公开(公告)号：JP2011071086A

公开(公告)日：2011-04-07

申请号：JP2010008791

申请日：2010-01-19

Applicant: Sony Corp ,  ソニー株式会社

Inventor： LUO WEI ,  YAMADA SEIJI ,  GOTO YOSHIO ,  TOKITA YUICHI

IPC: H01M14/00 ,  H01L31/04

CPC classification number: H01L51/0093 ,  B82Y10/00 ,  H01L51/4206 ,  H01L51/4253 ,  Y02E10/542 ,  Y02P70/521

Abstract: PROBLEM TO BE SOLVED: To provide a liquid-uncontacting all-solid-state protein photoelectric conversion element capable of working even when a liquid such as water is not present in the interior or exterior of the element, and to provide a method of manufacturing the element.
SOLUTION: The liquid-uncontacting all-solid-state protein photoelectric conversion element has a structure in which a solid protein layer 13 including an electron transport protein is sandwiched between an electrode 11 and an electrode 12. The solid protein layer 13 is immobilized on both the electrode 11 and the electrode 12. The solid protein layer 13 contains no liquid such as water. The solid protein layer 13 includes a monomolecular film or multi-molecular film of the electron transfer protein.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供即使在诸如水的液体不存在于元件的内部或外部中时也能够工作的液体 - 非接触全固体蛋白质光电转换元件，并且提供一种方法 制造元件。 解决方案：液体 - 非接触全固态蛋白质光电转换元件具有其中包含电子传输蛋白的固体蛋白质层13夹在电极11和电极12之间的结构。固体蛋白质层13是 固定在电极11和电极12上。固体蛋白质层13不含水等液体。 固体蛋白质层13包括电子转移蛋白质的单分子膜或多分子膜。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2010267459A

公开(公告)日：2010-11-25

申请号：JP2009117107

申请日：2009-05-14

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KUMITA HIDEYUKI ,  TOKITA YUICHI ,  SAKAI HIDEKI ,  MITA HIROKI ,  NAKAGAWA TAKAAKI

IPC: H01M4/86 ,  C12N9/02 ,  H01M8/00 ,  H01M8/02 ,  H01M8/10 ,  H01M8/16

CPC classification number: Y02E60/527 ,  Y02P70/56

Abstract: PROBLEM TO BE SOLVED: To provide a fuel cell for preventing deterioration of output characteristics, lifetime, and efficiency or the like and for improving maintenance rate of current by preventing elution of an electronic mediator fixed to a positive electrode together with an enzyme, and its manufacturing method. SOLUTION: A positive electrode 2 of a bio-fuel cell is manufactured by contacting a solution, in which a hydrophobic electronic mediator such as ferrocene is dissolved in an organic solvent having phase separation with water, on the surface of an electrode on which an enzyme is fixed, after the enzyme is fixed on the surface of the electrode with gaps inside, and fixing the hydrophobic electronic mediator on the surface of the electrode. As the organic solvent which carries out phase separation with water, methyl-isobutyl ketone or the like is used. By containing a water repellent material in this solution, the water repellent material is formed on the surface of the electrode to make it water repellent. Carbon powder or the like is used as the water repellent material. COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供一种用于防止输出特性，寿命和效率等的劣化的燃料电池，以及通过防止固定在正极上的电子介体与酶一起洗脱来提高电流的维持率 ，及其制造方法。 解决方案：生物燃料电池的正极2是通过使电极表面上溶解有疏水性电子介质如二茂铁的溶液与具有相分离的有机溶剂溶解在其上的溶液来制造的 将酶固定在具有内部间隙的电极表面上，并将疏水性电子介体固定在电极表面上之后固定酶。 作为与水进行相分离的有机溶剂，可以使用甲基 - 异丁基酮等。 通过在该溶液中含有防水材料，在电极表面上形成防水材料，使其具有防水性。 碳粉等用作防水材料。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2010251533A

公开(公告)日：2010-11-04

申请号：JP2009099642

申请日：2009-04-16

Applicant: Sony Corp ,  ソニー株式会社

Inventor： TOKITA YUICHI ,  GOTO YOSHIO ,  SHIMURA JUSUKE ,  YAMADA SEIJI ,  LUO WEI ,  YAMAGUCHI DAISUKE ,  ITO DAISUKE

IPC: H01L51/30 ,  B82B1/00 ,  G01J1/02 ,  H01L27/146 ,  H01L31/10 ,  H01L49/00 ,  H01L51/05

CPC classification number: H01L51/0595 ,  B82Y10/00 ,  H01L51/0093 ,  H01L51/4206

