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公开(公告)号:DE2828664B2
公开(公告)日:1979-09-06
申请号:DE2828664
申请日:1978-06-29
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
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公开(公告)号:DE2813528B2
公开(公告)日:1979-07-26
申请号:DE2813528
申请日:1978-03-29
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
IPC: C07C67/00 , C07C239/00 , C07C273/04 , C07C126/02
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公开(公告)号:DE2065782B2
公开(公告)日:1979-06-07
申请号:DE2065782
申请日:1970-07-16
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
Abstract: 1312353 Separating hydrocarbons by solvent extraction SNAM PROGETTI SpA 17 July 1970 [18 July 1969] 34912/70 Heading C5E A process for extracting aromatic hydrocarbons from a mixture of aromatic and aliphatic hydrocarbons comprises a first stage in which the feed mixture is contacted with a solvent in which aromatic hydrocarbons are soluble, so as to form an extract which contains aromatic hydrocarbons; a second stage in which the extract from the first stage is purified by contact with a countercurrent of a purifying agent comprising a hydrocarbon fraction coming at least in part from a third stage, so as to produce a purified extract; a third stage in which the purified extract is extractively distilled to produce an overhead product of which at least part is used in the second stage; and a fourth stage in which the bottom product of the third stage is rectified so as to separate the dissolved aromatic hydrocarbons from the solvent which is recycled to the first stage: wherein (a) the overhead product from the third stage is separated into a higher boiling fraction and a lower boiling fraction which is passed to the second stage, (b) the rectification in the fourth stage is effected in the presence of water, and (c) the extractive solvent used is selected from sulpholane and its derivatives, N-alkyl-pyrrolidones, dialkylsulphoxides, dialkyl formamides, diacetyl-formamides, methyl carbamide, alkyl derivatives of morpholine, glycols and etherified glycols and can contain up to 30 wt. per cent water. A feed 1 is extracted at 2 and the extract 9 is washed at 10 and extractively distilled at 17 to produce an overhead 18 and a bottoms stream 22 which is rectified at 23 to recover aromatics 29 and the solvent 24. The crosshead 18 containing non-aromatics and light aromatics is condensed and distilled at 19 to produce a lower boiling fraction 20 and a bottoms stream 21, comprising high boiling saturated hydrocarbons and non-aromatics of high polarity, which is recycled to the extraction column 2 at a point between the inlets for the feed and for the solvent stream 3 recycled from the rectification at 23. Water is separated from the overhead aromatic fraction at 28 and in part recycled as the stream 26 to remove solvent from the overhead fraction, in part passed to column 5 to recover extractive solvent from the feed raffinate 4, in part vaporized at 25 and passed into the bottom of column 23, and the remainder passed through line 32 mixing with the aqueous stream 8 and the hydrocarbon streams 14 and 20 to serve as the purification agent used in the extraction column 10. The raffinate 12 from the column 10 is separated in a distillation column 13 into an overhead stream 14 comprising light aliphatic hydrocarbons which is recycled to the column 10 and a bottoms stream 15 which is recycled to the extraction column 2. Instead of recovering the light aliphatic hydrocarbons from the raffinate from column 10 they can be recovered from the raffinate from column 2. The overhead stream 18 can be separated into the fractions 21 and 20 by condensation at different temperatures instead of by distillation at 19 as shown. The aromatic mixture 29 obtained can be further distilled to recover xylenes.
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公开(公告)号:DE2654928C3
公开(公告)日:1979-05-31
申请号:DE2654928
申请日:1976-12-03
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
IPC: C07C275/06 , C07C67/00 , C07C239/00 , C07C273/18 , C07C127/15 , C07D233/32
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公开(公告)号:DE2630783B2
公开(公告)日:1979-05-31
申请号:DE2630783
申请日:1976-07-08
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
Inventor: FARACI, ROCCO , RESCALLI, CARLO , CATINI, STEFANO
IPC: C07C7/12 , C07C1/00 , C07C7/148 , C07C7/152 , C07C7/17 , C07C11/00 , C07C11/02 , C07C11/24 , C07C67/00 , C07C69/15 , C07C69/18 , C07C7/01 , C07C67/04
Abstract: 1499646 Removing acetylenic compounds from hydrocarbons SNAMPROGETTI SpA 6 July 1976 [8 July 1975] 28110/76 Heading C5E Acetylenic compounds are removed from hydrocarbon mixtures containing them by contacting the mixtures with an organic acid in the presence of an acidic ion-exchange resin, the acidic groups of which have been substantially totally exchanged with both mercuric ions and alkali metal or alkaline earth metal ions, the acetylenes forming an addition compound with the organic acid. The esters formed may be removed by rectification. The preferred acid is acetic acid. The process may be carried out at 20-120‹ C. in the liquid or gaseous phases. The process may be used to purify ethylene, propylene, butadiene or mixtures thereof.
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公开(公告)号:DE2757877B2
公开(公告)日:1979-05-23
申请号:DE2757877
申请日:1977-12-23
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
Inventor: ZAFFARONI, PASQUALE, MENTANA, ROM , SENNI, ANTONIO , BRANDUZZI, PAOLO , FORMICONI, LAMBERTO, MONTEROTONDO, ROM
Abstract: The new microbial strain of the Candida genus was registered on 6 January 1977 at the Northern Regional Research Laboratory of Peoria, Illinois, USA under registration number NRRL-Y 11062. This strain is cultured to produce biomasses with a high protein content. The reaction is carried out on a growth medium comprising a saline solution containing as a source of energy and of carbon exclusively methanol.
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公开(公告)号:DE2625028C3
公开(公告)日:1979-01-18
申请号:DE2625028
申请日:1976-06-03
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
Inventor: MARCONI, WALTER, SAN DONATO MILANESE, MAILAND , BARTOLI, FRANCESCO, ROM , GULINELLI, SILVIO , ZACCARDELLI, DELIO , MORISI, FRANCO, SAN GIOVANNI IN PERSICETO
Abstract: A method is disclosed for embedding sequestering agents in filamentary structures, the method comprising the steps of preparing an emulsion formed by an aqueous or nearly aqueous solution of the sequestering agent and a solution of the filament-forming polymer in an appropriate solvent, and spinning the emulsion in a coagulation bath.
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公开(公告)号:DE2521965B2
公开(公告)日:1978-12-07
申请号:DE2521965
申请日:1975-05-16
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
Inventor: RESCALLI, CARLO , GINNASI, ALESSANDRO, DR.
IPC: C07C7/08 , C07C1/00 , C07C7/00 , C07C7/10 , C07C7/148 , C07C11/09 , C07C11/167 , C07C41/06 , C07C67/00 , C07C7/01 , C07C43/04 , C07C43/14
Abstract: The present invention is directed to a process for the separation of butadiene from a stream-cracked C4 hydrocarbon stream by a sequential etherification of isobutylene and the acetylenic compounds that is followed by a distillation step.
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公开(公告)号:DE2522257B2
公开(公告)日:1978-07-13
申请号:DE2522257
申请日:1975-05-20
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
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公开(公告)号:DE2555556C3
公开(公告)日:1978-06-08
申请号:DE2555556
申请日:1975-12-10
Applicant: SNAMPROGETTI S.P.A., MAILAND (ITALIEN)
Abstract: A method is disclosed for the preparation of ytterbium(III) beta-diketonates, the improvement consisting in that the reaction between an ytterbium(III) halide and a chelating agent (such as acetylacetone, dibenzoylmethane and dipivaloylmethane for example) is caused to take place in an anhydrous medium and in the presence of gaseous ammonia, the ytterbium(III) halide being also anhydrous.
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