公开(公告)号：WO1997006201A1

公开(公告)日：1997-02-20

申请号：PCT/NL1996000281

申请日：1996-07-08

Applicant: DSM N.V. ,  JANSSEN, Koen, Jan, Gerarda ,  RADEMAKERS, Gerardus, Arnoldus ,  RENKEMA, Jacob ,  VERWEIJ, Petronella, Danielle

Inventor： DSM N.V.

IPC: C08G81/02

CPC classification number: C08G83/005 ,  C08F8/00 ,  C08F8/10 ,  C08F8/30 ,  C08F8/34 ,  C08F8/42 ,  C08F8/46 ,  C08F255/023 ,  C08F290/04 ,  C08F290/042 ,  C08F2800/10 ,  C08F2810/20 ,  C08F2810/30 ,  C08F2810/40 ,  C08G81/02 ,  C08G81/021 ,  C08G81/024 ,  C10L1/146 ,  C10L1/1641 ,  C10L1/195 ,  C10L1/1963 ,  C10L1/198 ,  C10L1/236 ,  C10L1/2364 ,  C10L1/238 ,  C10L1/2468 ,  C10L1/285 ,  C10L10/00 ,  C10M133/52 ,  C10M145/10 ,  C10M149/02 ,  C10M155/02 ,  C10M157/00 ,  C10M2205/00 ,  C10M2205/024 ,  C10M2209/04 ,  C10M2209/06 ,  C10M2209/062 ,  C10M2209/08 ,  C10M2209/084 ,  C10M2209/086 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/24 ,  C10M2215/26 ,  C10M2217/00 ,  C10M2217/02 ,  C10M2217/028 ,  C10M2217/04 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2229/02 ,  C10M2229/04 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/043 ,  C10M2229/044 ,  C10M2229/045 ,  C10M2229/046 ,  C10M2229/047 ,  C10M2229/048 ,  C10M2229/05 ,  C10M2229/051 ,  C10M2229/052 ,  C10M2229/053 ,  C10M2229/054 ,  C10N2240/02 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/12 ,  C10N2240/121 ,  C10N2240/14 ,  C10N2240/40 ,  C10N2270/02 ,  C08F210/16 ,  C08F220/14

Abstract: A highly branched polymer in the form of a comb, star, nanogel and structural combinations thereof in which a plurality of polyolefin arms formed of polymers of 1-alkenes are attached to a backbone having repeating units containing aliphatic groups, aromatic groups, heteroatom-containing groups and combinations thereof.

Abstract translation: 梳状，星形，纳米凝胶及其结构组合形式的高支化聚合物，其中由1-烯烃聚合物形成的多个聚烯烃臂连接到具有含有脂族基团，芳族基团，含杂原子的重复单元的主链上 组及其组合。

公开(公告)号：WO1997000766A1

公开(公告)日：1997-01-09

申请号：PCT/NL1996000247

申请日：1996-06-14

Applicant: DSM N.V. ,  VAN DER LOO, Leonardus, Lambertus, Henricus

Inventor： DSM N.V.

IPC: B29C70/50

CPC classification number: B29C43/003 ,  B29C70/202 ,  B29C70/30 ,  B29K2105/0854 ,  F41H5/0485 ,  Y10T428/24074 ,  Y10T428/24116

Abstract: The invention relates to a ballistic-resistant moulded article containing a compressed stack of monolayers, with each monolayer containing unidirectionally oriented reinforcing fibres and at most 30 wt.% of a plastic matrix material and with the fibre direction in each monolayer being rotated with respect to the fibre direction in an adjacent monolayer, characterized in that the density ( rho P) of the compressed stack is at least 98.0 % of the theoretical maximum density. The invention also relates to a process for manufacturing the moulded article. The ballistic-resistant article may be used in, for instance, helmets, as inserts in bullet-proof vests, as armouring on military vehicles and in ballistic-resistant panels.

