公开(公告)号：KR1020120094364A

公开(公告)日：2012-08-24

申请号：KR1020110013821

申请日：2011-02-16

Applicant: 한국생산기술연구원

Inventor： 조진구 ,  김상용 ,  이도훈 ,  조재훈 ,  김보라 ,  정재원

IPC: B01J27/132 ,  C07D307/50

Abstract: PURPOSE: A metal catalytic composition for directly manufacturing furfural derivatives based on wood-based biomass materials and a method for directly manufacturing the furfural derivatives from the wood-based biomass materials using the same are provided to reduce costs required for raw materials and to raise yield. CONSTITUTION: A metal catalytic composition for directly manufacturing furfural derivatives based on wood-based biomass materials includes MXn or MXn·H_2O. In MXn or MXn·H_2O, M is a metal element; X is one of a halogen element, triflate, nonaflate, mesylate, tosylate, or diazonium-based function group; and n is 1 to 3. The content of MXn or MXn·H_2O is 1 to 20 mol% based on 100 mol% of the wood-based biomass materials. The metal element is one of manganese(Mn), nickel(Ni), iron(Fe), chrome(Cr), copper(Cu), cobalt(Co), ruthenium(Ru), tin(Sn), zinc(Zn), aluminum(Al), cerium(Ce), lanthanum(La), neodymium(Nd), scandium(Sc), ytterbium(Yb), or indium(In).

Abstract translation: 目的：提供一种用于直接制造基于木质生物质材料的糠醛衍生物的金属催化组合物，以及使用该金属催化组合物从使用其的木基生物质材料直接制造糠醛衍生物的方法，以降低原料所需的成本并提高产量 。 构成：用于直接制造基于木质生物质材料的糠醛衍生物的金属催化组合物包括MXn或MXn·H_2O。 在MXn或MXn·H_2O中，M是金属元素; X是卤素元素，三氟甲磺酸盐，壬酸盐，甲磺酸盐，甲苯磺酸盐或重氮基官能团之一; n为1〜3。基于木质生物质材料的100摩尔％，MXn或MXn·H_2O的含量为1〜20摩尔％。 金属元素是锰（Mn），镍（Ni），铁（Fe），铬（Cr），铜（Cu），钴（Co），钌（Ru），锡（Sn） ，铝（Al），铈（Ce），镧（La），钕（Nd），钪（Sc），镱（Yb）或铟（In）。

公开(公告)号：KR1020110123223A

公开(公告)日：2011-11-14

申请号：KR1020110042995

申请日：2011-05-06

Applicant: 한국생산기술연구원

Inventor： 김백진 ,  최전모 ,  조진구 ,  이은영 ,  김상용 ,  이도훈

IPC: C08G59/20 ,  C07D303/12 ,  C07D407/14 ,  C09J163/00

Abstract: PURPOSE: A manufacturing method of a phloroglucinol-based acrylate is provided to manufacture Phloroglucinol-based acrylate having a superior refractiveness, optical transmittance, adhesive property, coating property and high surface hardness with a high yield by a simple process. CONSTITUTION: A manufacturing method of Phloroglucinol-based acrylate comprises: a step oxidizing the trinitrotoluene thereby manufacturing a 2,4,6-trinitrobenzoic acid; a step deoxidizing the 2,4,6-trinitrobenzoic acid thereby manufacturing a 2,4,6-triaminobenzoic acid; a step manufacturing a phloroglucinol by a hydoxy group substitution reaction of the 2,4,6-triaminobenzoic acid; and a step insert the compound of the chemical formula 1 into the phloroglucinol, and then manufacturing a phloroglucinol-based acrylate by reacting the materials. The phloroglucinol-based acrylate is in the chemical formula 2.

