Abstract:
Provided is an oriented multilayer porous film comprising at least one layer comprising: a heat, solvent, and degradation resistant matrix polymer; a plurality of interconnecting pores; and a porosity less than 90%. The film is made by a dry and/or wet method, with its multilayer structure constructed by coextrusion, lamination, and coating. The film of this disclosure finds a wide range of applications as a permselective medium for use in energy harvesting and storage, filtration, separation and purification of gases and fluids, CO2 and volatile capture, electronics, devices, structural supports, packaging, labeling, printing, clothing, drug delivery systems, bioreactor, and the like. The film is preferably used as a separator of lithium-ion, lithium-sulfur, lithium-air, metal-air, and nonaqueous electrolyte batteries.
Abstract:
Provided are porogen compositions and methods of using such porogen compositions in the manufacture of porous materials, for example, porous silicone elastomers. The porogens generally include comprising a core material and shell material different from the core material. The porogens can be used to form a scaffold for making a resulting porous elastomer when the scaffold is removed.
Abstract:
ProblemTo provide a method for easily producing an adsorbing material used for the removal and recovery of metals and ions in a solution, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes.Means for ResolutionA polymer adsorbent for metals and ions, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes, is produced by a) preparing a reactive polymer having a large number of halogenated alkyl groups or glycidyl groups in the molecule, b) preparing a base material polymer insoluble in water and alcohols, c) dissolving the reactive polymer and the base material polymer in an organic solvent to give a mixed solution, d) removing the organic solvent to give a solid carrier in a desired form, and e) allowing a halogenated alkyl group or a glycidyl group in the solid carrier to react with an amine compound having a functional group capable of adsorbing metals and ions, thereby introducing an adsorptive functional group.
Abstract:
Disclosed is a process for production of a porous membrane that includes the steps of layering a film-forming dope that contains a polymer (A) that forms a membrane base, a polyvinylpyrrolidone (B) and a solvent (C) into a single layer or two or more layers; immersing the film-forming dope in a solidifying fluid that is a non-solvent with respect to the polymer (A) and is a good solvent with respect to the polyvinylpyrrolidone (B); and removing the polyvinylpyrrolidone (B), wherein the polyvinylpyrrolidone (B) has a K value of 50 to 80, a mass ratio r of the polyvinylpyrrolidone (B) to the polymer (A) is 0.5 or more and less than 1, and the viscosity of the film-forming dope at a membrane production temperature is 100 to 500 Pa·s. Accordingly, by using an appropriate amount of a low-molecular-weight hydrophilic polymer capable of being easily removed, it is possible to produce a porous membrane of a three-dimensional network structure in which macrovoids are suppressed, having high water permeability and superior filtration performance.
Abstract:
Technologies and implementations for providing melt processable poly(vinyl alcohol) blends and poly(vinyl alcohol) based membranes are generally disclosed.
Abstract:
The purpose of the present invention is to provide a method for manufacturing a porous hollow fiber membrane in which the amount of a hypochlorite used during pore forming agent removal treatment can be reduced and the facilities cost can be minimized, and in which the post-treatment waste liquid can be readily treated. This method for manufacturing a porous hollow fiber membrane has: coagulating a membrane forming material liquid containing a membrane forming resin and a pore forming agent by a coagulating liquid, to thereby form a porous hollow fiber membrane precursor; and removing the porous hollow fiber membrane precursor impregnated at least with a liquid into contact with ozone gas in a vapor phase, to thereby decompose and remove the pore forming agent present in the membrane.
Abstract:
A method of producing a porous molded part includes a mixing process for mixing a granular porous organizer composed of a water-soluble compound, a porous forming assistant agent composed of a polyhydric alcohol, and a cross-linking agent composed of an organic peroxide with a thermoplastic resin composition having a glass transition temperature below 0° C. to obtain a molding material; a cross-linking and forming process for placing the molding material in a molding die and performing a heat press molding thereby progressing coincidentally a cross-linking reaction and a shape forming of a seal face to obtain a molded material; an extracting process for extracting the granular porous organizer from the molded material obtained in the cross-linking and forming process to obtain a porous molded part; and a drying process for drying the porous molded part obtained in the extracting process.
Abstract:
Provided is a separator for nonaqueous electrolyte electricity storage devices that includes an improved porous epoxy resin membrane. In the separator for nonaqueous electrolyte electricity storage devices, a ratio I/Io between a peak intensity Io of an absorption peak present at 1240 cm−1 in an infrared absorption spectrum of the porous epoxy resin membrane and a peak intensity I of an absorption peak present at 1240 cm−1 in an infrared absorption spectrum of the porous epoxy resin membrane having been subjected to an acetic anhydride treatment is 1.0 or more and 2.4 or less. The amount of active hydroxyl groups present in the porous epoxy resin membrane can be evaluated by the value of the ratio I/Io.
Abstract:
Technologies and implementations for providing melt processable poly(vinyl alcohol) blends and poly(vinyl alcohol) based membranes are generally disclosed.
Abstract:
The present invention provides a method for producing a separator for nonaqueous electrolyte electricity storage devices. The method allows: avoidance of use of a solvent that places a large load on the environment; relatively easy control of parameters such as the porosity and the pore diameter; and a high electrochemical stability of a resultant separator for nonaqueous electrolyte electricity storage devices. The present invention relates to a method for producing a separator for nonaqueous electrolyte electricity storage devices that has a thickness ranging from 5 to 50 μm. The method of the present invention includes the steps of: preparing an epoxy resin composition containing an epoxy resin whose molecular structure has no aromatic ring, a curing agent, and a porogen; forming a cured product of the epoxy resin composition into a sheet shape or curing a sheet-shaped formed body of the epoxy resin composition, so as to obtain an epoxy resin sheet; and removing the porogen from the epoxy resin sheet by means of a halogen-free solvent.