (c) are made to react with each other in a polymerizable compound (d). (a) is a compound having a hydroxide group and a partial structure of a pigment adsorption, (b) is a polymer selected from an aliphatic polyester, poly(meth)acrylate, and polyether, and having a hydroxide group or a primary amino group, and (c) is an isocyanate compound having two or more functions. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 解决的问题：提供：制备颜料分散剂的方法，所述颜料分散剂具有优异的分散性和细颜料的分散稳定性; 表现出优异的清晰色调和高着色力的颜料分散组合物; 用于喷墨的可固化组合物具有高敏感性和优异的抗粘连性; 和喷墨记录方法。 解决方案：在颜料分散剂的制造方法中，至少使以下（a），（b）和（c）在可聚合化合物（d）中彼此反应。 （a）是具有氢氧化物基团和颜料吸附的部分结构的化合物，（b）是选自脂族聚酯，聚（甲基）丙烯酸酯和聚醚，并且具有氢氧基或伯氨基的聚合物 ，（c）是具有两个以上的功能的异氰酸酯化合物。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009138172A

公开(公告)日：2009-06-25

申请号：JP2008071541

申请日：2008-03-19

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE ,  NAGASE HISATO ,  TAKAHASHI HIDETOMO

IPC: B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/326 ,  C09D11/36 ,  C09D11/38

CPC classification number: C09D11/326 ,  C09D11/101 ,  Y10T428/24802 ,  Y10T428/31504 ,  Y10T428/31855

Abstract: PROBLEM TO BE SOLVED: To provide an active ray-curable ink composition excellent in fine pigment dispersibility and its stability, forming a high-quality image having vivid color tones and high coloring power, and suitably usable for inkjet recording application. SOLUTION: The ink composition includes at least a polymerizable compound, a pigment, and a polymer represented by a general formula (1). In the general formula (1), R 1 represents an (m+n)-valent organic linking group; R 2 represents a single bond or divalent organic linking group; A 1 represents a monovalent organic group having a pigment adsorption structure which consists of at least one selected from an organic pigment structure, a heterocyclic structure, an acidic group, a group having a basic nitrogen atom, a urea group, a urethane group, a group having a coordinating oxygen atom, a hydrocarbon group having 4 or more carbon atoms, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxy group; the n groups A 1 and bonds or groups R 2 may independently be the same or different; (m) is 1 to 8; (n) is 2 to 9; (m+n) is 3 to 10; P 1 represents a polymer skeleton; and the m skeletons P 1 may be the same or different. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：为了提供优异的细颜料分散性和稳定性的活性射线固化油墨组合物，形成具有鲜艳色调和高着色力的高质量图像，并且适用于喷墨记录应用。 解决方案：油墨组合物至少包含可聚合化合物，颜料和由通式（1）表示的聚合物。 在通式（1）中，R 1表示（m + n）价有机连接基团; R 2 表示单键或二价有机连接基团; A 1 表示具有颜料吸附结构的一价有机基团，其由选自有机颜料结构，杂环结构，酸性基团，具有碱性氮原子的基团，脲 基团，氨基甲酸酯基，具有配位氧原子的基团，具有4个或更多个碳原子的烃基，烷氧基甲硅烷基，环氧基，异氰酸酯基和羟基; n个基团A 1 和键或基团R 2 可以独立地相同或不同; （m）为1〜8; （n）为2〜9; （m + n）为3〜10; P 1 表示聚合物骨架; 并且m个骨架P 1 可以相同或不同。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009137930A

公开(公告)日：2009-06-25

申请号：JP2008071548

申请日：2008-03-19

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE ,  NAGASE HISATO ,  TSUJIHATA SHIGENORI

IPC: C07D221/14 ,  B41J2/01 ,  B41M5/00 ,  C07D487/06 ,  C07D487/16 ,  C08F212/32 ,  C08F220/36 ,  C08F257/00 ,  C08F290/04 ,  C09D11/00 ,  C09D11/38

