Polymer adsorbent
    63.
    发明授权
    Polymer adsorbent 有权
    聚合物吸附剂

    公开(公告)号:US09452426B2

    公开(公告)日:2016-09-27

    申请号:US14374735

    申请日:2013-01-26

    Abstract: ProblemTo provide a method for easily producing an adsorbing material used for the removal and recovery of metals and ions in a solution, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes.Means for ResolutionA polymer adsorbent for metals and ions, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes, is produced by a) preparing a reactive polymer having a large number of halogenated alkyl groups or glycidyl groups in the molecule, b) preparing a base material polymer insoluble in water and alcohols, c) dissolving the reactive polymer and the base material polymer in an organic solvent to give a mixed solution, d) removing the organic solvent to give a solid carrier in a desired form, and e) allowing a halogenated alkyl group or a glycidyl group in the solid carrier to react with an amine compound having a functional group capable of adsorbing metals and ions, thereby introducing an adsorptive functional group.

    Abstract translation: 一种金属和离子的高分子吸附剂,其耐久性高,具有适用于各种目的的各种吸附官能团和形式,是通过以下方法制备的:a)制备分子中具有大量卤代烷基或缩水甘油基的反应性聚合物,b )制备不溶于水和醇的基础材料聚合物,c)将反应性聚合物和基础材料聚合物溶解在有机溶剂中以得到混合溶液,d)除去有机溶剂,得到所需形式的固体载体,和 e)使固体载体中的卤代烷基或缩水甘油基与具有能够吸附金属和离子的官能团的胺化合物反应,从而引入吸附官能团。

    Process for production of porous membrane
    64.
    发明授权
    Process for production of porous membrane 有权
    多孔膜生产工艺

    公开(公告)号:US09393530B2

    公开(公告)日:2016-07-19

    申请号:US13261454

    申请日:2011-04-05

    Abstract: Disclosed is a process for production of a porous membrane that includes the steps of layering a film-forming dope that contains a polymer (A) that forms a membrane base, a polyvinylpyrrolidone (B) and a solvent (C) into a single layer or two or more layers; immersing the film-forming dope in a solidifying fluid that is a non-solvent with respect to the polymer (A) and is a good solvent with respect to the polyvinylpyrrolidone (B); and removing the polyvinylpyrrolidone (B), wherein the polyvinylpyrrolidone (B) has a K value of 50 to 80, a mass ratio r of the polyvinylpyrrolidone (B) to the polymer (A) is 0.5 or more and less than 1, and the viscosity of the film-forming dope at a membrane production temperature is 100 to 500 Pa·s. Accordingly, by using an appropriate amount of a low-molecular-weight hydrophilic polymer capable of being easily removed, it is possible to produce a porous membrane of a three-dimensional network structure in which macrovoids are suppressed, having high water permeability and superior filtration performance.

    Abstract translation: 公开了一种生产多孔膜的方法,其包括以下步骤:将含有形成膜基的聚合物(A),聚乙烯吡咯烷酮(B)和溶剂(C))的成膜原液分层成单层或 两层或多层; 将成膜原液浸渍在相对于聚合物(A)为非溶剂的凝固液中,相对于聚乙烯吡咯烷酮(B)为良好的溶剂; 除去聚乙烯吡咯烷酮(B),其中聚乙烯吡咯烷酮(B)的K值为50〜80,聚乙烯吡咯烷酮(B)与聚合物(A)的质量比r为0.5以上且小于1, 膜生成温度下的成膜原液的粘度为100〜500Pa·s。 因此,通过使用能够容易地除去的适量的低分子量亲水性聚合物,可以制造出抑制大孔,具有高透水性和优异过滤性的三维网状结构的多孔膜 性能。

    METHOD FOR MANUFACTURING POROUS HOLLOW FIBER MEMBRANE
    66.
    发明申请
    METHOD FOR MANUFACTURING POROUS HOLLOW FIBER MEMBRANE 审中-公开
    制造多孔中空纤维膜的方法

    公开(公告)号:US20140343178A1

    公开(公告)日:2014-11-20

    申请号:US14344469

    申请日:2012-09-14

    Abstract: The purpose of the present invention is to provide a method for manufacturing a porous hollow fiber membrane in which the amount of a hypochlorite used during pore forming agent removal treatment can be reduced and the facilities cost can be minimized, and in which the post-treatment waste liquid can be readily treated. This method for manufacturing a porous hollow fiber membrane has: coagulating a membrane forming material liquid containing a membrane forming resin and a pore forming agent by a coagulating liquid, to thereby form a porous hollow fiber membrane precursor; and removing the porous hollow fiber membrane precursor impregnated at least with a liquid into contact with ozone gas in a vapor phase, to thereby decompose and remove the pore forming agent present in the membrane.

