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公开(公告)号:WO2009050045A3
公开(公告)日:2009-04-23
申请号:PCT/EP2008/063243
申请日:2008-10-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , SUNALLOMER LTD , MASSARI, Paola , CIARAFONI, Marco , FUSCO, Ofelia , MURAKAMI, Hirofumi , NAKAJIMA, Takeshi , TAKEMIYA, Shintaro
Inventor: MASSARI, Paola , CIARAFONI, Marco , FUSCO, Ofelia , MURAKAMI, Hirofumi , NAKAJIMA, Takeshi , TAKEMIYA, Shintaro
IPC: C08F210/06 , C08F4/646 , C08F4/651
Abstract: Process for the production of propylene polymers having a Melt Flow rate (230°C, 2.16 Kg) higher than 30 g/10' and preferably higher than 50 g/10' and also characterized by having broad molecular weight distribution (MWD) carried out in the presence of a catalyst system comprising (a) a solid catalyst component containing Mg, Ti, halogen and an electron donor compound selected from succinates; (b) an alkylaluminum cocatalyst; and (c) a silicon compound of formula R 1 Si(OR) 3 in which R 1 is a branched alkyl and R is, independently, a C1-C10 alkyl.
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公开(公告)号:WO2008061843A1
公开(公告)日:2008-05-29
申请号:PCT/EP2007/060756
申请日:2007-10-10
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MARZOLLA, Roberta , CIARAFONI, Marco , GRAZZI, Michele , MASSARI, Paola , NEWS, Jean
Inventor: MARZOLLA, Roberta , CIARAFONI, Marco , GRAZZI, Michele , MASSARI, Paola , NEWS, Jean
CPC classification number: C08J5/18 , C08F210/06 , C08J2323/10 , C08L23/08 , C08L23/10 , C08L2666/06 , C08F2/001 , C08F4/6492 , C08F110/06 , C08F2500/12 , C08F210/16 , C08F210/08 , C08F2500/17
Abstract: Polyo lefin compositions, comprising (percent by weight): 1) 55-80% of a homopolymer or copolymer of propylene, said copolymer containing up to 15% of ethylene and/or C4-C10 -olefin(s). 2) 20-45% of a copolymer of ethylene with one or more C4-C10 -olefin(s) containing from 10 to 40% of said C4-C10 -olefin(s); said compositions having values of MFR (230 °C, 2.16 kg) up to 20 g/10 min, a total content of ethylene of 20% or more, a total content of C4-C10 -olefin(s) of 4.5% or more, a ratio of the total content of ethylene to the total content of C4-C10 -olefin(s) of 2.3 or more, a total fract ion soluble in xylene at room temperature of 18 wt% or higher and flexural modulus, referred to the composition as a reactor grade, of more than 700 MPa.
Abstract translation: 包含(重量%)的多元醇组合物:1)55-80%的丙烯均聚物或共聚物,所述共聚物含有至多15%的乙烯和/或C 4 -C 10α-烯烃。 2)乙烯与一种或多种含有10-40%所述C 4 -C 10α-烯烃的C 4 -C 10α-烯烃的共聚物的20-45%; 所述组合物的MFR(230℃,2.16kg)至多20g / 10min,乙烯的总含量为20%以上,C4-C10-烯烃的总含量为4.5%以上 ,乙烯的总含量与C4-C10-烯烃的总含量的比例为2.3以上,在室温下可溶于二甲苯的总分解离子的总重量为18重量%以上,弯曲弹性模量,称为 组成为反应器级,超过700MPa。
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公开(公告)号:WO2007060114A1
公开(公告)日:2007-05-31
申请号:PCT/EP2006/068423
申请日:2006-11-14
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
Inventor: MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
CPC classification number: C08F210/06 , C08F110/06 , C08L23/0815 , C08L23/10 , C08L23/14 , C08L2205/03 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F2500/04 , C08F2500/15 , C08F210/16 , C08F2500/17 , C08F2500/11
Abstract: The present invention provides polyolefin composition comprising a 50-80 wt% of propylene omopolymer or copolymer and a first and a second ethylene/alpha-olefin copolymer, said composition having good stress whitening resistance and gloss, in combination with a good balance of mechanical properties.
Abstract translation: 本发明提供了包含50-80重量%丙烯含量聚合物或共聚物和第一和第二乙烯/α-烯烃共聚物的聚烯烃组合物,所述组合物具有良好的耐应力增白性和光泽,以及机械性能的良好平衡 。
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64.
公开(公告)号:WO2006067023A1
公开(公告)日:2006-06-29
申请号:PCT/EP2005/056264
申请日:2005-11-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
Inventor: MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
CPC classification number: C08L23/10 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/12 , C08L23/142 , C08L23/16 , C08L2205/03 , C08L2666/02 , C08F210/06 , C08F2/001 , C08F4/6492 , C08F4/651
Abstract: A polypropylene composition comprising (per cent by weight) (a) 50-77% of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.5 molar % and a polydispersity index ranging from 4 to 10; (b) 13-28% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 70% and being partially soluble in xylene at ambient temperature, the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2 to 4 dl/g; and (c) 10-22% of polyethylene having an intrinsic viscosity value ranging from 1 to 3 dl/g, in said composition component (b) plus component (c) being in amounts of at least 25 wt%. The polymer composition exhibits good impact resistant, whitening resistance and relatively low stiffness.
