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公开(公告)号：US5451383A
公开(公告)日：1995-09-19
申请号：US172297
申请日：1993-12-23
Applicant: Frederick W. Leavitt
Inventor： Frederick W. Leavitt
CPC classification number: C01D15/04 , B01J20/18 , B01J39/043 , C01B13/027 , C01B2210/0046
Abstract: In the production of lithium-exchange adsorbents, lithium recovery from spent ion-exchange solutions is achieved with advantageous secondary recovery of lithium from zeolite wash liquor and precipitate salts by ion-exchange means.
Abstract translation: 在锂离子交换吸附剂的生产中，从废离子交换溶液中回收锂，通过离子交换方法从沸石洗涤液和沉淀盐中有利的二次回收得到。
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公开(公告)号：US5403492A
公开(公告)日：1995-04-04
申请号：US115219
申请日：1993-09-01
Applicant: Eli Salem , Robert Kunin
Inventor： Eli Salem , Robert Kunin
CPC classification number: C02F1/42 , B01J39/043
Abstract: The invention provides a method for removing metal oxides and colloidal material from high-resistivity water streams at a relatively high removal efficiency. The method includes hydrating a highly ionized dual morphology ion exchange resin in a macroreticular, desiccated morphology to produce a macroreticular, hydrated morphology. A water stream which is brought into contact with the resin is purified. The water stream may, optionally, also be contacted with both a cation exchange resin and an anion exchange resin.The invention additionally provides a method for selecting ion exchange resins which are particularly suited for use in removing metal oxides from a condensate stream. The method serves to narrow the field of candidates for pilot-scale resin testing with industrial water streams.
Abstract translation: 本发明提供了一种从较高去除效率的高电阻率水流中去除金属氧化物和胶体材料的方法。 该方法包括将高离子化的双重形态离子交换树脂水化成大网状干燥形态以产生大网状，水合形态。 与树脂接触的水流被净化。 任选地，水流也可以与阳离子交换树脂和阴离子交换树脂接触。 本发明另外提供了一种选择离子交换树脂的方法，其特别适用于从冷凝物流中除去金属氧化物。 该方法用于缩小工业水流中试规模树脂测试候选人的领域。
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公开(公告)号：US5397477A
公开(公告)日：1995-03-14
申请号：US2995
申请日：1993-01-11
Applicant: Eli Salem , Robert Kunin
Inventor： Eli Salem , Robert Kunin
CPC classification number: C02F1/42 , B01J39/043
Abstract: The invention provides a method for removing metal oxides and colloidal material from high-resistivity water streams at a relatively high removal efficiency. The method includes hydrating a highly ionized dual morphology ion exchange resin in a macroreticular, desiccated morphology to produce a macroreticular, hydrated morphology. A water stream which is brought into contact with the resin is purified. The water stream may, optionally, also be contacted with both a cation exchange resin and an anion exchange resin.The invention additionally provides a method for selecting ion exchange resins which are particularly suited for use in removing metal oxides from a condensate stream. The method serves to narrow the field of candidates for pilot-scale resin testing with industrial water streams.
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公开(公告)号：US5192446A
公开(公告)日：1993-03-09
申请号：US824998
申请日：1992-01-24
Applicant: Eli Salem , Robert Kunin
Inventor： Eli Salem , Robert Kunin
CPC classification number: C02F1/42 , B01J39/043
Abstract: The invention provides a method for removing transition metal oxides and soluble cation species from condensate at a relatively high removal efficiency. The method includes hydrating a strongly acidic dual morphology cation exchange resin in a macroeticular, desiccated morphology to produce a macroreticular, hydrated morphology. Condensate which is brought into contact with the resin when it is in a hydrogen form is purified. The condensate may, optionally, also be contacted with an anion exchange resin.The invention additionally provides a method for selecting cation exchange resins which are particularly suited for use in removing metal oxides from a condensate stream. The method serves to narrow the field of condidates for pilot-scale resin testing with industrial condensate.
