公开(公告)号：JPH05301923A

公开(公告)日：1993-11-16

申请号：JP12992292

申请日：1992-04-24

Applicant: SAGAMI CHEM RES

Inventor： NAGASE YUTAKA ,  AOYANAGI TAKAO ,  TAKAMURA YURIKO ,  MIYATA FUSAE

IPC: C07F7/10 ,  C08F30/08

Abstract: PURPOSE:To provide a new monomer having a specific structure, serving as the essential constituent for polymers useful as a membrane material with high coefficients of permeation and separation for gases such as oxygen and carbon dioxide. CONSTITUTION:The objective monomer having structure of formula III (e.g. a compound of formula IV) can be obtained by reaction of a pyridyl-contg. silanol compound of formula I (R and R are each 1-6C alkyl; q is 1-6) with an alkali metal compound such as sodium hydride followed by reaction with a chlorosilane compound of formula II (X is H, halogen, etc.; R is the same with R ; p is 2-6; m is 1-3) in a solvent such as THF in an inert gas atmosphere.

公开(公告)号：JPH04261514A

公开(公告)日：1992-09-17

申请号：JP4414291

申请日：1991-02-16

Applicant: KURARAY CO ,  SAGAMI CHEM RES

Inventor： YAMAMOTO FUMIO ,  NAGASE YUTAKA ,  AOYANAGI TAKAO ,  TAKAMURA YURIKO ,  NAKAMURA TOMOKO

IPC: C08G77/26 ,  C08G77/28 ,  G02C7/04

Abstract: PURPOSE:To enhance oxygen permeability and to improve water wettability by using the eyeglass lens material made of a polymer composed essentially of polymerizable polyorgano-siloxane having a specified pyridine ring on one terminal. CONSTITUTION:The contact lenses are obtained by raze cutting or molding or the like methods from the polymer composed essentially of the polymerizable polyorganosiloxane having the pyridine ring on one terminal of the polymer chain represented by formula I in which R is >=4C alkyl or phenyl; each of R -R is independently optionally substituted alkyl or such phenyl; Y is a polymerizable group; m is an integer of 0-2; p is an integer of 1-6; and n is an integer of 3-10.

公开(公告)号：JPH04217989A

公开(公告)日：1992-08-07

申请号：JP7205191

申请日：1991-03-13

Applicant: SAGAMI CHEM RES

Inventor： NAGASE YUTAKA ,  TAKAMURA YURIKO

IPC: C07F7/08 ,  C08F30/08

Abstract: PURPOSE:To provide the subject compound useful as a synthetic intermediate for a monomer for the synthesis of a side-chain type polymer liquid crystal exhibiting stable liquid crystal nature at a relatively low temperature. CONSTITUTION:A compound of formula I (R and R are alkyl or phenyl; X is single bond, O, COO or OCO; Q is mesogen group; p is 2-20), e.g. 4-(3- methylethoxysilylpropoxy)-4'-cyanobiphenyl. The compound can be produced by reacting an alkenyl compound of formula II (g is 0-18) having a mesogen group (e.g. 4-allyloxy-4'-cyanobiphenyl) with a compound of formula III (R is alkyl) in the presence of a hydrosilylation catalyst and hydrolyzing the resultant compound of formula IV. A side-chain type polymer liquid crystal having siloxane bond on a spacer can be produced by synthesizing a monomer having a mesogen group and a polymerizable group bonded through a siloxane bond using the compound of formula I and polymerizing the synthesized monomer.

