公开(公告)号：EP1080089B1

公开(公告)日：2003-11-05

申请号：EP99924925.3

申请日：1999-05-10

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： WITSCHEL, Matthias ,  LANGEMANN, Klaus ,  VON DEYN, Wolfgang ,  MISSLITZ, Ulf ,  BAUMANN, Ernst ,  ENGEL, Stefan ,  MAYER, Guido ,  NEIDLEIN, Ulf ,  WAGNER, Oliver ,  OTTEN, Martina ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut

IPC: C07D409/06 ,  C07D409/14 ,  A01N43/56

CPC classification number: C07D409/06 ,  A01N43/56 ,  C07D409/14 ,  C07F9/65586

Abstract: The invention relates to pyrazolyldioxothiochromanoyl derivatives of formula (I) in which the variables have the following meanings: X represents oxygen, sulfur, S=O, S(=O)2, CR4R5, C=O or C=NR6; R1 hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, alkyl sulfinyl, alkyl sulfinyl halide, alkyl sulfonyl, alkyl sulfonyl halide, optionally substituted amino sulfonyl or optionally substituted sulfonyl amino; R2 represents alkyl, alkyl halide, alkoxy or alkoxy halide; R3 represents hydrogen, alkyl or halogen; R4, R5 represent hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, alkyl sulfinyl, alkyl sulfinyl halide, alkyl sulfonyl, alkyl sulfonyl halide or optionally substituted amino; or R?4 and R5¿ jointly construct a chain which can be substituted and/or discontinued by oxygen or sulfur; or an optionally substituted methylidene group; l represents 0 to 4; and R7 represents substituted pyrazole-4-yl-carbonyl or substituted pyrazole-4-yl-methylidene. The invention also relates to the salts of said derivatives which can be used for agricultural purposes, to a method for producing the pyrazolyldioxothiochromanoyl derivatives, to agents containing the same, and to the use of these derivatives or agents containing the same for controlling undesirable plants.

Abstract translation: 本发明涉及式（I）的吡唑基二氧代二氢苯并噻喃酰基衍生物，其中变量具有以下含义：X代表氧，硫，S = O，S（= O）2，CR4R5，C = O或C = NR6; 卤素，氰基，烷基，烷基卤，烷氧基，烷氧基卤化物，烷基硫基，烷基硫代卤化物，烷基亚磺酰基，烷基亚磺酰卤，烷基磺酰基，烷基磺酰卤，任选取代的氨基磺酰基或任选取代的磺酰基氨基; R2表示烷基，烷基卤，烷氧基或烷氧基卤化物; R3代表氢，烷基或卤素; 硝基，卤素，氰基，烷基，烷基卤，烷氧基，烷氧基卤，烷基硫基，烷基硫代卤化物，烷基亚磺酰基，烷基亚磺酰卤，烷基磺酰基，烷基磺酰卤或任选取代的氨基; 或R 4和R 5'共同构成可被氧或硫取代和/或中断的链; 或任选取代的亚甲基; l表示0至4; 并且R 7代表取代的吡唑-4-基 - 羰基或取代的吡唑-4-基 - 亚甲基。 本发明还涉及可用于农业目的的所述衍生物的盐，制备吡唑基二氧代二氢苯并噻喃酰基衍生物的方法，含有它们的试剂，以及这些衍生物或含有它们的试剂用于防治不希望的植物的用途。

公开(公告)号：EP0960095B1

公开(公告)日：2003-10-01

申请号：EP97954746.0

申请日：1997-12-19

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： KARDORFF, Uwe ,  HILL, Regina, Luise ,  RACK, Michael ,  VON DEYN, Wolfgang ,  ENGEL, Stefan ,  OTTEN, Martina ,  WITSCHEL, Matthias ,  BAUMANN, Ernst ,  RHEINHEIMER, Joachim ,  MAYER, Guido ,  MISSLITZ, Ulf ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut

IPC: C07C251/60 ,  C07C251/86 ,  A01N33/24 ,  A01N33/26

CPC classification number: C07D335/02 ,  A01N37/42 ,  A01N41/10 ,  A01N43/08 ,  A01N43/16 ,  A01N43/18 ,  A01N43/32 ,  C07C45/46 ,  C07C243/38 ,  C07C259/10 ,  C07C317/44 ,  C07C317/46 ,  C07C2601/16 ,  C07D309/04 ,  C07D319/12 ,  C07D333/28 ,  C07C49/807