Abstract translation: 本发明提供一种以较高的去除效率从冷凝水中除去过渡金属氧化物和可溶性阳离子物质的方法。 该方法包括在大网络干燥形态中水合强酸性双重形态阳离子交换树脂以产生大网状，水合形态。 在氢气形式下与树脂接触的冷凝物被纯化。 冷凝物也可任选地与阴离子交换树脂接触。 本发明还提供一种选择特别适用于从冷凝物流中除去金属氧化物的阳离子交换树脂的方法。 该方法用于缩小用于工业冷凝水的中试规模树脂测试的候选领域。
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65.发明授权
公开(公告)号：US5174902A
公开(公告)日：1992-12-29
申请号：US485939
申请日：1990-02-27
Applicant: David C. Shubert , Galen R. Myers , Robert C. Richardson
Inventor： David C. Shubert , Galen R. Myers , Robert C. Richardson
CPC classification number: F01P11/06 , B01J39/043 , F01P2011/065 , F01P2011/068
Abstract: An apparatus and method for removing particulates, hydrcarbons (such as oil), cations and anions including nitrite ions from a liquid, such as an engine coolant liquid having a freezing point depressant and situated in an internal combination engine cooling system. The apparatus has at least one filter for removing particulates and hydrocarbons; a strong acid cation exchange bed in the hydrogen form for removing cations; a strong base anion exchange bed in the hydroxide form for removing anions; and separator for separating gas containing nitrogen, such as nitric oxide and/or nitrogen dioxide, that is produced in the cation exchange bed and/or the anion exchange bed. The method for removing particulates, hydrocarbons, cations, anions and nitrite ions from an engine coolant liquid having a freezing point depressant comprises providing an engine coolant liquid having particulates, hydrocarbons, cations, anions and nitrite ions; passing the engine coolant liquid through a zone for filtering wherein particulates and hydrocarbons are removed from the engine coolant liquid; and passing the engine coolant liquid through a strong acid cation exchanger bed in the hydrogen form wherein cations are removed from the engine coolant liquid and nitrite ions are converted into nitric oxide and/or nitrogen dioxide. The method further comprises passing the engine coolant liquid through a strong base anion exchanger bed in the hydroxide form wherein anions are removed from the engine coolant liquid; and subsequently separating the nitric oxide and/or nitrogen dioxide from the engine coolant liquid to produce an engine coolant liquid having the freezing point depressant.
Abstract translation: 一种用于从液体（例如具有凝固点下降剂并位于内部组合发动机冷却系统中的发动机冷却剂液体）中去除颗粒物，氢化物（例如油），阳离子和阴离子（包括亚硝酸根离子）的装置和方法。 该装置具有至少一个用于除去微粒和碳氢化合物的过滤器; 用于除去阳离子的氢形式的强酸阳离子交换床; 用于除去阴离子的氢氧化物形式的强碱性阴离子交换床; 以及用于分离在阳离子交换床和/或阴离子交换床中产生的含有氮气的分离器，例如一氧化氮和/或二氧化氮。 从具有凝固点抑制剂的发动机冷却剂液体中除去微粒，烃，阳离子，阴离子和亚硝酸根离子的方法包括提供具有微粒，烃，阳离子，阴离子和亚硝酸根离子的发动机冷却液; 将发动机冷却剂液体通过用于过滤的区域，其中从发动机冷却剂液体中除去微粒和烃; 并将发动机冷却剂液体通过氢形式的强酸性阳离子交换床，其中阳离子从发动机冷却剂液体中除去，亚硝酸根离子转化成一氧化氮和/或二氧化氮。 该方法还包括使发动机冷却液通过氢氧化物形式的强碱性阴离子交换床，其中阴离子从发动机冷却剂液体中除去; 并随后从发动机冷却剂液体中分离一氧化氮和/或二氧化氮，以产生具有凝固点降低剂的发动机冷却液。
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Patent Agency Ranking66.发明授权VX adsorption from a chlorofluorocarbon solvent using a macroreticular strong acid resin 失效使用大网状强酸树脂从氯氟烃溶剂中吸收VX
公开(公告)号：US5069797A
公开(公告)日：1991-12-03
申请号：US637028
申请日：1991-01-03
Applicant: Philip W. Bartram , Noel C. DiBona , James H. Buchanan , Dennis K. Rohrbaugh
Inventor： Philip W. Bartram , Noel C. DiBona , James H. Buchanan , Dennis K. Rohrbaugh
IPC: B01J39/04
CPC classification number: B01J39/043 , Y10S210/908 , Y10S210/911
Abstract: A polydivinylbenezene macroreticular strong acid resin can effectively detaminate solutions containing organophosphorus chemical warfare agents such as o-ethyl S-(2-diisopropylaminoethyl) methylphosphonothiolate (VX).
Abstract translation: 聚二乙烯基烯烃大网络强酸树脂可以有效去除含有机磷化学试剂如S-乙基S-（2-二异丙基氨基乙基）甲基膦硫醇盐（VX）的溶液。
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67.发明授权Process for removing residual monomers and oligemers from amine-containing polymers 失效从含胺聚合物中除去残留单体和寡聚体的方法
公开(公告)号：US5055197A
公开(公告)日：1991-10-08
申请号：US681038
申请日：1991-04-05
Applicant: Robert L. Albright , Jon R. Fisher , Eric G. Isacoff , Eric C. Peters
Inventor： Robert L. Albright , Jon R. Fisher , Eric G. Isacoff , Eric C. Peters
CPC classification number: B01D61/145 , B01J39/043 , C08F6/001
Abstract: Treatment of water-soluble, amine-containing polymers with strong acid, cation exchange resins from aromatic copolymer crosslinked with 2-25% polyvinyl crosslinker, followed by ultrafiltration with a membrane filter having a molecular-weight cutoff, measured against the polymers to be treated, of about 10,000 to about 15,000, results in a highly effective removal of residual monomers and oligomers of less than 500 molecular weight.
