公开(公告)号：EP0912524B1

公开(公告)日：2002-03-13

申请号：EP97923045.5

申请日：1997-05-09

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： RACK, Michael ,  RÖHL, Franz ,  AMMERMANN, Eberhard ,  HARRIES, Volker ,  LORENZ, Gisela ,  STRATHMANN, Siegfried ,  GROTE, Thomas ,  GRAMMENOS, Wassilios ,  KIRSTGEN, Reinhard ,  OBERDORF, Klaus ,  BAYER, Herbert ,  MÜLLER, Bernd ,  MÜLLER, Ruth ,  SAUTER, Hubert

IPC: C07D239/34 ,  C07D239/52 ,  C07D239/46 ,  A01N43/54

CPC classification number: C07D239/36 ,  A01N43/54 ,  C07D239/34

Abstract: 2-(O-[pyrimidin-4-yl] methylene oxy)phenyl acetic acid derivatives of general formula (I) and their salts and N oxides, in which R1 is halogen, alkyl or alkyl halide; R2 is hydrogen, amino, hydroxy, mercapto, halogen, possibly phenyl-substituted alkyl, alkyl halide, alkoxy alkyl, alkoxy, monoalkyl amino, dialkyl amino, alkylthio, alkyl sulphoxyl, alkylsulphonyl, cycloalkyl, trialkyl silyloxy or phenyl, phenoxy, phenoxy methyl, benzyloxy or heteroaryl possibly substituted in the aromatic ring, R2 being different from R1; R3 is hydrogen, cyano, halogen, C¿1?-C4 alkyl, C1-C4 alkyl halide or C1-C4 alkoxy, and Q is C(=CHCH3)-COOCH3 or C(=CHOCH3)-COOCH3, and their use in combatting noxious fungi and animal pests.

公开(公告)号：EP1131307A1

公开(公告)日：2001-09-12

申请号：EP99960983.7

申请日：1999-11-17

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： RACK, Michael ,  GÖTZ, Norbert ,  HAGEN, Helmut ,  VON DEYN, Wolfgang ,  BAUMANN, Ernst ,  LOCHTMAN, Rene ,  GEBHARDT, Joachim

IPC: C07D261/04

CPC classification number: C07D261/04

Abstract: The invention relates to a novel method of producing the compounds of formula (I) wherein the substituents have the following meanings: n is 0,1 or 2; R1, R2 represent C¿1?-C6-alkyl; R?3, R4, R5¿ are hydrogen, C¿1?-C6-alkyl or R?4 and R5¿ together form a bond; R6 is C1, Br. Said method comprises the following steps: a synthesis sequence starting from 1,2-dialkylbenzenes of formula (II); halogenation to form 3,6-dihalogen-1,2-dialkylbenzenes; haloalkylation to form benzyl bromides; oxidation to form benzaldehydes; reaction with alkenes to form isoxazoles; reaction to form thioethers and optionally oxidation to form sulfenyl or sulfonyl derivatives of formula (I).

公开(公告)号：EP1127050A1

公开(公告)日：2001-08-29

申请号：EP99955919.8

申请日：1999-10-30

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： GÖTZ, Norbert ,  GÖTZ, Roland ,  RACK, Michael

IPC: C07D231/18 ,  C07C243/30 ,  C07C241/04

CPC classification number: C07C243/30 ,  C07D231/20

Abstract: The invention relates to a method for producing substituted hydroxypyrazoles and new intermediate products. It relates in particular to a method for producing compounds of formula (I) in which R1 is hydrogen, an aliphatic group with between 1 and 8 carbon atoms, C¿1?-C6-alkoxycarbonyl, C1-C6-alkyl thiocarbonyl or a cyclic ring system with between 3 and 14 ring atoms; R?2¿ is hydrogen, an aliphatic group with between 1 and 8 carbon atoms; or R?1 and R2¿ together with the carbon atom to which they are bound are a cyclic or bicyclic ring system with between 3 and 14 ring atoms. Said method comprises the production, as starting or intermediate products, of compounds of formula (II) in which R?3 and R4¿ are readily cleavable groups and R?1 and R2¿ have the meanings given above. Said compounds are cyclized under suitable reaction conditions to yield compounds of formula (I).