Abstract: The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, alkyl, halogen alkyl or alkinyl; R4 stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or sulphur; m equals 0 or 1; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted cyclohexan-1,3-dione ring linked in position 2, whereas m equals 1 when R3 stands for hydrogen. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

Abstract translation: 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮，其中R 1，R 2为氢，硝基，卤素，氰基，氰硫基，烷基，卤代烷基，烷氧基烷基，烯基，炔基，-OR 5，-OCOR 6，-OSO 2 R 6 - SH，-S（O）nR7，-SO2OR5，-SO2NR5R8，-NR8SO2R6或-NR8COR6; R3是氢，烷基，卤代烷基，烯基或炔基; R4是氢，未取代或取代的烷基，环烷基，烯基，环烯基，炔基， -COR 9，-CO 2 R 9，-COSR 9或-CONR 8 R 9; X为氧或硫; Z为氧或NR 8; m为0或1; n为0,1或2; R 5为氢，烷基，卤代烷基，烷氧基烷基， 炔基; R 6是烷基，卤代烷基，烯基或炔基; R 8是氢或烷基; R 9是烷基，烯基，炔基，苯基或苄基; 在2-位连接的未取代或取代的环己烷-1,3-二酮环;如果R3是氢，其中m为1;其农业上有用的盐;制备的方法和中间体o f式I化合物; 包含它们的组合物; 以及包含它们的这些衍生物或组合物用于防治不需要的植物的用途。

公开(公告)号：EP0966453B1

公开(公告)日：2003-07-23

申请号：EP98912327.8

申请日：1998-02-18

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： WALTER, Helmut ,  PLATH, Peter ,  KARDORFF, Uwe ,  WITSCHEL, Matthias ,  HILL, Regina, Luise ,  VON DEYN, Wolfgang ,  ENGEL, Stefan ,  OTTEN, Martina ,  MISSLITZ, Ulf ,  WESTPHALEN, Karl-Otto

IPC: C07D275/06 ,  A01N43/80

CPC classification number: C07D275/06 ,  A01N43/80

Abstract: The invention concerns saccharine-5-carbonyl-cyclohexane-1,3,5-trione derivatives of formula (I), in which the substituents have the following meanings: L is C1-C3 alkyl, C1-C3 alkoxy; Z is C1-C4 alkyl, C3-C8 cycloalkyl, C3-C6 alkenyl, C3-C5 alkinyl, benzyl or phenyl, the phenyl rings each optionally being substituted one or a plurality of times by C1-C4 alkyl, C1-C3 alkoxy or halogen; M is hydrogen, C1-C3 alkyl, C1-C3 alkoxy, fluorine, chlorine, cyano, nitro or trifluoromethyl; and R , R , R , R are C1-C4 alkyl. The invention further concerns salts of compound (I) which can be used in agriculture.

公开(公告)号：EP0879239B1

公开(公告)日：2003-04-23

申请号：EP97904454.2

申请日：1997-02-17

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： ZAGAR, Cyrill ,  HEISTRACHER, Elisabeth ,  MENKE, Olaf ,  HAMPRECHT, Gerhard ,  MENGES, Markus ,  SCHÄFER, Peter ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf ,  WALTER, Helmut

IPC: C07F9/6512 ,  A01N57/08 ,  C07F9/6503 ,  C07F9/553 ,  C07F9/6506 ,  C07F9/6561 ,  C07F9/6539 ,  C07F9/40 ,  C07F9/6509

CPC classification number: C07F9/6561 ,  A01N57/24 ,  A01N57/32 ,  C07F9/4015 ,  C07F9/4056 ,  C07F9/5537 ,  C07F9/65033 ,  C07F9/65038 ,  C07F9/65062 ,  C07F9/650911 ,  C07F9/65121 ,  C07F9/6539 ,  C07F9/65583 ,  C07F9/65586

公开(公告)号：EP1296920A2

公开(公告)日：2003-04-02

申请号：EP01960460.2

申请日：2001-07-04

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： LANGEMANN, Klaus ,  MISSLITZ, Ulf ,  BAUMANN, Ernst ,  VON DEYN, Wolfgang ,  KUDIS, Steffen ,  VOLK, Thorsten ,  MAYER, Guido

