Abstract:
PURPOSE: A manufacturing method of an electrocatalyst is provided to have a narrow particle size distribution, a small alloy particle size, a high carrier dispersion amount and uniformity, and low agglomeration due to temperature. CONSTITUTION: A manufacturing method of an electrocatalyst comprises a step of obtaining a carbon solution; a step of obtaining a precursor solution; a step of obtaining a mixed solution by mixing the carbon solution and the precursor solution; a step of preparing a stabilizer solution; a step of obtaining a stabilizer mixed solution by adding the stabilizer solution into the mixed solution; a step of manufacturing a reductant solution; a step of conduct the reaction between the stabilizer mixed solution and the reductant solution; a step of manufacturing a catalyst by removing suspended materials and washing and drying residues; and a step of treating the catalyst with heat.
Abstract:
PURPOSE: Ceria composition is provided to enable low temperature sintering of ceria electrolyte for high temperature sensor or solid oxide fuel cell by adding lithium salt with a low melting point and/or volatility into a material in a ceria system or additionally adding bismuth oxide. CONSTITUTION: A ceria composition is composed of ceria or metal doped ceria, and lithium salt. The lithium salt occupies more than 0 weight% but less than 50 weight% among the ceria composition. The lithium salt is lithium carbonate, lithium hydroxide, or lithium nitride. The ceria composition additionally contains bismuth oxide. A sintering body is a sintering body of the ceria composition which comprises ceria or metal doped ceria, lithium carbonate, and bismuth oxide. The ceria composition contains lithium carbonate with more than 0 weight% but more or less than 5 weight% and bismuth oxide with more than 0 weight% but less than 10 weight% in the sintering body. A ceria complex electrolyte powder is a calcined body of the ceria composition. The ceria composition is composed of ceria or metal doped ceria, and lithium salt and the lithium salt occupies more than 0 weight% but less than 50 weight% in the calcined body.
Abstract:
PURPOSE: An in-situ method of evaluating the degradation of a membrane-electrolyte assembly is provided to detect the cell deterioration state of a fuel cell in real time and to remarkably reduce the sensing and analyzing time. CONSTITUTION: An in-situ method of evaluating the degradation of a membrane-electrolyte assembly comprises a current supply apparatus constantly supplying current by being connected to two coupling plates of a fuel cell stack; a voltage measuring apparatus measuring a voltage between two separators selected from (n+1) separators in the fuel cell stack; and a physical property determining apparatus determining a constant current, the capacity of an electric double layer, roughness factor, and electrochemical active surface area from the current value of the current supply apparatus and the voltage between the separators. [Reference numerals] (AA) Stack real-time measuring device; (BB) Current generator; (CC) Membrane electrode assembly; (DD) Separator
Abstract:
본발명은연료전지촉매및 그제조방법에관한것으로, 본발명의연료전지촉매는폴리도파민이코팅된담지체를포함하는촉매를사용하여촉매층을형성할시 발생하는촉매입자간응집문제를해결하여고밀도, 고분산의촉매층을갖는막-전극접합체를제조할수 있다. 또한, 본발명의연료전지촉매의제조방법은폴리도파민이코팅된담지체를포함하는촉매와고체상의할로젠화물을단순열처리하는 solid to solid 건식합성법으로합성에필요한용매가필요하지않고, 합성이후용매를사용하는워싱과정과시료획득을위한추출과정이필요하지않아단시간내에연료전지촉매를제조할수 있다.
Abstract:
막 전극 접합체는, 양이온 교환막 전극 접합체 및 음이온 교환막 전극 접합체를 포함한다. 상기 양이온 교환막 전극 접합체는 양이온 교환막, 상기 양이온 교환막 상부에 배치되는 제1 캐소드 전극, 상기 양이온 교환막 하부에 배치되는 제1 애노드 전극을 포함한다. 상기 음이온 교환막 전극 접합체는 음이온 교환막, 상기 음이온 교환막 상부에 배치되는 제2 캐소드 전극, 상기 음이온 교환막 하부에 배치되는 제2 애노드 전극을 포함한다. 상기 양이온 교환막 및 음이온 교환막은 부분적으로 접촉하며, 상기 제1 캐소드 전극, 제1 애노드 전극, 제2 캐소드 전극 및 제2 애노드 전극은 서로 접촉하지 않는다.