公开(公告)号：JPH0377891A

公开(公告)日：1991-04-03

申请号：JP21128789

申请日：1989-08-18

Applicant: SAGAMI CHEM RES

Inventor： NAGASE YUTAKA ,  AOYANAGI TAKAO ,  TAKAMURA YURIKO ,  NAKAMURA TOMOKO

IPC: C07D213/24 ,  A61K31/695 ,  A61K47/24 ,  A61K47/34 ,  A61P17/00 ,  C07F7/10 ,  C08G77/26 ,  C08G77/28

Abstract: NEW MATERIAL:A compound expressed by formula I [R represents hydrocarbon group; Y represents counter anion; R to R represent (substituted)alkyl or (substituted)phenyl; (p) is 1-6; (n) is >=3]. EXAMPLE:A compound expressed by formula II. USE:A percutaneous absorbefacient which promotes permeation and absorption of a drug through skin. PREPARATION:A silanol compound having a pyridine ring expressed by formula III is reacted with a strong base (example; methyl-lithium) and then reacted with a cyclosiloxane compound expressed by formula IV ((q) is 3-6), followed by termination of reaction by reacting a halosilane compound expressed by formula V (X represents halogen) to afford a polyorganosiloxane having a pyridine ring at its terminus expressed by formula IV. The resultant compound is reacted with an alkylating agent expressed by the formula RY (Y represents halogen, lower alkyl-sulfonyloxy, arylsulfonyl, nitroxy or sulfonyloxy).

公开(公告)号：JPH0377890A

公开(公告)日：1991-04-03

申请号：JP21128689

申请日：1989-08-18

Applicant: SAGAMI CHEM RES

Inventor： NAGASE YUTAKA ,  AOYANAGI TAKAO ,  TAKAMURA YURIKO ,  NAKAMURA TOMOKO

IPC: C07D213/24 ,  C07F7/10 ,  C08G77/26 ,  C08G77/28

Abstract: NEW MATERIAL:A compound expressed by formula I [R represents >=4C alkyl or phenyl; R to R represent (substituted)alkyl or (substituted)phenyl; Y represents H, alkyl or polymerizable group; (m) is 0-2; (p) is 1-6; (n) is >=3]. EXAMPLE:A compound expressed by formula II. USE:A silicone-based surfactant, percutaneous absorbefacient, precursor thereof and intermediate of a graft copolymer having pyridine ring at its branch terminus. PREPARATION:A silanol compound having a pyridine ring expressed by formula III is reacted with a strong base (example; methyl-lithium) and then reacted with a cyclosiloxane compound expressed by formula IV ((q) is 3-6), followed by termination of reaction with a halosilane compound expressed by formula V (X represents halogen).

公开(公告)号：JPS6356528A

公开(公告)日：1988-03-11

申请号：JP19947586

申请日：1986-08-26

Applicant: SAGAMI CHEM RES ,  TOSOH CORP

Inventor： MATSUI KIYOHIDE ,  NAGASE YUTAKA ,  UCHIKURA MASAKI

IPC: C08G77/42

Abstract: PURPOSE:To obtain the titled copolymer capable of giving membranes for effectively separating gas or liquid mixtures with excellent permeability and separability, by reaction of a poly-disubstituted acetylene with a strong base followed by with a cyclosiloxane compound and stopping the reaction with a terminator. CONSTITUTION:A poly-disubstituted acetylene of formula I (R -R are each alkyl, phenyl, etc.) is allowed to react with a strong base followed by with a cyclosiloxane compound of formula II (R and R are each alkyl, alkenyl or phenyl; m is 3-6) and then the reaction is stopped by adding a terminator (e.g. triorganohalogenosilane compound), thus obtaining the objective copolymer constituted of units of formula III (A is H or polyorganosiloxane of formula IV; B is H or of formula V; R -R are each H, alkenyl, etc.; n>=1) with the molar ratio for the recurring units of 99/1-10/90 (pref. 98/2-40/60) of the poly- disubstituted acetylene in the main chain to the polyorganosiloxane in the side chain.

公开(公告)号：JPS6356513A

公开(公告)日：1988-03-11

申请号：JP19947686

申请日：1986-08-26

Applicant: SAGAMI CHEM RES ,  TOSOH CORP

Inventor： MATSUI KIYOHIDE ,  NAGASE YUTAKA ,  UCHIKURA MASAKI

IPC: C08F238/02 ,  C08F8/00 ,  C08F238/00

Abstract: PURPOSE:To obtain the titled compound providing a separating film having improved separating characteristics readily, by reacting a polydisubstituted acetylene consisting of a specific repeating unit with a strong base and reacting the reaction product with a triorganosilane. CONSTITUTION:A polydisubstituted acetylene consisting of a repeating unit shown by formula I (A is alkyl, phenyl, etc.) is reacted with a base (e.g. organic lithium, etc.) in a solvent such as preferably n-hexane, etc., at 0-90 deg.C for 10 min-24hr. The reaction product is silylated with a triorganohalogenosilane compound shown by formula II (X is halogen; R -R are H, alkyl, alkenyl, phenyl, etc.) preferably for >=20min to give the aimed compound which consists of repeating units shown by formula I and formula III and has a molar ratio of the former to the latter of 99/1-1/99 and