IPC: C07C45/42 ,  C07C45/29

CPC classification number: C07C255/47 ,  C07C17/00 ,  C07C45/27 ,  C07C45/29 ,  C07C45/298 ,  C07C45/673 ,  C07C49/433 ,  C07C2602/44 ,  C07C23/30 ,  C07C49/693

Abstract: The invention relates to a method for producing compounds of formula (I), whereby: a) a bicyclic olefin of formula (II) is reacted with haloform in the presence of a base to produce the ring-enlarged product of formula (III); b) the compound of formula (III) is hydrolyzed to produce the allyl alcohol of formula (IV); c) the allyl alcohol of formula (IV) is oxidized to produce the unsaturated ketone of formula (V); d) the ketone of formula (V) is reacted with a nucleophilic ion Y, which stabilizes a negative charge, to produce the ketone of formula (VI), and; e) the ketone of formula (VI) is hydrolyzed to produce the bicyclic 1,3-diketone of formula (I). In formulas (I) to (VI), R1-R5, X, Y and Z have the meanings as cited in the description. The invention also relates to novel intermediate products and to novel methods for producing these intermediate products.

Abstract translation: 制备式I其中R 1，R 2，R 3和R 4的双环1,3-二酮的方法是氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基 - 羰基，卤素 氰基，硝基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基硫基或C 1 -C 4 - 烷基磺酰基，Z是C 1 -C 4亚烷基，O，S，NR 5，其中R 5是C 1 -C 4烷基或C 1 -C4 - 烷基羰基，其包括在碱存在下使式II的双环烯烃与卤代甲基反应，得到式III的环扩展产物，其中R 1 -R 4和Z如上所定义，X如上所定义，X 将式III的化合物的烯丙基卤水解成式IVc的烯丙醇，将式Ⅳ的烯丙醇氧化为式ⅤⅤ的不饱和酮）使式Ⅴ的酮与 亲核离子Y - ，其稳定负电荷，得到式VIe的酮）将式VI的酮水解成式I的双环1,3-二酮，新的中间体和新的制备方法 描述这些中间体。

公开(公告)号：EP0846113B1

公开(公告)日：2003-01-29

申请号：EP96927702.9

申请日：1996-08-07

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  KLINTZ, Ralf ,  SCHÄFER, Peter ,  ZAGAR, Cyrill ,  SCHIFFER, Helmut ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf ,  WALTER, Helmut

IPC: C07D401/04 ,  A01N43/56 ,  A01N43/40

CPC classification number: C07D231/12 ,  A01N43/56 ,  C07D233/56 ,  C07D249/08 ,  C07D401/04

Abstract: The invention concerns substituted 1-(pyridyl)-pyrazols of general formula (I) in which the substituents have the following meanings: R1: hydrogen, C¿1?-C3 alkyl, halogen, C1-C3 alkyl halide; R?2: C¿1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkinyl, C1-C4 alkoxy, C3-C4 alkenyloxy, C3-C4 alkinyloxy, which can be substituted by 1 to 6 halogen atoms, NO2, cyano, halogen, rhodano, amino, furthermore a C(=O)R7, S(O)¿nR?8 or NH-C(=O)R9 group; R3: amino, halogen, rhodano, cyano, nitro, hydroxy, C¿1?-C3 alkyl, C1-C3 alkyl halide, furthermore an S(O)nR?8, N(R10)R11, OR12, SR13, N=C(R14)-N(R15)R16¿ group or, if R1 = hydrogen, additionally N=C(R?17)R18; R4¿: halogen, an XR19 group or, if R3 = N=C(R?14)-N(R15)R16¿ and N(R?10)R11 when R10¿ = hydrogen or C(=O)R?7 and R11 = C¿3-C4 alkenyl or C3-C4 alkinyl or, if R6 = fluorine or trifluoromethyl, additionally hydrogen; and R5, R6: independently of each other, halogen or C¿1?-C3 alkyl halide. The invention further concerns the N-oxides and salts of compounds (I) which can be used for agricultural purposes, processes for their preparation and their use as herbicides.