CPC classification number: C07D221/06 ,  C07D471/06 ,  C07D471/16 ,  C09D11/101

Abstract: PROBLEM TO BE SOLVED: To provide a new polymerizable compound that is industrially exceedingly useful and a polymer that comprises a copolymerization unit derived from the polymerizable compound and is useful as a pigment dispersant for improving dispersibility of fine pigment and its stability. SOLUTION: The polymerizable compound is represented by general formula (1) (wherein R 1 is a hydrogen atom, a substituted alkyl group or a nonsubstituted alkyl group; R 2 is an alkylene group; W is -CO-, -C(=O)O-, -CONH-, -OC(=O)- or a phenylene group; X is -CO-, -NHCO-, -OC(=O)-, -CH(OH)CH 2 - or -SO 2 -; R 3 and R 4 are each a monofunctional substituent group and R 3 and R 4 may together form a cyclic structure; and m and n are each independently 0 or 1). COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供在工业上非常有用的新的可聚合化合物和包含由可聚合化合物衍生的共聚单元的聚合物，并且可用作改善细颜料的分散性及其稳定性的颜料分散剂。 解决方案：可聚合化合物由通式（1）表示（其中R 1 是氢原子，取代的烷基或非取代的烷基; R 2 SP 2 >是亚烷基; W是-CO - ， - C（= O）O-，-CONH-，-OC（= O） - 或亚苯基; X是-CO-，-NHCO-，-OC = O） - ， - CH（OH）CH - 或-SO 2 3; SP>各自是单官能取代基，R 3和R 4都可以一起形成环状结构; m和n各自独立地为0或1）。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008274219A

公开(公告)日：2008-11-13

申请号：JP2007298603

申请日：2007-11-16

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE ,  NAGASE HISATO

IPC: B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/326 ,  C09D11/328 ,  C09D11/38

Abstract: PROBLEM TO BE SOLVED: To provide an ink composition suitable for inkjet recording applications that is excellent in dispersibility and dispersion stability of fine pigments, can form an image of high image quality having clear color tones and high coloring power and is curable by irradiation with an active radiation. SOLUTION: The ink composition comprises at least a polymerizable compound, a pigment and a polymer containing a recurring unit derived from a monomer represented by general formula (1) (wherein R 1 is a hydrogen atom or an alkyl group; and R 2 and R 3 are each an optionally substituted alkylene or phenylene group). COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：为了提供适用于精细颜料的分散性和分散稳定性优异的喷墨记录应用的油墨组合物，可以形成具有清晰色调和高着色力的高图像质量的图像，并且可通过 用活性辐射照射。 解决方案：油墨组合物至少包含可聚合化合物，颜料和含有源自由通式（1）表示的单体的重复单元的聚合物（其中R 1 是氢原子 或烷基; R 2 SP 3和R 3 SP 3各自为任选取代的亚烷基或亚苯基）。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008274218A

公开(公告)日：2008-11-13

申请号：JP2007298601

申请日：2007-11-16

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE ,  NAGASE HISATO

IPC: C09D17/00 ,  B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/328 ,  C09D11/38

Abstract: PROBLEM TO BE SOLVED: To provide a particle dispersion exhibiting excellent particle dispersibility, an ink composition that is excellent in dispersibility and dispersion stability of fine pigments, can form an image of high image quality having clear color tones and high coloring power and is curable by irradiation with an active radiation, and the like. SOLUTION: The particle dispersion comprises at least an organic medium, a particle and a polymer bearing a hydrogen-bonding group capable of forming at least three hydrogen bonds. The ink composition comprises the particle dispersion, a polymerizable compound as the organic medium and a pigment as the particle. Preferably, the polymer contains a recurring unit represented by general formula (1) (wherein R is a hydrogen atom or a methyl group; W is -CO-, -COO-, -CONR 1 -, -OCO- or a phenylene group; R 1 is a hydrogen atom, an alkyl group, an aryl group or an aralkyl group; X is a single bond or a bivalent linking group; and A is a hydrogen-bonding group capable of forming at least three hydrogen bonds). COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题为了提供显示出优异的颗粒分散性的颗粒分散体，能够形成具有清晰色调和高着色力的高图像质量的图像，该分散性和分散稳定性优异的油墨组合物， 可通过用活性辐射照射等固化。 解决方案：颗粒分散体至少包含有机介质，颗粒和具有能够形成至少三个氢键的氢键基团的聚合物。 油墨组合物包含颗粒分散体，作为有机介质的可聚合化合物和作为颗粒的颜料。 优选地，聚合物含有由通式（1）表示的重复单元（其中R是氢原子或甲基; W是-CO-，-COO-，-CONR）， - OCO-或亚苯基; R 1是氢原子，烷基，芳基或芳烷基; X是单键或二价连接基团; A是氢原子， 能够形成至少三个氢键的键合基团）。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008274217A