公开(公告)号：JPS61271328A

公开(公告)日：1986-12-01

申请号：JP11375485

申请日：1985-05-27

Applicant: SAGAMI CHEM RES ,  TOYO SODA MFG CO LTD

Inventor： MATSUI KIYOHIDE ,  NAGASE YUTAKA ,  UEDA TOMOKO ,  UCHIKURA MASAKI

IPC: C08G77/00 ,  B01D71/70 ,  C08G65/48 ,  C08G77/42 ,  C08G77/46 ,  C08G81/00 ,  C08G81/02

Abstract: PURPOSE:A graft copolymer excellent in membrane forming property, film strength, gas permeability coefficient, etc., and suitable for the production of membranes for separation of a gas mixture, obtained by incorporating a polyorganosiloxane chain in polyphenylene oxide. CONSTITUTION:The purpose graft copolymer is obtained by reacting polyphenylene oxide of formula I (wherein A is a halogen, methyl or the like) with a strong base and reacting the product with a polyorganosiloxane having a reactive group on one end, of formula II (wherein X is a halogen, Y is a bivalent organic group, Z is a polyorganosiloxane chain and R -R are each alkyl, phenyl or the like). This graft copolymer is composed of repeating units of formula III (wherein B and B are each H or formula IV and A and A are each methyl, formula V or the like) and has a molar ratio of the polyphenylene oxide repeating units in the main chain to the polyorganosiloxane repeating units in the side chains in the range of 80/20-10/90 and a MW of at least 10,000.

公开(公告)号：JPS61247729A

公开(公告)日：1986-11-05

申请号：JP9061885

申请日：1985-04-26

Applicant: SAGAMI CHEM RES

Inventor： MATSUI KIYOHIDE ,  NAGASE YUTAKA ,  UEDA TOMOKO

IPC: C08G65/48

Abstract: PURPOSE:To produce a polyphenylene oxide derivative excellent in mechanical strength and durability, by reacting a specified halogenated polyphenylene oxide with a hydroxyl group-containing compound in the presence of a base. CONSTITUTION:A halogenated polyphenylene oxide having repeating units of formulas II and III (wherein R and R are each R1 or a halomethyl, A are each H or a halogen and at least 1% of the total of R , R and R in the total repeating units are halomethyl groups), and obtained by halogenating a polyphenylene oxide having repeating units of formula I [wherein R are each a halogen, methyl, alkoxy, or (substituted) phenyl, and either of these groups is methyl] is reacted with a hydroxyl group-containing compound in the presence of a base to obtain a polyphenylene oxide derivative having repeating units of formulae I, II and V (wherein R and R are each R or -CH2OX and at least 1% of the total of R , R , R , R and R are -CH2OX groups) and having a weight-average MW >=10,000.

公开(公告)号：JPS61174905A

公开(公告)日：1986-08-06

申请号：JP1557385

申请日：1985-01-31

Applicant: TOYO SODA MFG CO LTD ,  SAGAMI CHEM RES

Inventor： UCHIKURA MASAKI ,  MATSUI KIYOHIDE ,  NAGASE YUTAKA ,  OCHIAI JUNKO ,  UEDA TOMOKO

IPC: B01D61/36 ,  B01D71/44 ,  B01D71/70

Abstract: PURPOSE:To obtain polymer film having high permeability and separating capacity for liquid and suitable for separation of liquid compds. by pervaporation by using a polymer comprising a recurrent unit contg. Si as expressed by the specified formula. CONSTITUTION:A polymer comprising the recurrent unit as expressed by the formula, obtd. by polymerizing 1-trimethylsilyl propyne in a solvent such as toluene using tantalum pentachloride, etc. as catalyst, is redissolved in toluene. A homogeneous film is obtd. by flowing the soln. on a 'Teflon(R)' plate and evaporating the solvent. The film is fitted to a permeation cell for pervaporation and used for separation of water/alcohol mixture, etc.