Abstract: PROBLEM TO BE SOLVED: To provide a color imaging device and a photosensor that are stably usable for a long period with high definition and high sensitivity, and to provide a molecular device which is suitably used therefor. SOLUTION: A photoelectric conversion element is formed by immobilizing cytochrome c552 13 on a gold electrode 11 via a self-assembled molecular monolayer 12 and coupling an electron transfer protein 14 having a photoelectric conversion function to the cytochrome c552 13. Alternatively, a photoelectric conversion element for green light or blue light is formed by immobilizing zinc-substituted cytochrome c552 or zinc-modified porphyrin cytochrome c552 on the gold electrode. The color imaging device or photosensor is constituted using those photoelectric conversion elements. COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供一种能够以高清晰度和高灵敏度长期稳定使用的彩色成像装置和光电传感器，并提供适合使用的分子装置。 解决方案：通过自组装分子单层12将细胞色素c55213固定在金电极11上并将具有光电转换功能的电子转移蛋白14与细胞色素c55213结合而形成光电转换元件。或者， 通过将锌取代的细胞色素c552或锌修饰的卟啉细胞色素c552固定在金电极上，形成绿光或蓝光的光电转换元件。 彩色成像装置或光电传感器使用这些光电转换元件构成。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2010245015A

公开(公告)日：2010-10-28

申请号：JP2009126873

申请日：2009-05-26

Applicant: Sony Corp ,  ソニー株式会社

Inventor： MITA HIROKI ,  TOKITA YUICHI ,  SAKAI HIDEKI ,  KUMITA HIDEYUKI ,  TSUNODA MASAYA ,  NAKAGAWA TAKAAKI

IPC: H01M8/06 ,  C12M1/40 ,  H01M8/04 ,  H01M8/16

CPC classification number: H01M8/16 ,  H01M8/06 ,  H01M8/0625 ,  Y02E60/527

Abstract: PROBLEM TO BE SOLVED: To provide technology for actually generating power even when using highly safe and accessible material, such as, food and drink items or garbage as fuel for a bio fuel cell. SOLUTION: A fuel reformer is used for the fuel cell which produces an electromotive force with the progress of oxidation-reduction reaction using enzyme as a catalyst and includes, at least a primary fuel inlet part for introducing primary fuel; a fuel-reforming part communicating with the primary fuel inlet part for reforming the primary fuel into secondary fuel which can release electrons by the oxidation-reduction reaction by using the enzyme as the catalyst; and a secondary fuel supply part communicating with the fuel reforming part for supplying the secondary fuel to the fuel cell. COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：即使使用高度安全和可访问的材料，例如食品和饮料物品或垃圾作为生物燃料电池的燃料，也提供实际发电的技术。 解决方案：燃料重整器用于随着使用酶作为催化剂的氧化还原反应进程产生电动势的燃料电池，并且至少包括用于引入初级燃料的初级燃料入口部分; 与主燃料入口部分连通的燃料重整部分，用于将主燃料重整成二次燃料，其可以通过使用酶作为催化剂通过氧化还原反应释放电子; 以及与所述燃料重整部连通以将所述二次燃料供给到所述燃料电池的二次燃料供给部。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2010209375A

公开(公告)日：2010-09-24

申请号：JP2009054493

申请日：2009-03-09

Applicant: Sony Corp ,  ソニー株式会社

Inventor： MATSUMOTO RYUHEI ,  GOTO YOSHIO ,  SAKAI HIDEKI ,  TOKITA YUICHI

IPC: C25B1/00 ,  H01M8/16

CPC classification number: H01M8/16 ,  C12Q1/004 ,  C12Q1/32 ,  Y02E60/527

Abstract: PROBLEM TO BE SOLVED: To provide an electrolytic process, by which reverse reaction of an enzyme can be suppressed and the electrolysis rate can be improved.
SOLUTION: When fuel such as glucose is electrolyzed by using an enzyme/electron mediator 1 in which an enzyme such as gluconic acid-5-dehydrogenase, alcohol dehydrogenase and malic acid dehydrogenase, and an electron mediator are fixed to a porous electrode made of a carbon material or the like, the electrolytic reaction is induced only within the enzyme/electron mediator 1 electrode.
COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供可以抑制酶的反向反应并且可以提高电解速率的电解方法。 解决方案：当通过使用其中酶如葡萄糖酸-5-脱氢酶，醇脱氢酶和苹果酸脱氢酶的酶/电子介体1和电子介体被固定到多孔电极上时，诸如葡萄糖等燃料电解 由碳材料等制成，仅在酶/电子介体1电极内诱导电解反应。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009245920A

公开(公告)日：2009-10-22

申请号：JP2008262592

申请日：2008-10-09

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KUMITA HIDEYUKI ,  GOTO YOSHIO ,  NAKAGAWA TAKAAKI ,  SAKAI HIDEKI ,  MITA HIROKI ,  MATSUMOTO RYUHEI ,  TOKITA YUICHI