公开(公告)日：2008-11-13

申请号：JP2007298578

申请日：2007-11-16

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE ,  NAGASE HISATO

IPC: B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/38

Abstract: PROBLEM TO BE SOLVED: To provide an ink composition suitable for inkjet recording applications that is excellent in dispersibility and dispersion stability of fine pigments, can form an image of high image quality having clear color tones and high coloring power and is curable by irradiation with an active radiation. SOLUTION: The ink composition comprises at least a polymerizable compound, a pigment and a polymer containing a recurring unit derived from a monomer represented by general formula (1) (wherein R 1 is a hydrogen atom or an alkyl group; R 2 and R 3 are each a monovalent substituent group, and R 2 and R 3 may be linked together to form a ring structure; W is any one of -CO-, -C(=O)O-, -CONR-, -OC(=O)- and a phenylene group; R is a hydrogen atom, an alkyl group, an aryl group or an aralkyl group; and X is a single bond or a bivalent linking group). COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：为了提供适用于精细颜料的分散性和分散稳定性优异的喷墨记录应用的油墨组合物，可以形成具有清晰色调和高着色力的高图像质量的图像，并且可通过 用活性辐射照射。 解决方案：油墨组合物至少包含可聚合化合物，颜料和含有源自由通式（1）表示的单体的重复单元的聚合物（其中R 1 是氢原子 或烷基; R 2 SP＆gt;和R SP 3各自为一价取代基，并且R 2为SP 2和R SP 3 可以连接在一起形成环结构; W是-CO - ， - C（= O）O - ， - CONR - ， - OC（= O） - 和亚苯基中的任何一个; R是氢原子 ，烷基，芳基或芳烷基; X为单键或二价连接基团）。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008266561A

公开(公告)日：2008-11-06

申请号：JP2007296839

申请日：2007-11-15

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE

IPC: B41J2/01 ,  B41M5/00 ,  B82Y30/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/326 ,  C09D11/38

Abstract: PROBLEM TO BE SOLVED: To provide an ink composition excellent in shelf stability and capable of forming a high-quality image (having high concealing property) having a clear color tone and a high tinting power. SOLUTION: This ink composition comprises at least a pigment (a), a pigment dispersant (b) and a photo-acid generating agent (c), characterized in that the pigment (a) has an average particle diameter of primary particles thereof of 10 to 100 nm and the pigment dispersant (b) has basic functional groups. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供具有优异的储存稳定性并且能够形成具有清晰色调和高着色力的高质量图像（具有高掩蔽性）的油墨组合物。 解决方案：该油墨组合物至少包含颜料（a），颜料分散剂（b）和光酸产生剂（c），其特征在于，颜料（a）具有一次粒子的平均粒径 为10〜100nm，颜料分散剂（b）具有碱性官能团。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008248036A

公开(公告)日：2008-10-16

申请号：JP2007089731

申请日：2007-03-29

Applicant: Fujifilm Corp ,  富士フイルム株式会社

Inventor： SHIMOHARA NORIHIDE

IPC: B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/324 ,  C09D11/38

Abstract: PROBLEM TO BE SOLVED: To provide an ink composition which excels in the dispersibility of a fine pigment and its stability, can form a high quality image having a bright color tone and high coloring power, can be curable by irradiation with active radiation and is suitably used in inkjet recording, and an inkjet recording method using the above ink composition. SOLUTION: The ink composition comprises a pigment (a), a polymer (b) having a silane coupling group, and a polymer (c) having a basic functional group whose conjugate acid has a pKa of not less than 6.0. It is preferred that the polymer (b) contains a repeating unit represented by formula (1) as a constituting unit. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：为了提供优异的细颜料分散性及其稳定性的油墨组合物，可以形成具有明亮色调和高着色力的高质量图像，可以通过用活性辐射照射来固化 并且适用于喷墨记录和使用上述油墨组合物的喷墨记录方法。 解决方案：油墨组合物包含颜料（a），具有硅烷偶联基团的聚合物（b）和具有共轭酸的pKa不小于6.0的具有碱性官能团的聚合物（c）。 聚合物（b）优选含有由式（1）表示的重复单元作为构成单元。 版权所有（C）2009，JPO＆INPIT