公开(公告)号：EP0891336B1

公开(公告)日：2002-06-05

申请号：EP97907086.9

申请日：1997-03-10

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： MENKE, Olaf ,  HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  KLINTZ, Ralf ,  SCHÄFER, Peter ,  ZAGAR, Cyrill ,  MENGES, Markus ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut ,  MISSLITZ, Ulf

IPC: C07D239/54 ,  C07C271/22 ,  C07C275/24 ,  A01N43/54

CPC classification number: C07D239/54 ,  A01N43/54 ,  C07D405/10 ,  C07D405/12 ,  C07D409/10

Abstract: The invention concerns substituted 1-methyl-3-benzyluracils (I) and their salts and enol ethers as herbicides or desiccating/defoliating agents. In formula (I), R1 is C1-C4 alkyl halide; R2 is H or halogen; R3 is R2, CN, SCN, C¿1?-C4 alkyl halide, C1-C4 alkoxy halide or C1-C4 alkylthio halide; R?4 is R3, C¿1-C4 alkyl, C1-C4 alkoxy or (C1-C6 alkylamino)-CO-; R5 is R2, CN, NO¿2?, OH, optionally substituted amino, alkoxy, alkylthio, alkyl-CO2-, alkyl-COS-, alkyl-SO2-O- or alkyl-SO2-, the six last-mentioned groups optionally being functionalized and/or substituted; R?6¿, if it is in the α position with R5 then being in the β position, is OH, SH, alkyl, alkoxy, alkylthio, alkyl-CO¿2?-, alkyl-COS-, alkoxy-CO-, alkoxy-CO2-, alkyl-SO2-O-, alkyl-SO2-, alkyl-CO-, alkyl-CS-, alkyl-(N-alkyl)-imino or alkyl-(N-alkoxy)-imino, the thirteen last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted twice by optionally substituted alkoxy and alkylthio and optionally substituted once by alkyl; or R?6¿ in the β position, with R5 then being in the α position, has the above meanings, as well as alkyl-amino-CO-, alkoxy-CO-, alkylthio-CO-, alkyl-CO-, alkylimino-oxycarbonyl, alkyl-(N-alkoxy)-imino, alkoxy-(N-alkoxy)-imino or alkylthio-(N-alkoxy)-imino, the eight last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted three times by optionally substituted alkoxy, alkylthio and alkylamino.

公开(公告)号：EP1194407A2

公开(公告)日：2002-04-10

申请号：EP00945814.2

申请日：2000-06-23

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： NEIDLEIN, Ulf ,  GÖTZ, Norbert ,  BAUMANN, Ernst ,  VON DEYN, Wolfgang ,  KUDIS, Steffen ,  GÖTZ, Roland ,  LANGEMANN, Klaus ,  MAYER, Guido ,  MISSLITZ, Ulf ,  WITSCHEL, Matthias ,  OTTEN, Martina ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut

IPC: C07D231/20 ,  A01N43/56

CPC classification number: A01N43/56 ,  C07D231/20

Abstract: The invention relates to cycloalkyl-substituted benzoyl pyrazoles of formula (I) wherein said variables can, for example, have the following meanings: R1 = hydrogen, nitro, halogen, cyano, rhodano or an optionally substituted aliphatic radical; R2 = an optionally substituted aliphatic radical, halogen, nitro, in addition to substituted sulfonyl or amino groups; R3 = hydrogen, halogen, C¿1-C?6-alkyl, C¿1?-C6-halogenalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C?6¿-alkinyl; R4, R5 = hydrogen, nitro, halogen, cyano, rhodano, an optionally substituted aliphatic radical or substituted sulfonyl or amino groups; R6 = hydrogen, halogen, C¿1?-c6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R?7¿ = a cyclic ring system with 3 - 14 ring atoms; R16 = hydroxy or a substituted hydroxy group; in addition to tautomers or agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as herbicides.