Abstract translation: 本发明涉及一种制备取代的羟基吡唑和新的中间产物的方法。 本发明特别涉及制备式（I）化合物的方法，其中R 1为氢，具有1至8个碳原子的脂族基团，C 1 -C 6烷氧基羰基，C 1 -C 6烷基硫代羰基或环 具有3至14个环原子的环系; R 2是氢，一个有1到8个碳原子的脂族基团; 或R 1和R 2与它们所键合的碳原子一起是具有3-14个环原子的环状或双环环系。 所述方法包括生产式（II）化合物作为起始或中间产物，其中R 3和R 4是易裂解基团且R 1和R 2具有上述含义。 所述化合物在合适的反应条件下环化生成式（I）的化合物。

公开(公告)号：EP1117636A1

公开(公告)日：2001-07-25

申请号：EP99948764.8

申请日：1999-09-16

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： GROTE, Thomas ,  WOLF, Bernd ,  RACK, Michael ,  GÖTZ, Roland ,  GYPSER, Andreas ,  STEINMETZ, Adrian ,  SAUTER, Hubert ,  KEIL, Michael ,  MAYER, Horst

IPC: C07C249/08 ,  C07C251/34 ,  C07C251/60

CPC classification number: C07C251/38 ,  C07C249/08 ,  C07D317/28 ,  C07D319/06

Abstract: The present invention relates to a method for the production of trion-bis(oxime ether) derivatives of formula (I), wherein the substituents have the following meaning: R1, R3 represent unsubstituted, partially or totally halogenated C¿1?-C6-alkyl or C3-C6-cycloalkyl; R?2, R4¿ represent C¿1?-C4-alkyl or a methyl substituted by C2-C4-alkenyl, C2-C4-alkinyl or phenyl and X represents oxygen or N-OH. The invention also relates to the intermediate products obtained with said method.

公开(公告)号：EP1112256A1

公开(公告)日：2001-07-04

申请号：EP99944541.4

申请日：1999-08-27

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： WITSCHEL, Matthias ,  MISSLITZ, Ulf ,  BAUMANN, Ernst ,  VON DEYN, Wolfgang ,  LANGEMANN, Klaus ,  MAYER, Guido ,  NEIDLEIN, Ulf ,  GÖTZ, Roland ,  GÖTZ, Norbert ,  RACK, Michael ,  ENGEL, Stefan ,  OTTEN, Martina ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut

IPC: C07D215/18 ,  A01N43/42 ,  C07D215/14 ,  C07D215/36 ,  C07D405/12 ,  C07D401/08 ,  C07D401/06 ,  C07F9/60

CPC classification number: C07D401/06 ,  A01N43/42 ,  C07D215/14 ,  C07D215/18 ,  C07D215/36 ,  C07D401/08 ,  C07D405/12 ,  C07F9/60

Abstract: The invention relates to cyclohexenonquinolinoyl derivatives of formula (I), wherein the variables have the following meanings: R1 means hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxyiminomethyl, alkoxy, halogenalkoxy, alkylthio, C1-C6-halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, optionally substituted aminosulfonyl, optionally substituted sulfonylamino, optionally substituted phenoxy, optionally substituted heterocyclyloxy, optionally substituted phenylthio or optionally substited heterocyclylthio; R2, R3 mean hydrogen, alkyl, halogenalkyl or halogen; and R4 means substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene. The invention also relates to the agriculturally useable salts of said derivatives, to a method for producing the derivatives, to agents containing them and to the use of the derivatives or agents containing them for combating undesirable plants.

