Abstract:
A grease composition comprising a grease containing, in a base oil thereof, from 2 to 40% by weight, based on the total composition, of tricalcium phosphate [Ca₃(PO₄)₂], the grease further containing (A) from 0.5 to 10% by weight, based on the total composition, of a molybdenum dialkyldithiocarbamate sulfide and (B) from 0.1 to 5% by weight, based on the total composition, of at least one of a zinc dialkyldithiophosphate and triphenyl phosphorothionate. The grease composition is excellent in mechanical stability, heat resistance, extreme pressure properties, and wear resistance.
Abstract:
Disclosed are grease compositions containing a liquid fluorinated polymer and a thickening agent containing hexagonal lattice boron nitride powder having a bimodal particle size distribution as well as grease compositions containing a liquid fluorinated polymer and a thickening agent containing hexagonal lattice boron nitride powder and a solid fluorinated polymer.
Abstract:
Crystalline aluminates of the formula: I. (LiAx)y.2Al(OH)3.nH2O II. Li(R)v_r.2Al(OH)3.nH2O, or III. Mm(R)v_r.(D)w_z2Al(OH)3.nH2O wherein A is one or more anions and/or negative-valence radicals or mixtures thereof; wherein, in formula I, x is a quantity of A ions or radicals sufficient to substantially satisfy the valence requirements of Li; wherein n is zero or the number of waters of hydration; wherein y is a numerical value at least sufficient to maintain the crystalline structure; wherein R is a monocarboxylic acid or dicarboxylic acid of C6 C22, including those which are OH substituted; wherein r is greater than zero and represents the number of R ions in the molecule; wherein v is the valence of R, being monovalent or divalent; wherein M is divalent Zn or Ca cations; wherein D represents inorganic anions of valence 1-3, represented by w; wherein z is equal to or greater than zero and represents the number of D anions; wherein, in formula II, vr represents an amount of R anions to substantially satisfy the valence requirements of Li; wherein, in formula III, r>z and (vr + wz) represents an amount of combined anions, R and A, to substantially satisfy the valence requirements of M; with m representing the number of divalent M cations and having a numerical value in the range of 1 to 4, are found to improve the coefficient of friction and antiwear properties of lubrication fluids subjected to shearing, rubbing, or grinding forces at elevated pressure. Also, useful compositions are prepared by incorporating into organic materials, crystalline lithium aluminates of formula I.
Abstract:
Novel compositions useful as fluid gelling agents, especially for use in subterranean applications such as drilling fluids, are prepared by reacting an aqueous dispersion of a clay, such as bentonite, with an aqueous gel of a monodispersed mixed metal layered hydroxide.
Abstract:
A grease composition containing: (a) the reaction product of: (i) a calcium containing overbased organic acid; and (ii) at least one acid producing compound or derivatives thereof selected from the group consisting of: (1) a non-polymeric hydrocarbyl substituted dicarbonyl derivative selected from the group consisting of an acid, an ester, a salt, an anhydride, ester-acid, acid-salt and mixtures thereof; (2) a copolymer derived from monomers containing (1) an olefin; and (2) an unsaturated dicarboxylic acid anhydride or derivatives thereof; and (3) an inorganic acid containing about 2 or more acidic hydrogens; and (b) an oil of lubricating viscosity, wherein the overbased calcium sulphonate contains colloidally dispersed calcium carbonate is selected from the group consisting of calcite, vaterite and mixtures thereof. The invention further relates to the process to make the composition and its use in greases to increase water resistance.
Abstract:
The present invention provides a rolling apparatus comprising a movable member which can undergo rotary or linear motion, a support member which carries the movable member, rolling elements which are interposed between the movable member and the support member and which roll with the movement of the movable member, and a lubricant composition which is disposed between the movable member on which the rolling elements roll and the support member, wherein the lubricant composition is a mixture of (1) a thickening agent which is at least one selected from the group consisting of a solid fluoropolymer, a lamellar mineral powder, an ultrafinely particulate organic material, an organic solid lubricant and an ultrafinely particulate inorganic material, and (2) a base oil comprising a liquid fluorinated polymer oil.
Abstract:
The present invention provides a grease composition which is excellent in peel resistance, not to mention lubricity, as compared with the prior art products. A novel grease composition for rolling bearing is provided, comprising a base oil, an extender, an inorganic compound-based filler having an average particle diameter of not more than 2 &mgr;m and zinc dithiocarbamate.
Abstract:
Low bleed silicone grease compositions are prepared by blending high viscosity silicone oils with filler materials and/or silicone elastomers. Greases comprise three main types: I) grease comprising high viscosity silicone oil and filler material, II) grease comprising high viscosity silicone oil and silicone elastomer, and III) grease comprising high molecular weight silicone oil and filler material and silicone elastomer.
Abstract:
Elastic solids having reversible stress-induced fluidity are prepared, e.g., by combining liquid formulations with a crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.a) (A.sup.n).sub.a.xH.sub.2 Owhere m is amount of Li, d is amount of divalent metal D, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n and a is the amount of A, and xH.sub.2 O represents excess waters of hydration, if any. These make useful coatings.The instantly reversible fluidization of these unique elastic solids may be expressed as:.tau.=ka.epsilon.,When .epsilon.