公开(公告)号：DE3401834A1

公开(公告)日：1985-07-25

申请号：DE3401834

申请日：1984-01-20

Applicant: BASF AG

Inventor： MUENCH VOLKER DR ,  HAMBRECHT JUERGEN DR ,  NAARMANN HERBERT DR ,  ECHTE ADOLF DR ,  ILLERS KARL HEINZ DR

IPC: C08K13/02 ,  C08L25/00 ,  C08L61/04 ,  C08L23/00 ,  C08L25/04 ,  C08L9/00 ,  C08L15/00 ,  C08L19/00 ,  C08L21/00 ,  C08L51/04 ,  C08L55/02 ,  C08L61/06 ,  C08K5/00 ,  C08K5/02

Abstract: A flameproofed thermoplastic molding material consists of A. a thermoplastic resin containing a vinylaromatic monomer and furthermore contains B. from 0 to 100 parts by weight of an elastomer having a glass transition temperature Tg 0 DEG C., as an impact modifier, C. from 2 to 50 parts by weight of a halogen-containing organic compound (flameproofing agent), D. from 0.5 to 20 parts by weight of a compound containing a metal or non-metal (synergistic agent) and E. from 5 to 50 parts by weight of a novolak (phenol/aldehyde resin). The novolak is obtained from an aldehyde of the formula (I) R1-CHO (I) where R1 is H, C1-C10-alkyl, cycloalkyl, C6-C12-aryl or omega -aryl-C1-C3-alkyl, and a mixture of phenols, and this mixture contains two or more monosubstituted phenols and the substituents can be alkyl of 1 to 8 carbon atoms or CN. The molding material is used for the production of flameproofed moldings.

公开(公告)号：DE3344977A1

公开(公告)日：1985-06-20

申请号：DE3344977

申请日：1983-12-13

Applicant: BASF AG

Inventor： HAMBRECHT JUERGEN DR ,  MUENCH VOLKER DR ,  ECHTE ADOLF DR ,  SWOBODA JOHANN DR

IPC: C08K5/00 ,  C08L71/04 ,  C08L25/04 ,  C09K15/04

Abstract: Thermoplastic moulding compositions based on polyphenylene ethers and optionally on impact-modified styrene polymers, which additionally contain a metal-deactivating antioxidant.

公开(公告)号：DE3326393A1

公开(公告)日：1985-01-31

申请号：DE3326393

申请日：1983-07-22

Applicant: BASF AG

Inventor： REFFERT RUDI WILHELM ,  HAMBRECHT JUERGEN DR ,  MUENCH VOLKER DR ,  ECHTE ADOLF DR ,  SWOBODA JOHANN DR ,  GAUSEPOHL HERMANN DR

IPC: C08G65/46 ,  C08K5/16 ,  C08G65/44

公开(公告)号：DE3244899A1

公开(公告)日：1984-06-07

申请号：DE3244899

申请日：1982-12-04

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  MUENCH VOLKER DR ,  PENZIEN KLAUS DR

IPC: C08F8/28 ,  H01B1/12 ,  H01L31/0224 ,  H01L51/30 ,  C08F8/00 ,  C08F8/40 ,  C08F38/00 ,  C08L43/02 ,  C08L49/00 ,  H01L31/04

Abstract: A process for the preparation of electroconductive conjugated polymers having electrical conductivities of greater than 6 . 10 S/cm, in which phosphonium ylides of polyenes are reacted with aldehydes or ketones which contain a conjugated pi -electron system in the molecule, and the resultant polymer is subsequently treated with conventional complexing agents.

公开(公告)号：DE3237735A1

公开(公告)日：1984-04-12

申请号：DE3237735

申请日：1982-10-12

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  MUENCH VOLKER DR ,  PENZIEN KLAUS DR

IPC: C08F38/02

Abstract: Process for the preparation of polyacetylenes by homopolymerisation or copolymerisation of acetylene and/or acetylene compounds in the presence of certain metal catalysts and white phosphorus or phosphorus compounds containing a P-P bond.

