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公开(公告)号:WO2011036002A1
公开(公告)日:2011-03-31
申请号:PCT/EP2010/062225
申请日:2010-08-23
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , CAPUTO, Tiziana
Inventor: CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , CAPUTO, Tiziana
IPC: C08L23/12 , C08F297/08
CPC classification number: C08L23/12 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2308/00 , C08L2314/02 , C08L2666/06
Abstract: A propylene composition comprising (percent by weight): A) 70%-95%, of a propylene homopolymer having a Polydispersity Index (P.I.) value of from 4.6 to 10, a fraction insoluble in xylene at 25 °C, higher than 90 %, and MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) from 47 to 90 g/10 min; B) 5%-30%, of a copolymer of propylene containing from 40% to 34.5% extremes included of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 3 and 5 dl/g.
Abstract translation: 包含(重量%)的丙烯组合物:A)70%-95%的多分散指数(PI)值为4.6至10的丙烯均聚物,不溶于二甲苯的馏分,25℃,高于90% 和MFR L(根据ISO 1133的熔体流动速率,条件L,即230℃和2.16kg负荷)为47至90g / 10min; B)5%-30%的含有40%至34.5%极限的丙烯的共聚物,包括乙烯衍生单元; 该组合物具有在25℃下可溶于二甲苯的级分的特性粘度为3至5dl / g。
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公开(公告)号:WO2011012491A1
公开(公告)日:2011-02-03
申请号:PCT/EP2010/060461
申请日:2010-07-20
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , PANTALEONI, Roberto
Inventor: CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , PANTALEONI, Roberto
IPC: C08L23/12 , C08F297/08 , C08J5/18
CPC classification number: C08J5/18 , C08F297/083 , C08J2323/12 , C08L23/06 , C08L23/12 , C08L23/16 , C08L2205/03 , C08L2666/02
Abstract: A polymer composition comprising (per cent by weight): a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13 C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.5 molar % and a polydispersity index ranging from 5 to 10; b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt%.
Abstract translation: 包含(重量%)的聚合物组合物:a)57%-74%的具有全同立构五单元组的结晶丙烯聚合物(mmmm),通过13C-MNR测量在25℃下不溶于二甲苯的级分, 高于97.5摩尔%,多分散指数为5〜10; b)8至15%的乙烯和丙烯的弹性体共聚物,所述共聚物具有一定量的衍生自乙烯的重复单元,范围为30至50%,并且在环境温度下部分溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c)18-28%的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为35至60g / 10min,并且己烷可提取物的量低于4.0wt%。
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公开(公告)号:WO2010133434A1
公开(公告)日:2010-11-25
申请号:PCT/EP2010/055788
申请日:2010-04-29
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , CAPUTO, Tiziana , GALVAN, Monica
Inventor: CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , CAPUTO, Tiziana , GALVAN, Monica
IPC: C08F297/08 , C08L23/14
CPC classification number: C08F297/083 , C08L23/14 , C08L23/142 , C08L2205/02 , C08L2666/06
Abstract: A propylene composition comprising (percent by weight): A) 60%-90%, of a crystalline propylene copolymer containing from 3.5% to 10% of ethylene derived units; B) 10%-40%, of a copolymer of propylene containing from 18.5% to 23.5%, of ethylene derived units.
Abstract translation: 包含(重量%)的丙烯组合物:A)60%-90%的含有3.5%至10%乙烯衍生单元的结晶丙烯共聚物; B)10%-40%的丙烯共聚物,其含有18.5%至23.5%的乙烯衍生单元。
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公开(公告)号:WO2009050045A3
公开(公告)日:2009-04-23
申请号:PCT/EP2008/063243
申请日:2008-10-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , SUNALLOMER LTD , MASSARI, Paola , CIARAFONI, Marco , FUSCO, Ofelia , MURAKAMI, Hirofumi , NAKAJIMA, Takeshi , TAKEMIYA, Shintaro
Inventor: MASSARI, Paola , CIARAFONI, Marco , FUSCO, Ofelia , MURAKAMI, Hirofumi , NAKAJIMA, Takeshi , TAKEMIYA, Shintaro
IPC: C08F210/06 , C08F4/646 , C08F4/651
Abstract: Process for the production of propylene polymers having a Melt Flow rate (230°C, 2.16 Kg) higher than 30 g/10' and preferably higher than 50 g/10' and also characterized by having broad molecular weight distribution (MWD) carried out in the presence of a catalyst system comprising (a) a solid catalyst component containing Mg, Ti, halogen and an electron donor compound selected from succinates; (b) an alkylaluminum cocatalyst; and (c) a silicon compound of formula R 1 Si(OR) 3 in which R 1 is a branched alkyl and R is, independently, a C1-C10 alkyl.
