PLANT-PROTECTING COMPOSITIONS CONTAINING BETA-PIKOLINE DERIVATIVES AS ACTIVE COMPONENTS AND PROCESS FOR PRODUCING THE ACTIVE COMPONENTS

    公开(公告)号:HUT58184A

    公开(公告)日:1992-02-28

    申请号:HU189691

    申请日:1991-06-06

    Applicant: BASF AG

    Abstract: Beta-picoline derivs. (I) and their N-oxides and addn. salts are new. In (I), A = CR1R2; R1, R2 = H, 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; or R1+R2 = 2-6C n-alkylene; B = CH2, CHOR3, CHR4 or C=NOR5; R3 = H, 1-6C alkyl, 1-6C haloalkyl, 3-8C cycloalkyl, 3-6C alkenyl, 2-6C acyl or phenyl, benzyl or benzoyl opt. mono-, di- or tri-substd. in the ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, halogen, cyano or nitro; R4 = H, F, Cl, Br or I; R5 = H, 1-6C alkyl, 1-6C haloalkyl, 3-7C cycloalkyl, 3-6C alkenyl or aryl-1-4C alkyl opt. mono-, di- or tri-substd. in the aryl ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, halogen, cyano or nitro; Ar = phenyl or naphthyl opt. mono-, di- or tri-substd. by halogen, 1-6C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, phenyl, phenoxy, halophenyl, halophenoxy or benzyloxy; except 1-phenyl-3-(3-pyridyl) propan-1-one (IA). The use of cpd. (IA), which is known from J. Org. Chem. 43 (1978), 3396 and Arch. Pharm. 307 (1974), 550, for the control of fungi is also claimed. Further, intermediates (II) are claimed except where A = CH2 or CH(CH3). 3 Cpds. (I), e.g., 2-ethyl-1-(4-fluorophenyl) -2-(pyridyl-3-methyl)butan-1-ol, are specifically claimed.

    New beta-picoline derivs.
    72.
    发明专利

    公开(公告)号:DE4018260A1

    公开(公告)日:1991-12-12

    申请号:DE4018260

    申请日:1990-06-07

    Applicant: BASF AG

    Abstract: Beta-picoline derivs. (I) and their N-oxides and addn. salts are new. In (I), A = CR1R2; R1, R2 = H, 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; or R1+R2 = 2-6C n-alkylene; B = CH2, CHOR3, CHR4 or C=NOR5; R3 = H, 1-6C alkyl, 1-6C haloalkyl, 3-8C cycloalkyl, 3-6C alkenyl, 2-6C acyl or phenyl, benzyl or benzoyl opt. mono-, di- or tri-substd. in the ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, halogen, cyano or nitro; R4 = H, F, Cl, Br or I; R5 = H, 1-6C alkyl, 1-6C haloalkyl, 3-7C cycloalkyl, 3-6C alkenyl or aryl-1-4C alkyl opt. mono-, di- or tri-substd. in the aryl ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, halogen, cyano or nitro; Ar = phenyl or naphthyl opt. mono-, di- or tri-substd. by halogen, 1-6C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, phenyl, phenoxy, halophenyl, halophenoxy or benzyloxy; except 1-phenyl-3-(3-pyridyl) propan-1-one (IA). The use of cpd. (IA), which is known from J. Org. Chem. 43 (1978), 3396 and Arch. Pharm. 307 (1974), 550, for the control of fungi is also claimed. Further, intermediates (II) are claimed except where A = CH2 or CH(CH3). 3 Cpds. (I), e.g., 2-ethyl-1-(4-fluorophenyl) -2-(pyridyl-3-methyl)butan-1-ol, are specifically claimed.

    73.
    发明专利
    未知

    公开(公告)号:ES2166127T3

    公开(公告)日:2002-04-01

    申请号:ES98123302

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

    74.
    发明专利
    未知

    公开(公告)号:DE59509762D1

    公开(公告)日:2001-11-29

    申请号:DE59509762

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

    75.
    发明专利
    未知

    公开(公告)号:DE59509761D1

    公开(公告)日:2001-11-29

    申请号:DE59509761

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

    76.
    发明专利
    未知

    公开(公告)号:AT207293T

    公开(公告)日:2001-11-15

    申请号:AT98123303

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

    77.
    发明专利
    未知

    公开(公告)号:AT207292T

    公开(公告)日:2001-11-15

    申请号:AT98123302

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

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