ISOMERIZATION OF HALOGENATED THIOPHENES

    公开(公告)号:AU578290B2

    公开(公告)日:1988-10-20

    申请号:AU4288185

    申请日:1985-05-24

    Applicant: HOECHST AG

    Abstract: The invention relates to a process for the isomerization of halogenated thiophenes on zeolite catalysts. In this manner, in particular, 2-chlorothiophene is isomerized to 3-chlorothiophene and 2-bromothiophene is isomerized to 3-bromothiophene. Particularly suitable zeolites are synthetic zeolites of the pentasil, mordenite or faujasite type in their acid form.

    72.
    发明专利
    未知

    公开(公告)号:BR8700302A

    公开(公告)日:1987-12-01

    申请号:BR8700302

    申请日:1987-01-23

    Applicant: HOECHST AG

    Abstract: The invention relates to hemiacetals of glyoxylic esters and to a process for obtaining a glyoxylic ester having a C1 to C4 ester group from a mixture which essentially contains a glyoxylic ester of this type plus water and/or a C1 to C4 alcohol ROH. In this, the glyoxylic ester and the water and/or the alcohol are partly or completely in a chemically bonded form. A higher alcohol R'OH having a boiling point above 180 DEG C. is added, and distillation is carried out under a pressure not exceeding 800 mbar to remove first the water and/or the alcohol ROH and then the glyoxylic ester.

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