Abstract translation: 用强酸处理含胺聚合物，用2-25％交联剂交联的芳族共聚物的阳离子交换树脂，然后用对待处理的聚合物测量的具有分子量截留值的膜过滤器超滤， 约15,000，导致分子量为500道尔顿或更低的残余单体和低聚物的高效除去。
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68.发明授权Sodium-selective cation exchange resins for ammonia-cycle condensate polishing 失效用于氨循环冷凝物抛光的钠选择性阳离子交换树脂
公开(公告)号：US4857202A
公开(公告)日：1989-08-15
申请号：US34524
申请日：1987-04-03
Applicant: James T. McNulty
Inventor： James T. McNulty
IPC: B01J39/04
CPC classification number: B01J39/043
Abstract: Ion exchange resin beds used for ammonia-cycle condensate polishing show enhanced selectivity for sodium ions over ammonium ions when conventional, monosulfonated cation exchange resin is replaced with polysulfonated cation exchange resin. This enhanced selectivity results in a lower concentration of sodium ion leakage and longer bed life to critical leakage, compared with conventional, monosulfonated resins.
Abstract translation: 用于氨循环冷凝物抛光的离子交换树脂床当常规的单磺化阳离子交换树脂被多磺酸化阳离子交换树脂代替时，显示出钠离子对铵离子的选择性增强。 与传统的单磺化树脂相比，这种增强的选择性导致较低的钠离子泄漏浓度和较长的床体寿命。
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公开(公告)号：US4615806A
公开(公告)日：1986-10-07
申请号：US708992
申请日：1985-03-07
Applicant: Charles B. Hilton
Inventor： Charles B. Hilton
IPC: C07C51/42 , B01D15/04 , B01J20/26 , B01J39/04 , B01J41/04 , C07B31/00 , C07B63/02 , C07C45/79 , C07C51/00 , C07C51/47 , C07C51/487 , C07C53/08 , C07C67/00
CPC classification number: C07C51/47 , B01J39/043 , C07C45/79
Abstract: The invention relates to a method for removing iodide compounds from a non-aqueous organic medium, such as acetic acid. The medium is contacted with a macroreticulated strong-acid cation exchange resin which is stable in the organic medium and has at least one percent of its active sites converted to the silver or mercury form.
Abstract translation: 本发明涉及从非水有机介质如乙酸中除去碘化物的方法。 该介质与在有机介质中稳定的大网络化强酸阳离子交换树脂接触，并且其活性位点的至少1％转化为银或汞形式。
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公开(公告)号：US4182676A
公开(公告)日：1980-01-08
申请号：US711363
申请日：1976-08-03
Applicant: Angelo J. Casolo
Inventor： Angelo J. Casolo
CPC classification number: C02F9/00 , B01J39/04 , B01J39/043 , B01J45/00 , B01J47/04 , C02F1/001 , C02F1/283 , C02F1/66 , C02F2001/422 , C02F2001/425 , C02F2101/105 , C02F2101/18 , C02F2101/20 , C02F2101/203 , C02F2101/22 , C02F2301/043
Abstract: A method and system combining filtration and ion-exchange structures for removing contaminants from liquids. In overall concept, contaminated liquid is passed through filtering mediums to remove particulate matter from the incoming contaminated liquid. Organics are removed from the liquid by passage through adsorbent non-ionic type resins. The liquid is then passed through strong acid cation exchange resins, weak base anion exchange resins, weak acid cation exchange resins, and strong base anion exchange resins arranged in a predetermined location in the liquid flow path to provide optimized contaminant removal. One of the optimization techniques is through the pH adjustment of the liquid at predetermined points in the flow path. Additionally, the liquid to be purified is passed through mixed bed polisher resins as well as chelation resins to provide a final substantially contaminant free liquid which is returned to use in a closed loop fashion.
Abstract translation: 一种组合过滤和离子交换结构以从液体中除去污染物的方法和系统。 在总体概念中，污染的液体通过过滤介质以从进入的污染液体中除去颗粒物质。 有机物通过吸附剂非离子型树脂从液体中除去。 然后将液体通过强酸性阳离子交换树脂，弱碱性阴离子交换树脂，弱酸阳离子交换树脂和布置在液体流路中的预定位置的强碱性阴离子交换树脂，以提供优化的污染物去除。 优化技术之一是通过在流路中的预定点处的液体的pH调节。 此外，待纯化的液体通过混合床抛光树脂以及螯合树脂，以提供最终基本上无污染的液体，其返回以闭环方式使用。
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