Abstract translation: 本发明涉及一种防弹模制品，其包含压缩的单层叠层，每层单层包含单向取向的增强纤维和至多30wt％的塑料基质材料，并且每个单层中的纤维方向相对于 相邻单层中的纤维方向，其特征在于压缩叠层的密度（rho P）至少为理论最大密度的98.0％。 本发明还涉及一种用于制造模制品的方法。 防弹制品可用于例如头盔，作为防弹背心中的插入物，作为对军车和防弹板的铠装。

公开(公告)号：WO1997000353A1

公开(公告)日：1997-01-03

申请号：PCT/NL1996000246

申请日：1996-06-14

Applicant: DSM N.V. ,  JACOBS, Martinus, Johannes, Nicolaas ,  BACH, Elke ,  SCHOLLMEYER, Eckhard ,  CLEVE, Ernst

Inventor： DSM N.V.

IPC: D06P05/20

CPC classification number: D06P3/79 ,  B29C2043/527 ,  D01F6/04 ,  D06P1/94 ,  D06P7/005

Abstract: The invention relates to a process for the dyeing of a highly oriented moulded article substantially consisting of a polyethylene having a weight average molecular weight of at least 400 kg/mol. The invention also relates to dyeing of articles containing such a moulded article and to moulded articles and articles that can be obtained by these processes. In the process according to the invention the moulded article is contacted, at a temperature between 100 and 130 DEG C to a supercritical liquid in which a dye is dissolved.

Abstract translation: 本发明涉及一种基本上由重均分子量至少为400kg / mol的聚乙烯组成的高取向模塑制品的染色方法。 本发明还涉及含有这种模制品的制品的染色以及可以通过这些方法获得的模制品和制品。 在根据本发明的方法中，模塑制品在100-130℃的温度下与染料溶解的超临界液体接触。

公开(公告)号：WO1997000296A1

公开(公告)日：1997-01-03

申请号：PCT/NL1996000220

申请日：1996-06-05

Applicant: DSM N.V. ,  STANSSENS, Dirk, Armand, Wim ,  VAN DEN BERG JETHS, Robert

Inventor： DSM N.V.

IPC: C09D167/00

CPC classification number: C09D133/064 ,  C08L67/00 ,  C09D5/032 ,  C09D163/00 ,  C09D167/00 ,  C08L2666/36 ,  C08L2666/28 ,  C08L2666/14

Abstract: The invention relates to a binder composition, a powder paint composition and a cross-linker that result in mat powder coatings. The mat powder coatings are obtained by adding melamine particles having a relatively small particle size. In a preferred embodiment a powder paint composition comprises (i) a polymer capable of reacting with epoxy groups, (ii) a cross-linker containing epoxy groups, wherein the cross-linker comprises at least one C5-C26 linear or branched aliphatic chain and the cross-linker has an epoxy functionality greater than 1, with the proviso that the epoxy groups are carried on the at least one aliphatic chain and (iii) melamine.

Abstract translation: 本发明涉及粘结剂组合物，粉末涂料组合物和导致垫粉末涂料的交联剂。 通过添加具有相对小的粒度的三聚氰胺颗粒获得垫粉末涂料。 在优选的实施方案中，粉末涂料组合物包含（i）能够与环氧基反应的聚合物，（ii）含有环氧基的交联剂，其中所述交联剂包含至少一个C 5 -C 26直链或支链脂族链和 交联剂具有大于1的环氧官能度，条件是环氧基承载在至少一个脂族链上，和（iii）三聚氰胺。

公开(公告)号：WO1996035739A1

公开(公告)日：1996-11-14

申请号：PCT/NL1996000188

申请日：1996-05-02

Applicant: DSM N.V. ,  NIJENHUIS, Atza, Jan ,  SERNÉ, Martien ,  DE BRABANDER-VAN DEN BERG, Ellen, Marleen, Monique ,  ABERSON, René

Inventor： DSM N.V.