    Abstract translation: 本发明的目的是提供一种制造多孔中空纤维膜的方法,其中可以减少在成孔剂除去处理期间使用的次氯酸盐的量,并且可以使设备成本最小化,并且其中后处理 废液可以容易地处理。 这种制造多孔中空纤维膜的方法是:通过凝结液凝结含有成膜树脂和成孔剂的成膜材料液,从而形成多孔中空纤维膜前体; 并将至少用液体浸渍的多孔中空纤维膜前体除去与气相中的臭氧气体接触,从而分解和除去存在于膜中的成孔剂。

    POROUS SYNTHETIC RESIN MOLDED PART AND METHOD OF PRODUCING THE SAME
    67.
    发明申请
    POROUS SYNTHETIC RESIN MOLDED PART AND METHOD OF PRODUCING THE SAME 审中-公开
    多孔合成树脂成型部件及其制造方法

    公开(公告)号:US20140217635A1

    公开(公告)日:2014-08-07

    申请号:US14258049

    申请日:2014-04-22

    Abstract: A method of producing a porous molded part includes a mixing process for mixing a granular porous organizer composed of a water-soluble compound, a porous forming assistant agent composed of a polyhydric alcohol, and a cross-linking agent composed of an organic peroxide with a thermoplastic resin composition having a glass transition temperature below 0° C. to obtain a molding material; a cross-linking and forming process for placing the molding material in a molding die and performing a heat press molding thereby progressing coincidentally a cross-linking reaction and a shape forming of a seal face to obtain a molded material; an extracting process for extracting the granular porous organizer from the molded material obtained in the cross-linking and forming process to obtain a porous molded part; and a drying process for drying the porous molded part obtained in the extracting process.

    Abstract translation: 多孔成型体的制造方法包括将由水溶性化合物构成的粒状多孔质组合物,由多元醇构成的多孔形成助剂和由有机过氧化物构成的交联剂与 具有玻璃化转变温度低于0℃的热塑性树脂组合物以获得模塑材料; 一种用于将成型材料放置在成型模具中并进行热压成型的交联和成型方法,从而巧合地进行交联反应和密封面的形状以获得模制材料; 从交联成形工序得到的成型体中提取颗粒状多孔质量组织体,得到多孔成型体的提取方法; 以及用于干燥在提取过程中获得的多孔成型部件的干燥方法。

    SEPARATOR FOR NONAQUEOUS ELECTROLYTE ELECTRICITY STORAGE DEVICES AND NONAQUEOUS ELECTROLYTE ELECTRICITY STORAGE DEVICE
    68.
    发明申请
    SEPARATOR FOR NONAQUEOUS ELECTROLYTE ELECTRICITY STORAGE DEVICES AND NONAQUEOUS ELECTROLYTE ELECTRICITY STORAGE DEVICE 审中-公开
    非电解电解电容器和非电解电解电容器分离器

    公开(公告)号:US20140106235A1

    公开(公告)日:2014-04-17

    申请号:US14125252

    申请日:2012-06-12

    Abstract: Provided is a separator for nonaqueous electrolyte electricity storage devices that includes an improved porous epoxy resin membrane. In the separator for nonaqueous electrolyte electricity storage devices, a ratio I/Io between a peak intensity Io of an absorption peak present at 1240 cm−1 in an infrared absorption spectrum of the porous epoxy resin membrane and a peak intensity I of an absorption peak present at 1240 cm−1 in an infrared absorption spectrum of the porous epoxy resin membrane having been subjected to an acetic anhydride treatment is 1.0 or more and 2.4 or less. The amount of active hydroxyl groups present in the porous epoxy resin membrane can be evaluated by the value of the ratio I/Io.

    Abstract translation: 本发明提供一种非水电解质蓄电装置用隔膜,其包含改性多孔环氧树脂膜。 在非水电解质蓄电装置用隔膜中,多孔环氧树脂膜的红外线吸收光谱中存在于1240cm -1处的吸收峰的峰值强度Io与吸收峰的峰值强度I之比I / 在进行乙酸酐处理的多孔质环氧树脂膜的红外线吸收光谱中,存在于1240cm -1处为1.0以上且2.4以下。 存在于多孔环氧树脂膜中的活性羟基的量可以通过I / Io比值来评估。

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