Abstract translation: 目的：提供间苯三酚基丙烯酸酯的制造方法，通过简单的方法以高产率制造具有优异的折射率，光透射率，粘合性，涂布性和高表面硬度的间苯三酚类丙烯酸酯。 构成：基于间苯三酚的丙烯酸酯的制造方法包括：氧化三硝基甲苯从而制造2,4,6-三硝基苯甲酸的步骤; 使2,4,6-三硝基苯甲酸脱氧，从而制造2,4,6-三氨基苯甲酸; 通过2,4,6-三氨基苯甲酸的羟基取代反应制备间苯三酚的步骤; 并且将化学式1的化合物插入间苯三酚中，然后通过使材料反应来制造间苯三酚基丙烯酸酯。 间苯三酚基丙烯酸酯为化学式2。

公开(公告)号：KR1020110123222A

公开(公告)日：2011-11-14

申请号：KR1020110042970

申请日：2011-05-06

Applicant: 한국생산기술연구원

Inventor： 김백진 ,  최전모 ,  조진구 ,  이은영 ,  김상용 ,  이도훈

IPC: C07C67/14 ,  C07C69/017 ,  C07C69/54 ,  C07C69/773

Abstract: PURPOSE: A manufacturing method of a phloroglucinol-based acrylate is provided to manufacture Phloroglucinol-based acrylate having superior refractiveness, optical transmittance, adhesive property, coating property and high surface hardness with a high yield by a simple process. CONSTITUTION: A manufacturing method of Phloroglucinol-based acrylate comprises: a step oxidizing the trinitrotoluene thereby manufacturing a 2,4,6-trinitrobenzoic acid; a step deoxidizing the 2,4,6-trinitrobenzoic acid thereby manufacturing a 2,4,6-triaminobenzoic acid; a step manufacturing a phloroglucinol by a hydoxy group substitution reaction of the 2,4,6-triaminobenzoic acid; and a step insert the compound of the chemical formula 1 into the phloroglucinol, and then manufacturing a phloroglucinol-based acrylate by reacting the materials. The phloroglucinol-based acrylate is in the chemical formula 2.

Abstract translation: 目的：提供间苯三酚基丙烯酸酯的制造方法，通过简单的方法以高产率制造具有优异的折射率，光透射率，粘合性，涂布性和高表面硬度的间苯三酚类丙烯酸酯。 构成：基于间苯三酚的丙烯酸酯的制造方法包括：氧化三硝基甲苯从而制造2,4,6-三硝基苯甲酸的步骤; 使2,4,6-三硝基苯甲酸脱氧，从而制造2,4,6-三氨基苯甲酸; 通过2,4,6-三氨基苯甲酸的羟基取代反应制备间苯三酚的步骤; 并且将化学式1的化合物插入间苯三酚中，然后通过使材料反应来制造间苯三酚基丙烯酸酯。 间苯三酚基丙烯酸酯为化学式2。

公开(公告)号：KR1020110026670A

公开(公告)日：2011-03-16

申请号：KR1020090084425

申请日：2009-09-08

Applicant: 한국생산기술연구원 ,  학교법인 선목학원

Inventor： 조진구 ,  김백진 ,  김상용 ,  이도훈 ,  이상협 ,  이재성

IPC: C07D407/14 ,  A61K31/06

CPC classification number: C07D493/08 ,  A61K31/06 ,  C08F2/48 ,  C08G59/04

Abstract: PURPOSE: A biomass-derived curable bicyclic compound and a method for preparing the same are provided to obtain curing material with low shrinkage. CONSTITUTION: A biomass-derived curable bicyclic compound is denoted by one of chemical formula I-V. The curable bicyclic compound has a basic framework and has one or two epoxide functional groups. A solvent-free curable composition contains the biomass-derived curable bicyclic compound and initiator or hardener. The initiator is a cationic curing initiator. A method for preparing the curing bicyclic compound comprises: a step of preparing maleic anhydride and furan from cellulose and hemicellulose; a step of performing Diels-Alder reaction and continuous reduction of the maleic anhydride and furan; a step of preparing an intermediate compound containing bicycle and two alcohol functional groups; and a step of reacting the intermediate compound and epichlorohydrin.