IPC: C08G69/48

CPC classification number: C08G69/48 ,  C08G81/00 ,  Y10S424/16

Abstract: The invention relates to a star-shaped branched polyamide that has a high thermal stability and can be produced in existing production facilities for the corresponding linear polyamide. This is achieved by allowing the polyamide branches, at least three, to be formed from a multifunctional core having functional groups chosen from the group comprising amine and carboxyl groups, the amine or carboxyl groups being bound to an acyclic compound in which branching occurs, if it is branched, at a carbon atom, or via an acyclic chain to a heterocyclic compound showing point symmetry. The process for the preparation is carried out under the conditions of the preparation of the corresponding linear polyamide. It proves to be possible to obtain, after shorter polymerisation times, a product with mechanical properties that are comparable with those of the linear polyamide after significantly longer polymerisation times. Examples of suitable multifunctional nuclei are 2,4,6-trisaminocaproic acid-1,3,5-triazine and 4-aminomethyl-1,1-octanediamine.

Abstract translation: 本发明涉及一种具有高热稳定性的星形支链聚酰胺，可用于相应线性聚酰胺的现有生产设备中。 这是通过使具有至少三个的聚酰胺支链由具有选自胺和羧基的官能团的多官能核心形成的，胺或羧基与发生分支的非环状化合物结合，如果 其在碳原子处分支，或通过无环链与显示点对称性的杂环化合物。 制备方法在制备相应的线性聚酰胺的条件下进行。 在更短的聚合时间后，证明可以在显着更长的聚合时间后获得具有与线性聚酰胺相当的机械性能的产品。 合适的多功能核的实例是2,4,6-三氨基己酸-1,3,5-三嗪和4-氨基甲基-1,1-辛二胺。

公开(公告)号：WO1996032528A1

公开(公告)日：1996-10-17

申请号：PCT/NL1996000147

申请日：1996-04-04

Applicant: DSM N.V. ,  ALLIEDSIGNAL INC.

Inventor： DSM N.V. ,  ALLIEDSIGNAL INC. ,  HENDRIX, Jan, Agnes, Jozef ,  KERSSEMAKERS, Arnoldus, Maria ,  MOHAJER, Yousef ,  SLOAN, Forrest, Eugene ,  JANSSEN, Nicolaas, Jan, Maria, Leonie

IPC: D05C17/02

CPC classification number: D06N7/0068 ,  D06N7/0065 ,  D06N2201/0263 ,  D06N2203/065 ,  D06N2209/105 ,  D06N2209/1628 ,  D06N2213/03

Abstract: The present invention relates to a tufted fabric and a method of manufacturing the same. The tufted fabric generally comprises a primary backing and tufts mounted in the primary backing to form a fabric with a faceside having piles and a backside having loops. A thermoplastic polymer adhesive, which bonds the tufts to the primary backing, is formed by applying a reactive mixture comprising a polymerizable monomer to the backside of the tufted fabric and in-situ polymerizing the monomers to form the thermoplastic polymer adhesive. The process is particularly advantageous for the manufacture of recyclable tufted fabrics in which the adhesive polymer and tufts are formed from substantially the same polymer. The tufted fabric can be used in articles, such as, for example carpets, rugs and upholstery.

Abstract translation: 本发明涉及一种簇绒织物及其制造方法。 簇状织物通常包括主衬里和安装在主衬里中的簇，以形成具有桩的面的背面和具有环的背面的织物。 通过将包含可聚合单体的反应性混合物施加到簇绒织物的背面并原位聚合单体以形成热塑性聚合物粘合剂，形成将簇结束到主衬里的热塑性聚合物粘合剂。 该方法对于可再生簇绒织物的制造特别有利，其中粘合剂聚合物和簇由基本上相同的聚合物形成。 簇绒织物可用于制品中，例如地毯，地毯和室内装潢。

公开(公告)号：WO1996032427A1

公开(公告)日：1996-10-17

申请号：PCT/NL1996000151

申请日：1996-04-09

Applicant: DSM N.V. ,  BORESKOV INSTITUTE OF CATALYSIS ,  ZAKHAROV, Vladimir Aleksandrovitch ,  BUKATOV, Gennadii Dmitrievich ,  SERGEEV, Sergei Andreevich

