公开(公告)号：DE1096528B

公开(公告)日：1961-01-05

申请号：DEST015423

申请日：1959-08-03

Applicant: STANDARD OIL CO

Inventor： SABOL ALBERT R ,  MATTANO LEONARD A ,  WATSON ROGER W

IPC: C10M163/00

公开(公告)号：CA996101A

公开(公告)日：1976-08-31

申请号：CA183273

申请日：1973-10-12

Applicant: STANDARD OIL CO

Inventor： UDELHOFEN JOHN H ,  WATSON ROGER W ,  KURASIEWICZ ADAM S

IPC: C08L23/00 ,  C08K5/45 ,  C08K5/46 ,  C08L101/00 ,  C10G29/20 ,  C10M159/12 ,  C10M161/00 ,  C10M163/00 ,  C10N30/00 ,  C10N30/10 ,  C10N30/12 ,  C10N40/25

Abstract: 1447097 Stabilizing phosphosulphurized polyolefins STANDARD OIL CO 12 Oct 1973 [13 Oct 1972] 47819/73 Heading C3P [Also in Divisions C5 and C2] A composition suitable for use as an additive for an oily lubricant (see Division C5) comprises a phosphosulphurized hydrocarbon and a m nor amount of a 2,5-bis-(alkyl-dithio)1,3,4-thiadiazole. The thiadiazole derivative serves to improve the stability and reduce the odour of the phosphosulphurized hydrocarbon. The preferred phosphosulphurized hydrocarbons are derived from viscous polymers of propene or butene which have molecular weights of 200- 4000 and weight ratios S : P of 1 to 3. Preferred thiadiazole derivatives are those in which the alkyl group has eight or more carbon atoms, particularly those in which it is octyl or dodecyl.

公开(公告)号：CA891517A

公开(公告)日：1972-01-25

申请号：CA891517D

Applicant: STANDARD OIL CO

Inventor： WATSON ROGER W ,  BLAHA ELI W

IPC: C07F3/06 ,  C07F9/02

公开(公告)号：CA681298A

公开(公告)日：1964-03-03

申请号：CA681298D

Applicant: STANDARD OIL CO

Inventor： KARLL ROBERT E ,  RICHARDSON EUGENE E ,  WATSON ROGER W

公开(公告)号：CA655232A

公开(公告)日：1963-01-01

申请号：CA655232D

Applicant: STANDARD OIL CO

Inventor： WATSON ROGER W ,  LITTLE RANDEL Q JR

公开(公告)号：CA536222A

公开(公告)日：1957-01-22

申请号：CA536222D

Applicant: STANDARD OIL CO

Inventor： DITTO CLAIR R ,  WATSON ROGER W

公开(公告)号：GB744779A

公开(公告)日：1956-02-15

申请号：GB998653

申请日：1953-04-13

Applicant: STANDARD OIL CO

Inventor： WATSON ROGER W ,  FAINMAN MORTON ,  DITTO CLAIRE R

IPC: C07F9/04 ,  C10M159/12 ,  F02B3/06

Abstract: A non-gaseous hydrocarbon is reacted with 1 to 50 per cent of a phosphorus sulphide at 200 DEG to 600 DEG F. and the product, which may be previously diluted with hydrocarbon oil, is hydrolysed at 220 DEG to 500 DEG F. and then contacted with an alkaline mineral adsorbent at 100 DEG to 500 DEG F. until substantially all of the inorganic phosphorus acids have been removed. The mixture is filtered and the filtrate may then be neutralized, in particular with barium hydroxide. Neutralization may optionally be effected prior to hydrolysis. In a modification, precipitation of inorganic phosphorus acids and neutralization are effected in one step by steaming at 220 DEG to 300 DEG F. with at least a stoichiometric amount of barium hydroxide and a barium containing additive is obtained. Hydrocarbons specified are polymers of propylene, butylene or amylene, polymers of hydrocarbons derived from vapour phase cracking of paraffin wax in presence of aluminium chloride or of gasoline in presence of sulphuric acid or fuller's earth, and voltolized hydrocarbons. The alkaline mineral adsorbent may be Attapalgus clay, Floridin, fuller's earth, bentonite, magnesite, bauxite, calcium oxide, carbonate or hydroxide, barium oxide or hydroxide or magnesium oxide. The products are useful as lubricating oil additives.ALSO:A non-gaseous hydrocarbon is reacted with 1 to 50 per cent of a phosphorus sulphide at 200 DEG to 600 DEG F. and the product, which may be previously diluted with hydrocarbon oil, is hydrolysed at 220 DEG to 500 DEG F. and then contacted with an alkaline mineral adsorbent at 100 DEG to 500 DEG F. until substantially all of the inorganic phosphorus acids have been removed. The mixture is filtered and may then be neutralized with an alkaline reagent, in particular barium hydroxide. Neutralization may optionally be effected prior to hydrolysis. In a modification, precipitation of inorganic phosphorus acids and neutralization are effected in one step by steaming at 220 DEG to 300 DEG F. with at least a stoichiometric amount of barium hydroxide and a barium containing derivative is obtained. Hydrocarbons specified are paraffinic hydrocarbons such as bright stock residuums, lubricating oil distillates, petrolatums, paraffin waxes, condensation products of hydrocarbons with aromatic hydrocarbons, olefins such as cetene and melene, olefins obtained by dehydrogenation of paraffins or dehalogenation of alkyl halides (e.g. halogenated paraffin waxes), benzene, naphthalene, toluene, xylene, diphenyl and alkylated aromatic hydrocarbons. The alkaline mineral adsorbent may be Attapulgus clay, Floridin, fuller's earth, bentonite, magnesite, bauxite, calcium oxide, carbonate or hydroxide, barium oxide or hydroxide or magnesium oxide. The products of the invention are useful as lubricating oil additives.ALSO:Lubricating oil additives are obtained by reacting a non-gaseous hydrocarbon with 1 to 50 per cent of a phosphorus sulphide at 200 DEG to 600 DEG F. and the product, which may be previously diluted with hydrocarbon oil, is hydrolyzed at 220 DEG to 500 DEG F. and then contacted with an alkaline mineral absorbent at 100 DEG to 500 DEG F. until substantially all of the inorganic phosphorus acids have been removed. The mixture is filtered and may then be neutralized, e.g. with barium hydroxide. Neutralization may optionally be effected prior to hydrolysis. In a modification, precipitation of inorganic phosphorus acids and neutralization are effected in one step by steam at 220 DEG to 300 DEG F. with at least a stoichiometric amount of barium hydroxide and barium containing derivative is obtained. Various hydrocarbons are specified (see also Groups IV(a) and IV(b)) including bright stock residuums, lubricating oil distillates, petrolatums and paraffin waxes. Lubricating compositions comprising hydrocarbon oil, such as mineral oil, together with the additives, reduce valve wear in diesel engines particularly when using fuels having high sulphur content.