公开(公告)号：EP1077955A1

公开(公告)日：2001-02-28

申请号：EP99922160.9

申请日：1999-05-04

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： RHEINHEIMER, Joachim ,  VON DEYN, Wolfgang ,  GEBHARDT, Joachim ,  RACK, Michael ,  LOCHTMAN, Rene ,  GÖTZ, Norbert ,  KEIL, Michael ,  WITSCHEL, Matthias ,  HAGEN, Helmut ,  MISSLITZ, Ulf ,  BAUMANN, Ernst

IPC: C07D261/04 ,  C07D413/10 ,  C07C251/40 ,  C07C319/14

CPC classification number: C07C249/06 ,  C07C201/10 ,  C07C201/12 ,  C07C205/44 ,  C07C209/62 ,  C07C251/48 ,  C07C253/00 ,  C07C255/50 ,  C07C315/04 ,  C07C319/14 ,  C07D261/04 ,  C07D413/10 ,  C07C323/09 ,  C07C317/24 ,  C07C317/32 ,  C07C205/06 ,  C07C211/52

Abstract: The invention relates to a method for producing isoxazolene of the formula (I), where the substituents have the following meanings: R1 is hydrogen, C¿1?-C6 alkyl, R?2 is C¿1-C6 alkyl, R?3, R4, R5¿ are hydrogen, C¿1?-C6 alkyl or R?4 and R5¿ together form a linkage, R6 is a heterocyclic ring, and n is 0, 1 or 2. Said method comprises the production of an intermediate compound of the formula (VI) where R?1, R3, R4 and R5¿ have the meanings given above. This step is followed by halogenation, thiomethylation, oxidation and acylation to yield compounds of formula (I). The invention also relates to new intermediate products for producing compounds of formula (I) and new methods for producing the intermediate products.

公开(公告)号：EP0960100A1

公开(公告)日：1999-12-01

申请号：EP97954936.0

申请日：1997-12-19

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HILL, Regina, Luise ,  KARDORFF, Uwe ,  RACK, Michael ,  GÖTZ, Norbert ,  BAUMANN, Ernst ,  VON DEYN, Wolfgang ,  ENGEL, Stefan ,  MAYER, Guido ,  OTTEN, Martina ,  REINHEIMER, Joachim ,  WITSCHEL, Matthias ,  MISSLITZ, Ulf ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto

IPC: A01N ,  C07D ,  C07D231 ,  A01N43 ,  C07D409

CPC classification number: A01N43/56 ,  C07D231/24

Abstract: The invention concerns 4-benzoyl-pyrazoles of formula (I), in which the variables have the following meanings: R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, cyano, alkyl, halogen alkyl, -OR?7, -SR7 or -NR7R10; R4¿ stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or NR8; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted pyrazol linked in position 4. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

Abstract translation: 本发明涉及式（I）的4-苯甲酰基 - 吡唑，其中各变量具有以下含义：R 1，R 2表示氢，硝基，卤素，氰基，rhodano，烷基，卤素烷基，烷氧基烷基，烯基，炔基， - OR 5，-OCOR 6，-OSO 2 R 6，-SH，-S（O）n R 7，-SO 2 OR 5，-SO 2 NR 5 R 8，-NR 8 SO 2 R 6或-NR 8 COR 6; R3代表氢，氰基，烷基，卤代烷基，-OR 7，-SR 7或-NR 7 R 10; R 4代表氢，任选取代的烷基，环烷基，烯基，环烯基，炔基，-COR 9，-CO 2 R 9，-COSR 9或-CONR 8 R 9; X代表氧或NR8; n等于0,1或2; R5代表氢，烷基，卤素烷基，烷氧基烷基，烯基或炔基; R6代表烷基或卤素烷基; R7代表烷基，卤代烷基，烷氧基烷基，烯基或炔基; R8代表氢或烷基; R9代表烷基，烯基，炔基，苯基或苄基; R10代表烷基，卤代烷基，烯基或炔基; Q表示在4位连接的任选取代的吡唑。还公开了用于农业的这些化合物的盐; 用于制备式（I）化合物的方法和中间产物，含有它们的试剂以及这些衍生物的用途或含有它们的试剂用于防治不希望的植物。

