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公开(公告)号：KR100371516B1
公开(公告)日：2003-02-06
申请号：KR1020000025013
申请日：2000-05-10
Applicant: 제일모직주식회사
IPC: C09D5/25
Abstract: 본 발명은 CRT(Cathod Ray Tube) 유리표면의 코팅에 이용되는 코팅제 조성물, 특히 폴리에틸렌디옥시티오펜 수용액, 알콜 및 아마이드계 혼합용매, 알콕시실란, 수용성 고분자, 술폰산 모노머 도판트, 수분산성 카본블랙, 수분산성 유색안료, 알콜가용성 유색염료를 포함하는 대전방지성 착색 코팅제 조성물, 그의 제조 방법, 및 그를 이용한 유리표면의 코팅방법에 관한 것으로, 본 발명의 코팅제 조성물은 CRT 유리표면에 코팅되어 양호한 외관과 대전방지성을 가진 CRT를 제공한다.
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公开(公告)号：KR100364245B1
公开(公告)日：2002-12-16
申请号：KR1020000018269
申请日：2000-04-07
Applicant: 제일모직주식회사
IPC: C09D5/00
Abstract: 본 발명은 CRT(Cathod Ray Tube) 유리표면의 코팅에 이용되는 코팅제 조성물, 특히 폴리에틸렌디옥시티오펜 수용액, 알콜 및 아마이드계 혼합용매, 알콕시실란, 수용성 고분자, 술폰산 모노머 도판트, 수분산성 카본블랙, 및 수분산성 유색안료를 포함하는 대전방지성 착색 코팅제 조성물, 그의 제조 방법, 및 그를 이용한 유리표면의 코팅방법에 관한 것으로 본 발명의 코팅제 조성물은 내후성, 밀착성, 경도 등의 물성이 우수할 뿐만 아니라 CRT 유리표면에 코팅되는 경우 양호한 외관을 제공함과 동시에 생산비용이 저렴한 이점이 있다.
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公开(公告)号：KR1020010096959A
公开(公告)日：2001-11-08
申请号：KR1020000020663
申请日：2000-04-19
Applicant: 제일모직주식회사
IPC: C09D5/24
CPC classification number: C09D5/24 , C08K3/08 , C08K2003/0806 , C08K2003/085 , C09D1/00
Abstract: 본 발명은 도전성 재료로서 금속 분말, 구체적으로 은 분말 또는 은이 코팅된 동 분말을 매질을 매개체로 하여 혼합기의 임펠라에 의한 금속 분말과 매질간의 충격력 및 전단력에 의해서 비히클에 분산시키는 것을 특징으로 하는 도전성 페인트의 제조 방법 및 상기 방법으로 제조된 도전성 페인트 조성물에 관한 것으로서, 본 발명에 의한 도전성 페인트는 MHz 내지 GHz 영역의 전자파를 차단할 수 있기 때문에 특히 이동 통신 단말기, 사무기기, 의료기기등의 내부 소자로부터 발생되는 전자파에 의한 EMI(Electro Magnetic Interference; 전자파 방해) 및 RFI(Radio Frequency Interference; 무선 주파 방해) 문제를 해결하는 데에 유용하다.
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公开(公告)号：KR1020010092987A
公开(公告)日：2001-10-27
申请号：KR1020000015770
申请日：2000-03-28
Applicant: 제일모직주식회사
IPC: C09D5/00
Abstract: PURPOSE: Provided are an antistatic coloring coating agent used in coating the surface of CRT(Cathode Ray Tube) glass, the preparation method thereof, and the coating method using the agent. CONSTITUTION: The antistatic coloring coating agent comprises 6-26 wt.% of polyethylene dioxythiophene solution having 0.6-3.0 wt.% of solid concentration; 64-90 wt.% of alcohol and amide-based mixing solvent; 3-10 wt.% of alkoxy silane; 0.005-0.1 wt.% of water-soluble polymer; 0.005-0.05 wt.% of sulfonic acid monomer dopant; and 0.05-0.40 wt.% of water-dispersive carbon black. The method for preparing antistatic coloring coating agent comprises (a) putting polyethylene dioxythiophene solution into a reactor and stirring it; (b) adding an alcohol and amide-based mixing solvent, alkoxy silane, a sulfonic acid monomer dopant, and a water-soluble polymer and stirring the solution for 6 hours; and (c) adding water-dispersive carbon black to (b) and stirring it for at least 2 hours.