Abstract translation: 目的：提供生物质衍生的可固化双环化合物及其制备方法，以获得低收缩率的固化材料。 构成：由生物质衍生的可固化双环化合物由化学式I-V之一表示。 可固化双环化合物具有碱性骨架并具有一个或两个环氧官能团。 无溶剂的可固化组合物含有生物质衍生的可固化双环化合物和引发剂或硬化剂。 引发剂是阳离子固化引发剂。 制备固化双环化合物的方法包括：从纤维素和半纤维素制备马来酸酐和呋喃的步骤; 进行Diels-Alder反应和连续还原马来酸酐和呋喃的步骤; 制备含有自行车的中间体化合物和两个醇官能团的步骤; 和使中间体化合物和表氯醇反应的步骤。

公开(公告)号：KR101010290B1

公开(公告)日：2011-01-25

申请号：KR1020080052386

申请日：2008-06-04

Applicant: 한국생산기술연구원

Inventor： 김상용 ,  조재훈 ,  조진구 ,  이도훈 ,  이준석 ,  박철환 ,  박용석

IPC: C09B62/012 ,  C09B62/00

Abstract: 본 발명은 (a) 하기 화학식 1의 발색단과 trichlorotriazine을 결합시켜 색소중간체를 제조하는 단계, (b) 상기 색소중간체에 NH
4 OH를 첨가하여 Reactive Black 8 이 20 ~ 25 중량 % 포함된 염료합성액을 제조하는 단계, (c) 상기 염료합성액에 10 ~ 15 중량%의 염을 첨가하여 혼합액을 제조하는 단계 및 (d) 상기 혼합액에서 석출되는 Reactive Black 8 을 여과하는 단계를 포함하는 Reactive Black 8 의 생산을 위한 염석결정화 방법에 관한 것이다.

또한, 본 발명은 상기의 방법으로 생산된 Reactive Black 8 에 관한 것이다.
염석결정화, 염료, Reactive Black 8

公开(公告)号：KR102144418B1

公开(公告)日：2020-08-12

申请号：KR1020180130885

申请日：2018-10-30

Applicant: 한국생산기술연구원

Inventor： 이홍식 ,  김상용 ,  이도훈

IPC: C10G3/00 ,  C10L1/32 ,  B01J19/18 ,  B01J19/00

公开(公告)号：KR1020140054578A

公开(公告)日：2014-05-09

申请号：KR1020120120233

申请日：2012-10-29

Applicant: 한국생산기술연구원

Inventor： 이도훈 ,  김상용 ,  조진구 ,  정상호 ,  엄희준 ,  김민성 ,  이명석 ,  이관영

IPC: B01J37/08 ,  B01J23/46 ,  C07D307/32

CPC classification number: B01J23/462 ,  B01J35/1023 ,  B01J35/1061 ,  B01J37/00 ,  C07D307/33

Abstract: The present invention relates to a method by which a ruthenium nanoparticle-carrying silica catalyst can be obtained from a synthetic solvent without a process of separating ruthenium nanoparticles. The present invention relates to the ruthenium nanoparticle-carrying silica catalyst produced by the method, and a method for producing gamma-butyrolactone by a hydrogenation reaction of succinic anhydride.

Abstract translation: 本发明涉及不用分离钌纳米粒子的方法，由合成溶剂得到载有钌纳米颗粒的二氧化硅催化剂的方法。 本发明涉及通过该方法制备的载有钌纳米粒子的二氧化硅催化剂，以及通过琥珀酸酐的氢化反应制备γ-丁内酯的方法。