公开(公告)号：DE3162512D1

公开(公告)日：1984-04-12

申请号：DE3162512

申请日：1981-07-09

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  MUENCH VOLKER DR ,  PENZIEN KLAUS DR

IPC: C08K5/50 ,  C08L65/02 ,  H01B1/12 ,  H01L31/02 ,  H01L51/30 ,  H01L51/42 ,  H01L29/28

公开(公告)号：DE3232483A1

公开(公告)日：1984-03-01

申请号：DE3232483

申请日：1982-09-01

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  MUENCH VOLKER DR ,  FRANZ KLAUS-DIETER DR

IPC: C09K3/16 ,  C08F8/00 ,  C08F38/00 ,  C08L49/00 ,  C08L101/00 ,  G02F1/15 ,  G02F1/17 ,  H01B1/12 ,  H01L31/02 ,  H01L51/30 ,  H01L51/42 ,  H01M4/60 ,  H01L31/04 ,  H01B3/30

Abstract: Polymers which comprise polyene units possessing 5 or more conjugated aliphatic C-C double bonds and contain 1,9-disubstituted phenalenes as chemically bonded side groups are prepared by a process in which acetylene derivatives carrying 1,9-disubstituted phenalene groups are polymerized. The polymers obtained are used in the electrical industry or as reversible redox systems or for the antistatic treatment of plastics.

公开(公告)号：DE3225876A1

公开(公告)日：1984-01-12

申请号：DE3225876

申请日：1982-07-10

Applicant: BASF AG

Inventor： HAMBRECHT JUERGEN DR ,  MUENCH VOLKER DR ,  BANKOWSKY HEINZ-HILMAR ,  WISTUBA ECKEHARDT DR

IPC: C08F212/00 ,  C08F212/06 ,  C09D11/10 ,  C09D11/107 ,  C08F220/04 ,  C08F222/02

公开(公告)号：DE3114967A1

公开(公告)日：1982-11-04

申请号：DE3114967

申请日：1981-04-13

Applicant: BASF AG

Inventor： MUENCH VOLKER DR ,  BRANDSTETTER FRANZ DR ,  NAARMANN HERBERT DR ,  PENZIEN KLAUS DR

IPC: C08K5/5397 ,  C08K5/53

Abstract: The invention relates to a thermoplastic moulding composition comprising a thermoplastic resin (A), a chlorine- or bromine-containing organic compound, the flameproofing agent (B), and a polymeric phospholine oxide as synergist for B. The composition may furthermore contain conventional additives (D).

公开(公告)号：DE3018389A1

公开(公告)日：1981-11-19

申请号：DE3018389

申请日：1980-05-14

Applicant: BASF AG

Inventor： MUENCH VOLKER DR ,  NAARMANN HERBERT DR ,  PENZIEN KLAUS DR

IPC: C08F4/00 ,  C08F4/06 ,  C08F26/06 ,  C08F32/08 ,  C08F38/00 ,  H01L51/30 ,  C08F26/00 ,  C08L39/00 ,  H01L31/06

Abstract: A process for the preparation of electrically conductive polymers by polymerizing acenaphthylene, N-vinyl-heterocyclics, eg. N-vinylcarbazole or N-vinylpyridine, or N,N-divinylaniline at from -80 DEG to +100 DEG C. in the presence of a cationtic catalyst, wherein from 1 to 50 percent by weight of an oxidizing Lewis acid, preferably FeCl3, FeBr3, SbCl5, SbF5, AsF5 or CF3-SO3H, or a combination of AlCl3 or TiCl4 with the said compounds or with CrO3 or OsO4 is used as the catalyst. In a preferred embodiment of the process, thin films of the monomers to be polymerized, applied to glass or to a polymeric base, preferably to a plastic film, are treated with gaseous SbCl5, SbF5 or AsF5. The conductive polymers obtained can be used in the electrical industry for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches, as well as for the antistatic treatment of plastics.