Abstract translation: 目的：提供用于涂覆CRT（阴极射线管）玻璃表面的抗静电着色涂层剂及其制备方法和使用该试剂的涂布方法。 构成：抗静电着色涂层剂含有6-26重量％的具有0.6-3.0重量％固体浓度的聚乙烯二氧噻吩溶液; 64-90重量％的醇和酰胺类混合溶剂; 3-10重量％的烷氧基硅烷; 0.005-0.1重量％的水溶性聚合物; 0.005-0.05重量％的磺酸单体掺杂剂; 和0.05-0.40重量％的水分散性炭黑。 制备抗静电着色涂层剂的方法包括：（a）将聚乙烯二氧噻吩溶液加入反应器中并搅拌; （b）加入醇和酰胺类混合溶剂，烷氧基硅烷，磺酸单体掺杂剂和水溶性聚合物，并搅拌该溶液6小时; 和（c）向（b）中加入水分散性炭黑并搅拌至少2小时。
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公开(公告)号：KR1020000040197A
公开(公告)日：2000-07-05
申请号：KR1019980055759
申请日：1998-12-17
Applicant: 제일모직주식회사
IPC: C09D5/24
Abstract: PURPOSE: A coating composition is provided that can be prepared by using a dispersion solvent and a high refractive inorganic sol which is a metal oxide dispersible in a conductive polymer solution with a high ratio and has a refraction ratio of RI = 1.60. CONSTITUTION: A coating composition for a conductive polymeric transparent thin film having a high refraction ratio comprises 2 to 20 wt% of an aqueous conductive polymer solution with a solid content of 1.2 to 1.5 wt%, 0.5 to 20 wt% of high refractive inorganic sol with a solid content of 14 to 16 wt%, 50 to 97.4 wt% of alcohol solvent having a carbon atom of 1 to 3 below, 0.1 to 10 wt% of amide solvent, 0.005 to 0.05 wt% of water-soluble or alcohol-soluble resin binder, and 0.005 to 0.05 wt% of sulfonic acid monomer dopant.
Abstract translation: 目的：提供一种涂料组合物，其可以通过使用分散溶剂和高折射率无机溶胶来制备，该无机溶胶是以高比例分散在导电聚合物溶液中并且折射率为RI = 1.60的金属氧化物。 构成：具有高折射率的导电聚合物透明薄膜用涂料组合物包含2至20重量％的固体含量为1.2-1.5重量％的导电聚合物溶液，0.5-20重量％的高折射率无机溶胶 固体含量为14〜16重量％，50〜97.4重量％的碳原子为1〜3的醇溶剂，0.1〜10重量％的酰胺系溶剂，0.005〜0.05重量％的水溶性或醇 - 可溶性树脂粘合剂和0.005〜0.05重量％的磺酸单体掺杂剂。
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Patent Agency Ranking
公开(公告)号：KR1020000031306A
公开(公告)日：2000-06-05
申请号：KR1019980047281
申请日：1998-11-05
Applicant: 제일모직주식회사
IPC: C08L81/02
CPC classification number: C08G61/126 , C09D5/24
Abstract: PURPOSE: A composition is provided to produce conductive film which has good conductivity and transparency and used for shielding electromagnetic wave. CONSTITUTION: A PEDT is a conductive polymer which is water-soluble, stable against temperature and atmosphere and has good transparency while forming film. The PEDT 16 to 32 wt% is needed to have both good transparency and conductivity. Alcohol solvent used for the PEDT polymer is methanol, ethanol, propanol, isopropanol and butanol. The solution composition is to add sulfonate monomer dopant, alcohol solvent and amide-based organic solvent in turn in a minute while stirring PEDT solution in the blunger: and to mix it homogeneously.
