公开(公告)号：DE1132540B

公开(公告)日：1962-07-05

申请号：DEF0029388

申请日：1959-09-15

Applicant: HOECHST AG

Inventor： ORTHNER DR LUDWIG ,  HORST DR KARL ,  SCHARF DR ALFRED ,  KIRST DR WERNER ,  OXE JOSEF ,  GROSS DR RICHARD

IPC: C09B67/42

公开(公告)号：DE1130161B

公开(公告)日：1962-05-24

申请号：DEF0031517

申请日：1960-06-25

Applicant: HOECHST AG

Inventor： ORTHNER DR LUDWIG ,  HORST DR KARL ,  WELLENS DR HEINO

IPC: C08K5/20 ,  D06M15/423

公开(公告)号：DE1127084B

公开(公告)日：1962-04-05

申请号：DEF0023756

申请日：1957-08-14

Applicant: HOECHST AG

Inventor： BRODERSEN DR KARL ,  ORTHNER DR LUDWIG

IPC: C08G73/00 ,  D06M15/61

公开(公告)号：DE1124933B

公开(公告)日：1962-03-08

申请号：DEF0016651

申请日：1955-01-24

Applicant: HOECHST AG

Inventor： REUTER DR MARTIN ,  ORTHNER DR LUDWIG

IPC: C07F7/00 ,  D06M13/503

公开(公告)号：DE1061513B

公开(公告)日：1959-07-16

申请号：DEF0025048

申请日：1958-02-14

Applicant: HOECHST AG

Inventor： REUTER DR MARTIN ,  WOLF DR EHRHARD ,  ORTHNER DR LUDWIG

IPC: A01N57/18 ,  C07F9/54 ,  C08G12/40 ,  C08G79/06 ,  D06M15/431 ,  D06M15/667 ,  D06P1/607 ,  D06P3/76

Abstract: Quaternary phosphonium compounds are obtained by reacting tris (hydroxymethyl)-phosphine with a methylol compound capable of forming a resin and, if desired, converting the resulting quaternary phosphonium hydroxide into a salt with an inorganic or organic acid, e.g., phosphonic, acetic, benzoic or picrolonic. Suitable methylol compounds include the reaction products of formaldehyde with phenol, cresols, urea, thiourea, ethylene-urea, dicyandiamide, benzene sulphonamide, p-toluene sulphonamide or melamine. The process of the invention may be effected by adding the methylol compounds to tris (hydroxymethyl)-phosphine dissolved in a solvent such as water or a lower-alkanol or, advantageously, in a molten state, and further heating to about 40 DEG C.-120 DEG C., e.g. 60 DEG C.-90 DEG C. The products are stated to be pesticides and flame-proofing agents, e.g. for textiles. Examples describe the preparation of tris-(hydroxymethyl) phosphonium derivatives from monomethylol-urea, dimethylol-urea, trimethylol-melamine, trimethylol-phenol, 2,5- dimethylol - p - cresol and N - methylol - p-toluene-sulphonamide. Specifications 871,190 and 881,656 are referred to.

公开(公告)号：DE1045651B

公开(公告)日：1958-12-04

申请号：DEF0020936

申请日：1956-07-31

Applicant: HOECHST AG

Inventor： ORTHNER DR LUDWIG ,  BRODERSEN DR KARL

IPC: C08G12/42

公开(公告)号：DE1045100B

公开(公告)日：1958-11-27

申请号：DEF0018054

申请日：1955-07-28

Applicant: HOECHST AG

Inventor： REUBER DR RUDOLF ,  GROSSMANN DR MAX ,  ORTHNER DR LUDWIG

IPC: C08G63/83 ,  C08G63/86

公开(公告)号：DE1042518B

公开(公告)日：1958-11-06

申请号：DEF0019503

申请日：1956-02-11

Applicant: HOECHST AG

Inventor： ORTHNER DR LUDWIG ,  BRODERSEN DR KARL ,  GUTMANN DR WALTER ,  LINKE DR FRITZ

IPC: D06M15/423 ,  D06P1/56

公开(公告)号：DE917970C

公开(公告)日：1954-09-16

申请号：DEF0009180

申请日：1942-09-29

Applicant: HOECHST AG

Inventor： ORTHNER DR LUDWIG ,  WAGNER DR HERMANN ,  HARTMANN DR ADOLF ,  HAUSSMANN DR HANS ,  SCHNEIDERS DR JOSEF

IPC: D06M13/432

公开(公告)号：DE907163C

公开(公告)日：1954-03-22

申请号：DEF0003959

申请日：1938-06-08

Applicant: HOECHST AG

Inventor： BALLE DR GERHARD ,  ROSENBACH DR JOHANN ,  ORTHNER DR LUDWIG

IPC: D06M13/248 ,  D06M13/322