公开(公告)号：EP1181295A2

公开(公告)日：2002-02-27

申请号：EP00940273.6

申请日：2000-05-26

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： WITSCHEL, Matthias ,  KUDIS, Steffen ,  LANGEMANN, Klaus ,  BAUMANN, Ernst ,  DEYN, Wolfgang von ,  MAYER, Guido ,  MISSLITZ, Ulf ,  NEIDLEIN, Ulf ,  OTTEN, Martina ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut

IPC: C07D495/04 ,  C07D498/04 ,  A01N43/90

CPC classification number: C07D495/04

Abstract: The invention relates to tricyclic benzoylcyclohexanedione derivatives of formula (I), wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR?6R7, NR8¿ or a bond; y forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle with the two carbons to which it is bonded; R?1, R2, R6, R7¿ is hydrogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R3 is halogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R4 is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, C¿1?-C6- alkylthio halide, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl, or optionally substituted sulfonylamino; R?5¿ is hydrogen, alkyl or halogen; m is 0, 1 or 2; R8 is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide; and R9 is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene; and to agriculturally useable salts thereof. The invention also relates to a method for producing the tricyclic benzoylcyclohexanedione derivatives, to products containing them and to the use of said derivatives or said products containing them for combating unwanted vegetation.

Abstract translation: 本发明涉及式（I）的三环苯甲酰基环己二酮衍生物，其中各变量具有以下含义：X是氧，硫，S = O，S（= O）2，CR 6 R 7，NR 8或键; y与其所键合的两个碳形成饱和的，部分饱和或不饱和的5-或6-元杂环; R 1，R 2，R 6，R 7是氢，烷​​基，烷基卤，烷氧基或烷氧基卤化物; R3是卤素，烷基，烷基卤，烷氧基或烷氧基卤化物; 卤素，氰基，烷基，烷基卤，烷氧基，烷氧基卤，烷硫基，C1-C6烷硫基卤，烷基亚磺酰基，烷基亚磺酰卤，烷基磺酰基，烷基磺酰卤，任选取代的氨基磺酰基或任选取代的磺酰氨基 ; R 5是氢，烷基或卤素; m是0,1或2; R8为氢，烷基，烷基卤，烷基羰基，甲酰基，烷氧基羰基，烷氧基羰基卤，烷基磺酰基或烷基磺酰卤; （3-氧代-1-环己烯-2-基） - 羰基或取代的（1,3-二氧代-2-环己基） - 亚甲基; R 9为取代的（3-氧代-1-环己烯-2-基） 并涉及其可农用盐。 本发明还涉及生产三环苯甲酰基环己二酮衍生物的方法，含有它们的产品以及所述衍生物或含有它们的所述产品用于防治不想要的植物的用途。

公开(公告)号：EP1163240A1

公开(公告)日：2001-12-19

申请号：EP00915171.3

申请日：2000-03-08

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： WITSCHEL, Matthias ,  KUDIS, Steffen ,  LANGEMANN, Klaus ,  BAUMANN, Ernst ,  VON DEYN, Wolfgang ,  MAYER, Guido ,  MISSLITZ, Ulf ,  NEIDLEIN, Ulf ,  OTTEN, Martina ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut

IPC: C07D413/06 ,  C07D498/04 ,  C07D495/04 ,  C07D491/04 ,  A01N43/90 ,  A01N43/80 ,  C07D261/20

CPC classification number: C07D413/06 ,  A01N43/80 ,  A01N43/90 ,  C07D491/04 ,  C07D495/04

Abstract: The invention relates to tricyclic benzoylpyrazole derivatives of formula (I), wherein the variables have the following meanings: X is oxygen or sulphur, S=O, S(=O)2, CR?6R7, NR8¿ or a bond; Y, together with the two other carbons to which it is bonded, forms a saturated, partially saturated or unsaturated 5 or 6-membered heterocycle; R?1, R2, R6, R7¿ are hydrogen, alkyl, alkyl halide, alkoxy or halogenalkoxy; R3 is halogen, alkyl, alkyl halide, alkoxy or halogenalkoxy; R4 is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogen alkylthio, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl or optionally substituted sulfonylamino; R5 is hydrogen, alkyl or halogen; l is 0, 1 or 2; R8 is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide and R9 is substituted pyrazole-4-yl-carbonyl or substituted 5-oxo-pyrazolin-4-yl-methylides; and the agriculturally useable salts thereof. The invention also relates to a method and intermediate products for producing tricyclic benzoylpyrazole derivatives, to products which contain the same and to the use of said derivatives or said products for combating undesirable plants.