Abstract translation: 目的：提供一种具有良好导电性和透明性，用于屏蔽电磁波的导电膜的组合物。 构成：PEDT是一种导电聚合物，其水溶性，耐温度和气氛稳定，并且在形成膜时具有良好的透明性。 需要16至32wt％的PEDT具有良好的透明度和导电性。 用于PEDT聚合物的醇溶剂是甲醇，乙醇，丙醇，异丙醇和丁醇。 该溶液组合物是在搅拌PEDT溶液在搅拌器中的同时依次加入磺酸酯单体掺杂剂，醇溶剂和酰胺类有机溶剂，并均匀混合。
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公开(公告)号：KR1020000010221A
公开(公告)日：2000-02-15
申请号：KR1019980031011
申请日：1998-07-31
Applicant: 제일모직주식회사
IPC: C09D5/24
CPC classification number: C09D5/24 , C08L83/02 , C09D165/00
Abstract: PURPOSE: A transparent conductive hard coating film is applied to computers, television Braun tube glass surface, clean room's wall, hand carrier surface, CPP and PET film and PC and PMMA panel surface, portable telephone housing and PVC resin with good conductivity and transparency. CONSTITUTION: The hard coating film comprises a laminated coating of a polythiopene-based solution and a silica sol solution on a substrate. The polythiopene-based solution is prepared by mixing at least one solvent selected from the group consisting of alcohol, aldehydes and ketones with an aqueous or alcohol soluble polymer in an amide solvent. The silica sol solution is prepared by hydrolyzing and condensing silane compounds having three and four functional groups with an organic coupling agent. The substrate is selected from the group consisting of glass, polymethamethylacryl resin, polyacryl resin, polycarbonate resin, PET resin and PVC resin. The polyethylenedioxythiopene is doped with polystyrene sulfonate. The solvent is at least one selected from the group consisting of lower alcohol having one to four carbon atoms such as methanol, ethanol, propanol, isopropanol or acetaldehyde represented by the formula 1, and ketones such as acetone, methyl ethyl ketone or methyl isobutyl ketone. Formula 1:R1-C(O)-R2 (wherein R1 is H or C1-C10 alkyl or aryl; and R2 is C1-C10 alkyl or aryl).
Abstract translation: 目的：将透明导电硬涂膜应用于电脑，电视布朗管玻璃表面，洁净室墙壁，手提表面，CPP和PET膜以及PC和PMMA面板表面，便携式电话外壳和PVC树脂，导电性和透明度好。 构成：硬涂层包括在基板上的聚噻吩系溶液和硅溶胶溶液的层压涂层。 通过将选自醇，醛和酮的至少一种溶剂与水溶性或醇溶性聚合物在酰胺溶剂中混合来制备聚噻吩类溶液。 通过用有机偶联剂水解和缩合具有三个和四个官能团的硅烷化合物来制备二氧化硅溶胶溶液。 基材选自玻璃，聚甲基丙烯酸树脂，聚丙烯酸树脂，聚碳酸酯树脂，PET树脂和PVC树脂。 聚亚乙基二氧噻吩掺杂聚苯乙烯磺酸盐。 溶剂是选自由式1表示的甲醇，乙醇，丙醇，异丙醇或乙醛的具有一至四个碳原子的低级醇组成的组中的至少一种，酮类如丙酮，甲基乙基酮或甲基异丁基酮 。 式1：R1-C（O）-R2（其中R1是H或C1-C10烷基或芳基; R2是C1-C10烷基或芳基）。
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公开(公告)号：KR1020000001824A
公开(公告)日：2000-01-15
申请号：KR1019980022270
申请日：1998-06-15
Applicant: 제일모직주식회사
IPC: C09D5/24
CPC classification number: C09D5/24 , C09D165/00
Abstract: PURPOSE: A composition containing silica sol comprising polythiophene conductive polymer, alkoxysilane, C1-4 alcohol, and amide organic solvent is coated on glass or synthetic film to give an excellent scratchless and electromagnetic wave shielding performance. CONSTITUTION: The composition comprises 20-40 weight% of polythiophene conductive polymer solution, 4-12 weight% of alkoxysilane, 38-74 weight% of C1-4 alcohol such as methanol, ethanol, propanol, isopropanol, or butanol, and 2-10 weight% of amide organic solvent. The polythiophene conductive polymer solution is a mixture of polyethylenedioxythiophene and polystyrenesulfonate with a solid concentration of 1.0-1.5 weight%. The amide solvent is selected from formamide, N-methylformamide, N,N-dimethylformamide, acetamide, N-methylacetamide, N,N-dimethylacetamide, N-methylpropionamide, or N-methylpyrrolidone. The composition gives a high conductivity and transparency with a conductivity of below 1-20 (1 / kilo ohm), a transparency of 90-98%, and a film hardness of 4-6H.