Abstract translation: 包含(重量百分数)(a)50-77%的具有全同立构五单元组(Mwmm)的结晶丙烯聚合物的聚丙烯组合物,其通过13C-MNR测量在25℃下不溶于二甲苯的级分,高于 97.5摩尔%,多分散指数为4〜10; (b)13-28%的乙烯和丙烯的弹性体共聚物,该共聚物具有一定量的衍生自乙烯的重复单元,范围为30至70%,并且在环境温度下部分溶于二甲苯,聚合物馏分可溶于二甲苯 环境温度的特性粘度值范围为2至4dl / g; 和(c)所述组合物组分(b)加组分(c)的特性粘度值为1至3dl / g的聚乙烯的10-22%的量为至少25重量%。 聚合物组合物表现出良好的抗冲击性,耐白化性和相对低的刚度。
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公开(公告)号:WO2006037705A1
公开(公告)日:2006-04-13
申请号:PCT/EP2005/054370
申请日:2005-09-05
Applicant: Basell Poliolefine Italia s.r.l. , MASSARI, Paola , NEUMANN, Andreas , COLLINA, Gianni , FUSCO, Ofelia
Inventor: MASSARI, Paola , NEUMANN, Andreas , COLLINA, Gianni , FUSCO, Ofelia
IPC: C08L23/10
CPC classification number: C08F210/06 , C08F10/00 , C08F110/06 , C08F210/16 , C08L23/0815 , C08L23/10 , C08L23/16 , C08F4/651 , C08F2/001 , C08L2666/06 , C08F2500/15 , C08F2500/12 , C08F2500/17 , C08F2500/04 , C08F210/08 , C08F2500/21 , C08F210/14
Abstract: An olefin polymer composition comprising (by weight, unless otherwise specified): A) 60-85% of a crystalline propylene homopolymer or a crystalline copolymer of propylene containing 3% or less of ethylene or C 4 -C 10 α-olefin(s) or of combinations thereof, said homopolymer or copolymer having a Polydispersity Index (P.I.) value of from 4.5-6 and a content of isotactic pentads (mmmm), measured by 13 C NMR on the fraction insoluble in xylene at 25 °C, higher than 96%; B) 15-40% of a partially amorphous copolymer of ethylene containing from 35% to 70% of propylene or C 4 -C 10 α-olefin(s) or of combinations thereof, and optionally minor proportions of a diene. The said olefin polymer composition exhibits a value of elongation at break ranging from 150 to 600% according to ISO method 527.
Abstract translation: 包含(按重量计,除非另有说明)的烯烃聚合物组合物:A)60-85%的结晶丙烯均聚物或含有3%或更少乙烯或C 4 -C 3的丙烯的结晶共聚物 所述均聚物或共聚物的多分散指数(PI)值为4.5-6,全同立构五单元组(mmmm)的含量由 25℃,高于96%的不溶于二甲苯的级分的13 C NMR; B)15-40%的含有35%至70%丙烯或C 4 -C 10α-烯烃的部分无定形乙烯共聚物或 它们的组合,和任选的少量二烯。 所述烯烃聚合物组合物根据ISO方法527显示出150至600%的断裂伸长率值。
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公开(公告)号:EP4259700A1
公开(公告)日:2023-10-18
申请号:EP21810638.3
申请日:2021-11-25
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MASSARI, Paola , FELISATI, Andrea , CAVALIERI, Claudio , GALVAN, Monica , GRAZZI, Michele
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公开(公告)号:EP3983454A1
公开(公告)日:2022-04-20
申请号:EP20727644.5
申请日:2020-05-26
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: CAVALIERI, Claudio , MASSARI, Paola , CAMURATI, Isabella Maria Vittoria , PANTALEONI, Roberto , COLLINA, Gianni , VITALE, Gianni , CIARAFONI, Marco , GADDI, Benedetta
IPC: C08F210/06 , C08F2/00 , C08J5/18 , C08F210/14 , C08F210/16
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公开(公告)号:EP3890969A1
公开(公告)日:2021-10-13
申请号:EP19801601.6
申请日:2019-11-18
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: FELISATI, Andrea , IZZI, Marco , MASSARI, Paola
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公开(公告)号:EP3140330B1
公开(公告)日:2020-12-09
申请号:EP15720683.0
申请日:2015-04-28
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MASSARI, Paola , PIEMONTESI, Fabrizio , VITALE, Gianni , CATHELIN, Caroline , MORINI, Giampiero , CIARAFONI, Marco , CAVALIERI, Claudio , FELISATI, Andrea
IPC: C08F110/06 , C08F210/06 , C08F4/657 , C08L23/12 , C08L23/14
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公开(公告)号:EP3024857B1
公开(公告)日:2020-09-30
申请号:EP14734145.7
申请日:2014-07-01
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: DESTRO, Mara , CIARAFONI, Marco , MASSARI, Paola , CAPUTO, Tiziana , GUIDICINI, Alessandro
IPC: A61J1/00
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