Inventor： DSM N.V. ,  BORESKOV INSTITUTE OF CATALYSIS

IPC: C08F10/00

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/6565 ,  C08F2500/15 ,  C08F2500/18 ,  C08F2500/24

Abstract: The invention relates to a method for the preparation of a catalyst suitable for the polymerisation of an olefine by contacting a magnesium compound with a halogenized Ti compound, characterised in that the magnesium compound is obtained by: a) contacting metallic magnesium with an aromatic halide RX, where R is an aromatic group containing from 6 to 20 carbon atoms and X is a halide, whereupon the dissolved reaction product I is separated from the solid residual products and then b) adding an alkoxy group or aryloxy group-containing silane compound to the obtained reaction product I at a temperature of from -20 to 20 DEG C, whereupon the precipitate formed is purified to obtain reaction product II, which subsequently during a step c is contacted with TiCl4 as halogenized Ti compound and is purified to obtain a catalyst.

Abstract translation: 本发明涉及通过使镁化合物与卤化Ti化合物接触来制备适用于烯烃聚合的催化剂的方法，其特征在于镁化合物是通过以下方法获得的：a）使金属镁与芳族卤化物RX 其中R是含有6至20个碳原子的芳族基团，X是卤化物，随后将溶解的反应产物I与固体残余物分离，然后b）将含有烷氧基或含芳氧基的硅烷化合物加入到 得到的反应产物I在-20至20℃的温度下进行纯化，得到反应产物II，反应产物II随后在步骤c中与作为卤化Ti化合物的TiCl 4接触并纯化得到催化剂。

公开(公告)号：WO1996030340A1

公开(公告)日：1996-10-03

申请号：PCT/NL1996000116

申请日：1996-03-19

Applicant: DSM N.V. ,  MULDERS, Joannes, Maria, Cornelis, Antonius ,  CALLANT, Dominique, Monique, Charles ,  CASTELIJNS, Anna, Maria, Cornelia, Francisca

Inventor： DSM N.V.

IPC: C07D209/48

CPC classification number: C07D209/48 ,  Y02P20/582

Abstract: Method for the preparation of N-alkoxy-(tetra-or hexahydro)-phthalimide according to formula (I), R1 being methyl or ethyl and R2 and R3 being each independently of one another hydrogen or alkyl with 1-4C atoms of R2 and R3 together with the carbon atom to which they are bonded forming a ring with 5 or 6 C atoms, wherein the salt of the corresponding N-hydroxy-(tetrahydro- or hexahydro)-phthalimide according to formula II; with R2 and R3 as defined and M being an alkali metal, is brought into contact with R1Cl as alkylating agent, wherein R1 has the mentioned meaning. The N-alkoxy-(tetra- or hexahydro)-phthalimide can afterwards be converted with the aid of hydroxylamine sulphate into the corresponding alkoxyamine after which the alkoxyamine obtained can be isolated. In this manner a simple and commercially attractive process for the preparation of O-(m)ethylhydroxylamine can be implemented.

Abstract translation: 用于制备根据式（I）的N-烷氧基 - （四或六氢） - 邻苯二甲酰亚胺的方法，R 1是甲基或乙基，R 2和R 3各自独立地是氢或具有1-4C原子的R 2的烷基和 R3与它们所键合的碳原子一起形成具有5或6个C原子的环，其中根据式II的相应的N-羟基 - （四氢 - 或六氢） - 邻苯二甲酰亚胺的盐; 其中R 2和R 3如所定义，M是碱金属，与R1Cl作为烷基化剂接触，其中R1具有上述含义。 N-烷氧基 - （四或六氢） - 邻苯二甲酰亚胺可以随后借助于硫酸羟胺转化成相应的烷氧基胺，之后可以分离获得的烷氧基胺。 以这种方式，可以实现用于制备O-（m）乙基羟胺的简单和商业上有吸引力的方法。

公开(公告)号：WO1996028396A1

公开(公告)日：1996-09-19

申请号：PCT/NL1996000110

申请日：1996-03-12

Applicant: DSM N.V.