公开(公告)号：KR1020130070970A

公开(公告)日：2013-06-28

申请号：KR1020110138254

申请日：2011-12-20

Applicant: 한국생산기술연구원

Inventor： 김백진 ,  조진구 ,  김종석 ,  김승택 ,  김선희 ,  이도훈

IPC: C09J11/06 ,  C09J4/00 ,  C09J5/00

CPC classification number: C09J4/00 ,  C08K5/17 ,  C09J11/06

Abstract: PURPOSE: An adhesive material is provided to have high adhesion, excellent light transmittance, and excellent hardness. CONSTITUTION: An adhesive material includes a compound represented by chemical formula 1. In chemical formula 1, each of R^1-R^6 is hydrogen, deuterium, a substituted or non-substituted C1-30 alkyl group, a substituted or non-substituted C6-30 aryl group, or a substituted or non-substituted C2-30 heteroaryl group. An adhesive composition includes the adhesive material and a photoinitiator. A curing method of the adhesive composition comprises a step of preparing the adhesive composition; a step of spreading the adhesive composition onto a substrate; and a step of curing the adhesive composition.

Abstract translation: 目的：提供粘合材料以具有高粘附性，优异的透光性和优异的硬度。 构成：粘合剂材料包括由化学式1表示的化合物。在化学式1中，R 1〜R 6中的每一个为氢，氘，取代或未取代的C 1-30烷基， 取代的C 6-30芳基，或取代或未取代的C 2-30杂芳基。 粘合剂组合物包括粘合剂材料和光引发剂。 粘合剂组合物的固化方法包括制备粘合剂组合物的步骤; 将粘合剂组合物铺展到基材上的步骤; 和固化粘合剂组合物的步骤。

公开(公告)号：KR1020130052221A

公开(公告)日：2013-05-22

申请号：KR1020110117544

申请日：2011-11-11

Applicant: 한국생산기술연구원

Inventor： 김상용 ,  조진구 ,  이도훈 ,  전계택 ,  신우식

IPC: C12N1/14 ,  C12N15/01 ,  C12N1/38 ,  C12R1/66

Abstract: PURPOSE: A method for quickly screening Aspergillus terreus strains with high itaconic acid productivity is provided to quickly and efficiently select a strain with high itaconic acid productivity. CONSTITUTION: A method for quickly screening strains with high itaconic acid productivity comprises: a step of culturing Aspergillus terreus mutant strain on a PDA plate; a step of selecting strains with a colony diameter of 1.3 mm or greater; a step of culturing the selected strains in a PDA slant; and a step of selecting strains with a colony diameter of 10 mm or greater and a spore forming rate of 55% or more.

Abstract translation: 目的：快速筛选具有高衣康酸生产力的土曲霉菌株快速有效选择具有高衣康酸生产力的菌株的方法。 构成：用于快速筛选具有高衣康酸生产力的菌株的方法包括：在PDA板上培养土曲霉菌突变菌株的步骤; 选择菌落直径为1.3mm以上的菌株的步骤; 在PDA倾斜中培养所选择的菌株的步骤; 以及选择菌落直径为10mm以上，孢子形成率为55％以上的菌株的步骤。

公开(公告)号：KR101263324B1

公开(公告)日：2013-05-15

申请号：KR1020110042995

申请日：2011-05-06

Applicant: 한국생산기술연구원

Inventor： 김백진 ,  최전모 ,  조진구 ,  이은영 ,  김상용 ,  이도훈

IPC: C08G59/20 ,  C07D303/12 ,  C07D407/14 ,  C09J163/00

Abstract: 본발명은트리니트로톨루엔을산화시켜 2,4,6-트리니트로벤조산(2,4,6-trinitrobenzoic acid)을제조하는단계(a); 2,4,6-트리니트로벤조산을환원시켜 2,4,6-트리아미노벤조산(2,4,6-triaminobenzoic acid)을제조하는단계(b); 2,4,6-트리아미노벤조산을히드록시기치환반응으로플로로글루시놀(phloroglucinol)을제조하는단계(c); 및플로로글루시놀에할로겐화에폭시화합물을투입하고반응시켜플로로글루시놀계에폭시를제조하는단계(d);를포함하는플로로글루시놀계에폭시의제조방법을제공함으로서폐탄약을처리함에따른문제점을해결하며동시에접착성, 코팅성, 광학특성및 경도가우수한플로로글루시놀계에폭시의제조방법을제공한다.