SYNTHESIS OF SILYL KETENE ACETAL FROM ALLYL 2-ORGANOACRYLATES

    公开(公告)号:CA1327209C

    公开(公告)日:1994-02-22

    申请号:CA573691

    申请日:1988-08-03

    Applicant: DOW CORNING

    Inventor: REVIS ANTHONY

    Abstract: SYNTHESIS OF SILYL KETENE ACETAL FROM ALLYL 2-ORGANOACRYLATES A process is described for preparing silyl ketene acetals having the formula, (CH3)RC=C(OSiRi3)2 , from allyl 2-organoacrylates. The process comprises contacting an allyl 2-organoacrylate with a trisubstituted silane in the presence of a rhodium catalyst; and separating and isolating the silyl ketene acetal. Silyl ketene acetal of greater than 85-90 percent purity can be recovered.

    64.
    发明专利
    未知

    公开(公告)号:DE3884109D1

    公开(公告)日:1993-10-21

    申请号:DE3884109

    申请日:1988-08-23

    Applicant: DOW CORNING

    Inventor: REVIS ANTHONY

    Abstract: A process is described for preparing silyl ketene acetals having the formula, (CH3)RC=C(OSiR 3)2 , from allyl 2-organoacrylates. The process comprises contacting an allyl 2-organoacrylate with a trisubstituted silane in the presence of a rhodium catalyst; and separating and isolating the silyl ketene acetal. Silyl ketene acetal of greater than 85-90 percent purity can be recovered.

    66.
    发明专利
    未知

    公开(公告)号:DE3586332D1

    公开(公告)日:1992-08-20

    申请号:DE3586332

    申请日:1985-04-02

    Applicant: DOW CORNING

    Abstract: Porous materials having a dual surface are disclosed. Also disclosed is a method for their preparation. An example of such a material is a silica gel reacted with a reactive silane intermediate such as (CH 3 ) 2 Si=O and then, with a reactive silane such asto give a dual treated material having -(CH 3 ) 2 SiO) x H on the exterior surface andon the interior surface of the pores.

    69.
    发明专利
    未知

    公开(公告)号:AT381591T

    公开(公告)日:2008-01-15

    申请号:AT03795659

    申请日:2003-09-05

    Applicant: DOW CORNING

    Inventor: REVIS ANTHONY

    Abstract: Modified silica fillers are prepared by a method in which silica surfaces are contacted with compositions containing organosilicon compounds. The organosilicon compounds in the compositions are only of types of structural groups of monomeric dichlorosilanes and trialkoxysilanes. The compositions may be (i) mixtures or blends of alkyl and aryl group containing dichlorosilanes and trialkoxysilanes free of hydrocarbon or organofunctional groups reactive with silica surfaces, (ii) mixtures or blends of substituted alkyl and substituted aryl group containing dichlorosilanes in which the dichlorosilanes are free of hydrocarbon or organofunctional groups reactive with silica surfaces and trialkoxysilanes free of hydrocarbon or organofunctional groups reactive with silica surfaces, or (iii) substituted and unsubstituted alkyl and aryl group containing dichlorosilanes in which the dichlorosilanes are free of hydrocarbon or organofunctional groups reactive with silica surfaces. The mixtures and blends contain the dichlorosilanes and trialkoxysilanes in a weight ratio of 1:0.1 to 1:2, respectively.

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