Abstract translation: 目的：将包含聚噻吩导电聚合物，烷氧基硅烷，C 1-4醇和酰胺有机溶剂的二氧化硅溶胶的组合物涂覆在玻璃或合成膜上，以提供优异的无刮擦和电磁波屏蔽性能。 构成：该组合物包含20-40重量％的聚噻吩导电聚合物溶液，4-12重量％的烷氧基硅烷，38-74重量％的C 1-4醇如甲醇，乙醇，丙醇，异丙醇或丁醇，以及2- 10重量％的酰胺有机溶剂。 聚噻吩导电聚合物溶液是固体浓度为1.0-1.5重量％的聚亚乙基二氧噻吩和聚苯乙烯磺酸盐的混合物。 酰胺溶剂选自甲酰胺，N-甲基甲酰胺，N，N-二甲基甲酰胺，乙酰胺，N-甲基乙酰胺，N，N-二甲基乙酰胺，N-甲基丙酰胺或N-甲基吡咯烷酮。 该组合物具有导电率低于1-20（1 /千欧姆），透明度为90-98％，膜硬度为4-6H的高导电率和透明度。
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公开(公告)号：KR101050529B1
公开(公告)日：2011-07-20
申请号：KR1020080086507
申请日：2008-09-02
Applicant: 제일모직주식회사
IPC: H01B1/22
Abstract: 600℃ 이하의 공기분위기에서 소성이 가능하고, 반복소성 공정을 거치더라도 저항의 절대치 및 저항의 증가가 미미한 전극 형성용 조성물이 제공된다. 본 발명에 따른 전극 형성용 조성물은 하기 식 (1)의 입도분포폭이 2.0 이하이고 및
0.1≤D50≤20㎛ 범위의 D50 값을 가지는 가지는 알루미늄 분말 5~95중량%; 유기바인더 3~60 중량%; 잔량으로서 용제를 포함한다
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(상기 식(1)에서, D10, D50, D90은 전체중량을 100%하여 입도 분포의 누적곡선을 구할 때 이 누적 곡선이 각각 10%, 50%, 90%로 되는 점의 입경을 의미함)
또한, 상기 조성물을 이용하여 형성된 전극 및 PDP 소자도 제공된다.
600℃, 저항값, 조성물, 전극, 알루미늄, 분말, 입도분포-
公开(公告)号：KR1020110069697A
公开(公告)日：2011-06-23
申请号：KR1020100102102
申请日：2010-10-19
Applicant: 제일모직주식회사
Abstract: PURPOSE: A conductive paste for preparing a bus electrode of a plasma display panel is provided to improve withstand voltage of a bus electrode of a PDP apparatus by reducing edge curl and suppressing the increase of line resistance of bilayered bus electrode. CONSTITUTION: A conductive paste for preparing a bus electrode of a plasma display panel comprises conductive materials, glass frit, 1 - 10 weight% of urethane resin as an organic binder, and solvent. The conductive material includes one or more selected from the group consisting of silver(Ag), gold(Au), palladium(Pd), platinum(Pt), copper(Cu), chrome(Cr), cobalt(Co), aluminum(Al), tin(Sn), lead(Pb), zinc(Zn), iron(Fe), iridium(Ir), osmium(Os), rhodium(Rh), tungsten(W), molybdenum(Mo), nickel and ITO(Indium-Tin-Oxide).
Abstract translation: 目的：提供一种用于制备等离子体显示面板的总线电极的导电膏，以通过减少边缘卷曲并抑制双层母线电极的线路电阻的增加来改善PDP装置的总线电极的耐受电压。 构成：用于制备等离子体显示面板的总线电极的导电浆料包括导电材料，玻璃料，1-10重量％的作为有机粘合剂的聚氨酯树脂和溶剂。 导电材料包括选自银（Ag），金（Au），钯（Pd），铂（Pt），铜（Cu），铬（Cr），钴（Co），铝 Al），锡（Sn），铅（Pb），锌（Zn），铁（Fe），铱（Ir），锇（Os），铑（Rh），钨（W），钼（Mo） ITO（铟锡氧化物）。
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