Inventor： DSM N.V. ,  SZUM, David, M. ,  BISHOP, Timothy, E. ,  SCHMID, Steven, R.

IPC: C03C25/02

CPC classification number: C09D175/16 ,  C03C25/106 ,  C03C25/1065 ,  C08G18/672 ,  Y10T428/2938 ,  C08G18/48

Abstract: Provided is a radiation-curable, glass optical fiber coating composition which when suitably cured exhibits resistance to attack from hydrocarbon gel cable filling material. The composition contains about 10 to about 90 % by weight of a first radiation-curable oligomer; from 0 to about 40 % by weight of a reactive diluent; from 0 to about 40 % by weight of a photoinitiator; from 0 to about 10 % by weight of a pigment; and about 10 to about 90 % by weight of a second radiation-curable oligomer according to the following formula (1): R - L - C - L - R , where R and R , independently, each represents a radiation-curable functional group; L and L , independently, each represents an alkyleneoxy chain having from about 2 to about 40 carbon atoms, wherein L and L are linked to C through an oxygen atom; C comprises a hydrocarbon having from about 5 to about 40 carbon atoms and containing at least one cyclic group.

Abstract translation: 提供了一种可辐射固化的玻璃光纤涂层组合物，其在适当固化时表现出抗烃凝胶电缆填充材料的抵抗性。 该组合物含有约10至约90重量％的第一可辐射固化的低聚物; 0至约40重量％的反应性稀释剂; 0至约40重量％的光引发剂; 0至约10重量％的颜料; 和约10至约90重量％的根据下式（1）的第二可辐射固化低聚物：R 1 -L 1 -C 1 -L 2 -R 2， 其中R 1和R 2各自独立地表示可辐射固化的官能团; L 1和L 2独立地表示具有约2至约40个碳原子的亚烷基氧基，其中L 1和L 2通过氧原子与C 1连接; C 1包含具有约5至约40个碳原子并含有至少一个环状基团的烃。

公开(公告)号：WO1996020247A1

公开(公告)日：1996-07-04

申请号：PCT/NL1995000441

申请日：1995-12-21

Applicant: DSM N.V. ,  REPIN, Johannes, Fredericus ,  BRULS, Wilhelmus, Gerardus, Marie ,  CHODAK, Ivan ,  CHORVATH, Igor

Inventor： DSM N.V.

IPC: C08L23/10

CPC classification number: C08K5/14 ,  C08L23/0815 ,  C08L23/12 ,  C08L23/16 ,  C08L53/00 ,  C08L2312/00 ,  C08L23/10 ,  C08L2666/06

Abstract: The invention relates to a cross-linked polymer composition containing 40-90 wt.% propylene-ethylene copolymer with 8-20 wt.% ethylene and 10-60 wt.% ethylene- alpha -olefin copolymer with 75-90 wt.% ethylene and a density of 920-890 kg/m , having a notched Izod impact strength >/= 10kJ/m at -20 DEG C and a flexural modulus higher than 500 MPa. The cross-linked polymer composition is prepared by melting and kneading propylene-ethylene copolymer and ethylene- alpha -olefin copolymer in the presence of a radical forming agent, a cross-linking agent and, eventually a peroxide inhibitor.

Abstract translation: 本发明涉及含有40-90重量％丙烯 - 乙烯共聚物和8-20重量％乙烯和10-60重量％乙烯-α-烯烃共聚物与75-90重量％乙烯的交联聚合物组合物 和密度为920-890kg / m 3，在-20℃下具有缺口伊佐德冲击强度> / = 10kJ / m 2，弯曲模量高于500MPa。 交联聚合物组合物通过在自由基形成剂，交联剂和最终的过氧化物抑制剂的存在下熔融和捏合丙烯 - 乙烯共聚物和乙烯-α-烯烃共聚物来制备。