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公开(公告)号:WO2008061843A1
公开(公告)日:2008-05-29
申请号:PCT/EP2007/060756
申请日:2007-10-10
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MARZOLLA, Roberta , CIARAFONI, Marco , GRAZZI, Michele , MASSARI, Paola , NEWS, Jean
Inventor: MARZOLLA, Roberta , CIARAFONI, Marco , GRAZZI, Michele , MASSARI, Paola , NEWS, Jean
CPC classification number: C08J5/18 , C08F210/06 , C08J2323/10 , C08L23/08 , C08L23/10 , C08L2666/06 , C08F2/001 , C08F4/6492 , C08F110/06 , C08F2500/12 , C08F210/16 , C08F210/08 , C08F2500/17
Abstract: Polyo lefin compositions, comprising (percent by weight): 1) 55-80% of a homopolymer or copolymer of propylene, said copolymer containing up to 15% of ethylene and/or C4-C10 -olefin(s). 2) 20-45% of a copolymer of ethylene with one or more C4-C10 -olefin(s) containing from 10 to 40% of said C4-C10 -olefin(s); said compositions having values of MFR (230 °C, 2.16 kg) up to 20 g/10 min, a total content of ethylene of 20% or more, a total content of C4-C10 -olefin(s) of 4.5% or more, a ratio of the total content of ethylene to the total content of C4-C10 -olefin(s) of 2.3 or more, a total fract ion soluble in xylene at room temperature of 18 wt% or higher and flexural modulus, referred to the composition as a reactor grade, of more than 700 MPa.
Abstract translation: 包含(重量%)的多元醇组合物:1)55-80%的丙烯均聚物或共聚物,所述共聚物含有至多15%的乙烯和/或C 4 -C 10α-烯烃。 2)乙烯与一种或多种含有10-40%所述C 4 -C 10α-烯烃的C 4 -C 10α-烯烃的共聚物的20-45%; 所述组合物的MFR(230℃,2.16kg)至多20g / 10min,乙烯的总含量为20%以上,C4-C10-烯烃的总含量为4.5%以上 ,乙烯的总含量与C4-C10-烯烃的总含量的比例为2.3以上,在室温下可溶于二甲苯的总分解离子的总重量为18重量%以上,弯曲弹性模量,称为 组成为反应器级,超过700MPa。
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公开(公告)号:WO2007060114A1
公开(公告)日:2007-05-31
申请号:PCT/EP2006/068423
申请日:2006-11-14
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
Inventor: MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
CPC classification number: C08F210/06 , C08F110/06 , C08L23/0815 , C08L23/10 , C08L23/14 , C08L2205/03 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F2500/04 , C08F2500/15 , C08F210/16 , C08F2500/17 , C08F2500/11
Abstract: The present invention provides polyolefin composition comprising a 50-80 wt% of propylene omopolymer or copolymer and a first and a second ethylene/alpha-olefin copolymer, said composition having good stress whitening resistance and gloss, in combination with a good balance of mechanical properties.
Abstract translation: 本发明提供了包含50-80重量%丙烯含量聚合物或共聚物和第一和第二乙烯/α-烯烃共聚物的聚烯烃组合物,所述组合物具有良好的耐应力增白性和光泽,以及机械性能的良好平衡 。
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公开(公告)号:WO2006067023A1
公开(公告)日:2006-06-29
申请号:PCT/EP2005/056264
申请日:2005-11-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
Inventor: MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
CPC classification number: C08L23/10 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/12 , C08L23/142 , C08L23/16 , C08L2205/03 , C08L2666/02 , C08F210/06 , C08F2/001 , C08F4/6492 , C08F4/651
Abstract: A polypropylene composition comprising (per cent by weight) (a) 50-77% of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.5 molar % and a polydispersity index ranging from 4 to 10; (b) 13-28% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 70% and being partially soluble in xylene at ambient temperature, the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2 to 4 dl/g; and (c) 10-22% of polyethylene having an intrinsic viscosity value ranging from 1 to 3 dl/g, in said composition component (b) plus component (c) being in amounts of at least 25 wt%. The polymer composition exhibits good impact resistant, whitening resistance and relatively low stiffness.
Abstract translation: 包含(重量百分数)(a)50-77%的具有全同立构五单元组(Mwmm)的结晶丙烯聚合物的聚丙烯组合物,其通过13C-MNR测量在25℃下不溶于二甲苯的级分,高于 97.5摩尔%,多分散指数为4〜10; (b)13-28%的乙烯和丙烯的弹性体共聚物,该共聚物具有一定量的衍生自乙烯的重复单元,范围为30至70%,并且在环境温度下部分溶于二甲苯,聚合物馏分可溶于二甲苯 环境温度的特性粘度值范围为2至4dl / g; 和(c)所述组合物组分(b)加组分(c)的特性粘度值为1至3dl / g的聚乙烯的10-22%的量为至少25重量%。 聚合物组合物表现出良好的抗冲击性,耐白化性和相对低的刚度。
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公开(公告)号:EP4448653A1
公开(公告)日:2024-10-23
申请号:EP22823010.8
申请日:2022-11-29
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: GALVAN, Monica , GRAZZI, Michele , CIARAFONI, Marco , DI CAPUA, Alessia , BASILE, Lelio
IPC: C08L23/14
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公开(公告)号:EP3911702A1
公开(公告)日:2021-11-24
申请号:EP20700106.6
申请日:2020-01-07
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: GALVAN, Monica , GRAZZI, Michele , CIARAFONI, Marco , CAVALIERI, Claudio
IPC: C08L23/16
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公开(公告)号:EP3083820B1
公开(公告)日:2020-11-25
申请号:EP14821562.7
申请日:2014-12-15
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MASSARI, Paola , CIARAFONI, Marco , WILLEMS, Sander , ROHRMANN, Jürgen
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