公开(公告)号：EP0958291A1

公开(公告)日：1999-11-24

申请号：EP98905274.0

申请日：1998-01-08

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： VON DEYN, Wolfgang ,  HILL, Regina, Luise ,  KARDORFF, Uwe ,  BAUMANN, Ernst ,  ENGEL, Stefan ,  MAYER, Guido ,  WITSCHEL, Matthias ,  RACK, Michael ,  GÖTZ, Norbert ,  GEBHARDT, Joachim ,  MISSLITZ, Ulf ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  OTTEN, Martina ,  RHEINHEIMER, Joachim

IPC: C07D277 ,  A01N43 ,  C07D231 ,  C07D261 ,  C07D263 ,  C07D273 ,  C07D291 ,  C07D403 ,  C07D413 ,  C07D417 ,  C07D419 ,  C07D498 ,  C07D237 ,  C07D311

CPC classification number: C07D413/10 ,  A01N43/76 ,  A01N43/80 ,  C07D231/20 ,  C07D261/04 ,  C07D261/20 ,  C07D403/12 ,  C07D417/10

Abstract: The invention concerns benzoyl derivatives of formula (I) in which the variables have the following meanings: R1, R2: hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkylthio halide, alkylsulphinyl, alkylsulphinyl halide, alkylsulphonyl, or C¿1?-C6 alkylsulphonyl halide; R?3¿: hydrogen, halogen or alkyl; R4, R5: hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the six last-mentioned groups can be substituted; X: O, S, NR9, CO or CR10R11; Y: O, S, NR12, CO or CR?13R14; R15¿: optionally substituted pyrazole which is bonded in position 4 and carries a hydroxy or sulphonyloxy group in position 5. The invention also concerns: the salts of these 3-heterocyclyl-substituted benzoyl derivatives which can be used for agricultural purposes; processes and intermediate products for preparing these substances; agents containing them; and the use as herbicides of these derivatives or agents containing them.

公开(公告)号：EP0931068A1

公开(公告)日：1999-07-28

申请号：EP97942894.0

申请日：1997-08-29

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HAMPRECHT, Gerhard ,  GEBHARDT, Joachim ,  ISAK, Heinz ,  RACK, Michael ,  RHEINHEIMER, Joachim ,  SCHÄFER, Peter

IPC: B01J31 ,  C07D213

CPC classification number: C07D213/62

Abstract: Process for the production of substituted phenylpyridines having formula (I), characterized by the fact that substituted pyridine having formula (II) is made to react with an aryl compound having formula (III).

公开(公告)号：EP0885194A1

公开(公告)日：1998-12-23

申请号：EP97905033.0

申请日：1997-02-17

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： OBERDORF, Klaus ,  GRAMMENOS, Wassilios ,  SAUTER, Hubert ,  GROTE, Thomas ,  MÜLLER, Bernd ,  KIRSTGEN, Reinhard ,  MÜLLER, Ruth ,  BAYER, Herbert ,  PTOCK, Arne ,  RACK, Michael ,  HARREUS, Albrecht ,  RÖHL, Franz ,  LORENZ, Gisela ,  AMMERMANN, Eberhard ,  STRATHMANN, Siegfried ,  HARRIES, Volker

IPC: A01N43 ,  C07D213

CPC classification number: C07D213/64 ,  A01N43/40 ,  C07D213/643

Abstract: The invention concerns pyridyl-phenyl- and benzylethers of formula (I), and their salts and N-oxides, in which the substituents and indices have the following meanings: Q is C(CO2CH3)=CHCH3, C(CO2CH3)=CHOCH3, C(CONH2)=NOCH3, C(CO2CH3)=NOCH3, C(CONHCH3)=NOCH3 or N(OCH3)-CO2CH3; n is 0 or 1; R1 is hydrogen or an organic group bonded via a carbon atom; R2 is hydrogen, cyano, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; R3 is hydrogen, halogen, C¿1?-C4 alkyl or C1-C2 alkyl halide; x is 0, 1 or 2; R?4¿ is cyano, nitro, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; y is 0, 1, 2 or 3; and R5 is cyano, halogen, C¿1?-C4 alkyl, C1-C4 alkyl halide or C1-C4 alkoxy. The invention further concerns a process and intermediate products for preparing these substances and their use.