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    71.
    发明专利
    未知

    公开(公告)号：CH601428A5

    公开(公告)日：1978-07-14

    申请号：CH1790573

    申请日：1973-12-20

    Applicant: BASF AG

    Inventor： DEHNERT JOHANNES DR ,  LAMM GUNTHER DR

    IPC: C07D213/82 ,  C07D213/85 ,  C09B29/42 ,  C09B31/153 ,  C09B29/36 ,  C09B31/14

    Abstract: Azo dyes having a 2,6-diamino-pyridine as coupling component, one of the amino groups bearing a bicyclic or polycyclic non-aromatic radical as a substituent. The dyes are eminently suitable as disperse dyes, particularly for synthetic linear polyesters, and give bright dyeings having excellent fastness properties.

    AZO DYES FROM 2,6-DIAMINOPYRIDINE DERIVATIVES
    75.
    发明专利
    AZO DYES FROM 2,6-DIAMINOPYRIDINE DERIVATIVES 未知

    公开(公告)号：GB1377505A

    公开(公告)日：1974-12-18

    申请号：GB5865371

    申请日：1971-12-17

    Applicant: BASF AG

    Inventor： DEHNERT JOHANNES DR ,  LAMM GUNTHER DR

    IPC: C07D213/74 ,  C07D213/82 ,  C07D213/85 ,  C07D401/06 ,  C09B29/42 ,  C09B31/153 ,  C09B39/00 ,  C09B43/00 ,  C09B43/20 ,  C09B29/36 ,  C09B31/14

    Abstract: 1377505 Azo dyes from 2,6-diaminopyridine coupling components BADISCHE ANILIN- & SODA-FABRIK AG 17 Dec 1971 [19 Dec 1970 15 Nov 1971] 58653/71 Heading C4P Novel dyestuffs of the formula in which D is the radical of a diazo component the linking bond of which is attached to a condensed or uncondensed benzene, thiophene, isothiazole, thiazole, thiadiazole, triazole or pyrazole ring; X is -CN or -CONH 2 ; NR 2 R 3 may independently have any of the values of NRR 1 ; and either NRR 1 is pyrrolidino, piperidino, morpholino, the S-dioxide of thiomorpholino, piperazino or N 1 -methylpiperazino or R 1 is H or C 1-8 alkyl optionally substituted by OH, NH 2 or C 1-8 alkoxy or mono- or di-alkylamino and R is R 1 , C 1-8 alkyl which may also optionally be substituted by phenyl, phenoxy, optionally esterified carboxy or C 1-10 acyloxy, any of the open chains in the foregoing R groups optionally being interrupted by oxygen, or R is ethyl or propyl substituted in the omega position by an N-atom which is part of a 2-pyrrolidone or morpholine-S-oxide ring, or R is allyl, cyclohexyl optionally substituted by hydroxy or acyloxy, or phenyl optionally substituted by Cl, CN, CH 3 , OCH 3 , CH 3 NHCO, CH 3 OC 2 H 4 NHCO, C 2 H 5 , OC 2 H 5 , 2-hydroxyethyl, 2-hydroxyethoxy or 2-acyloxyethoxy are prepared by coupling of diazotized amines DNH 2 with appropriately substituted 3-cyano or carbamoyl-4-methylpyridines. Products wherein X is CN may be hydrolysed to the corresponding amides, and products containing free OH or CO 2 H groups may be acylated or esterified. The new dyes are yellow to green-blue and are suitable for dyeing acrylonitrile polymer textile material and, particularly, textile material of synthetic polyamides, cellulose esters and synthetic linear polyesters. The coupling components and their' 6-chloroprecursors are described and claimed in Specification 1,377,506.

    Pyrimidine disperse azo dyes - prepd from diazotisable aromatic amines,for textiles
    76.
    发明专利
    Pyrimidine disperse azo dyes - prepd from diazotisable aromatic amines,for textiles 未知

    公开(公告)号：DE2258609A1

    公开(公告)日：1974-06-06

    申请号：DE2258609

    申请日：1972-11-30

    Applicant: BASF AG

    Inventor： DUNKELMANN GUENTER DR ,  DEHNERT JOHANNES DR

    IPC: C09B29/36

    Abstract: Title dyes are of formula: D-N=N-A (I) where D is the residue of a diazotisable aniline substd by in not 1 2nd order substit., or of a diazotisable amino-naphthalene, aminobiphenyl, aminoazobenzene, aminoanthraquinone, or heterocyclic amine, and A is a gp. of formula: where Z is H or a (substd). (cyclo)aliphatic, araliphatic aromatic, or heterocyclic gp; Z1 is H or a (substd). (cyclo)aliphatic, araliphatic or aromatic gp; Z2 is H or a (substd) aliphatic gp. or Z1 and Z2 form a heterocyclic gp. with the N atom; Z3 has the same meaning as Z1, Z4 has the same meaning as Z2, Z3 and Z4 may form a heterocyclic gp. with the N atom, and 1 of the gps. Z1-Z4 is not H. Suitable 2nd order substits. include NO2. CN, alkanoyl, aroyl, alkyl- or phenyl-sulphonyl, carbalkoxy (substd). carbamoyl, or sulphamoyl, or sulphonic acid ester gps. I are yellow to blue and can be used to dye polyacrylonitrile, synthetic polyamide, cellulose, ester and esp. linear polyester textiles. Fast dyeings of good colour strength are obtd.

    Monoazo dispersion dyes - from 4,6-or 2,6-diamino pyrimidine coupling components
    80.
    发明专利
    Monoazo dispersion dyes - from 4,6-or 2,6-diamino pyrimidine coupling components 未知

    公开(公告)号：DE2202820A1

    公开(公告)日：1973-07-26

    申请号：DE2202820

    申请日：1972-01-21

    Applicant: BASF AG

    Inventor： DUNKELMANN GUENTER DR ,  DEHNERT JOHANNES DR

    IPC: C09B29/36

    Abstract: The dyes are of formula D-N=N-A, (in which D is the group of a diazo component and A is a group of formula (I) or (II): in which B is hydrogen, alkyl opt. substd. with hydroxy, alkoxy, alkanoyl oxy, or phenoxy, aralkyl cycloalkyl or opt. substd. phenyl, R is hydrogen, 1-8 C alkyl, 2-7 C hydroxyalkyl, 3-11 C alkoxyalkyl, up to 11 C phenoxyalkyl, 2-15 C carbalkoxyalkyl, up to 15 C acyloxyalkyl, opt. substd. phenyl, cyclohexyl, benzyl, phenylethyl or epsilon -N-pyrrolidonalkyl, R1 is hydrogen, 1-8 C alkyl, 2-7 C hydroxyalkyl or up to 15 C acyloxyalkyl, or RR1 together with N form a pyrrolidine, piperidine or morpholine group, R2 is as R and R3 as R1, but not all are hydrogen. The alkyl chains may be interrupted by O atoms. The dyes are yellow to blue and suitable for colouring of textiles of polyacrylonitrile, synthetic polyamides, cellulose esters, and esp. linear polyester, giving strong colours with good fastness.

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