IPC: H01M8/02 ,  H01M4/90 ,  H01M8/16

CPC classification number: H01M8/16 ,  Y02E60/527

Abstract: PROBLEM TO BE SOLVED: To provide a fuel cell that, when an enzyme is immobilized on at least one of a positive electrode and a negative electrode, can obtain satisfactory buffering capability even during high-output operation, can satisfactorily exhibit capability inherent in the enzyme, and has excellent performance. SOLUTION: The fuel cell is a biofuel cell having a structure comprising a positive electrode 2 and a negative electrode 1 arranged opposite to each other through an electrolyte layer 3 containing a buffering substance, an enzyme being immobilized on at least one of the positive electrode 2 and the negative electrode 2. An imidazole ring-containing compound is included as a buffering substance in the electrolyte layer 3. Further, at least one acid selected from a group consisting of acetic acid, phosphoric acid, and sulfuric acid is added. For the imidazole ring-containing compound, imidazole, 1-methylimidazole, 2-methylimidazole, 4-methylimidazole, or 2-ethylimidazole is used. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：为了提供一种燃料电池，当酶固定在正极和负极中的至少一个上时，即使在高输出操作期间也可以获得令人满意的缓冲能力，可以令人满意地展现出固有的能力 在酶中，具有优异的性能。 解决方案：燃料电池是具有包括通过包含缓冲物质的电解质层3彼此相对布置的正极2和负极1的结构的生物燃料电池，酶固定在至少一个 正电极2和负极2.在电解质层3中含有含咪唑环的化合物作为缓冲物质。此外，添加至少一种选自乙酸，磷酸和硫酸的酸， 。 对于含咪唑环的化合物，使用咪唑，1-甲基咪唑，2-甲基咪唑，4-甲基咪唑或2-乙基咪唑。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009140824A

公开(公告)日：2009-06-25

申请号：JP2007317488

申请日：2007-12-07

Applicant: Sony Corp ,  ソニー株式会社

Inventor： SAKAI HIDEKI ,  NAKAGAWA TAKAAKI ,  TSUNODA MASAYA ,  TOKITA YUICHI

IPC: H01M8/16 ,  H01M4/86 ,  H01M8/00 ,  H01M8/02 ,  H01M8/04

CPC classification number: H01M4/86 ,  H01M8/04186 ,  H01M8/16 ,  Y02E60/527

Abstract: PROBLEM TO BE SOLVED: To provide a fuel cell capable of simply supplying fuel and efficiently generating electricity. SOLUTION: The fuel cell generates electricity by the progress of an oxidation-reduction reaction with an enzyme as a catalyst. The fuel cell includes at least a fuel vaporization layer formed by vaporizing fuel, a negative electrode to which the vaporized fuel is supplied from the fuel vaporization layer, and a positive electrode connected to the negative electrode in a proton conductible state. Since the fuel cell supplies fuel in a vaporized state to an electrode, the vaporized fuel is supplied into the electrode, the reaction on the inner surface of the electrode fully progresses, and thus higher output can be obtained by efficient generation of electricity. Since the fuel is supplied in the vaporized state to the electrode even when enzyme or the like is fixed to the electrode, the enzyme or the like can be prevented from being eluted into liquid fuel, and a reduction in output due to the elution of the enzyme or the like can be prevented. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 解决的问题：提供能够简单地供给燃料并有效发电的燃料电池。 解决方案：燃料电池通过用酶作为催化剂进行氧化还原反应而发电。 燃料电池至少包括通过汽化燃料形成的燃料汽化层，从燃料汽化层供给汽化燃料的负极和在质子传导状态下与负极连接的正电极。 由于燃料电池向电极供给处于汽化状态的燃料，因此将汽化后的燃料供给到电极中，电极内表面的反应充分进行，能够通过有效的发电获得更高的输出。 由于即使将酶等固定在电极上，也能将蒸发状态的燃料供给电极，所以可以防止酶等被洗脱成液体燃料，并且由于 可以防止酶等。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009139257A

公开(公告)日：2009-06-25

申请号：JP2007316759

申请日：2007-12-07

Applicant: Amano Enzyme Inc ,  Sony Corp ,  ソニー株式会社 ,  天野エンザイム株式会社

Inventor： TOKITA YUICHI ,  SAKAI HIDEKI ,  SUGIURA TOSHIYUKI ,  GOTO CHINATSU ,  TAKAHASHI TETSUYA

IPC: G01N27/327 ,  G01N27/416 ,  H01M4/90 ,  H01M8/16

CPC classification number: H01M8/16 ,  H01M4/8652 ,  H01M4/90 ,  Y02E60/527

Abstract: PROBLEM TO BE SOLVED: To provide an electrode producing a reduced coenzyme, in a multi-stage manner from a given substrate. SOLUTION: The electrode contains at least 2-hydroxycarboxylic acid producing enzyme, 2-oxo acid producing enzyme and 2-oxo acid carboxy-lyase. Since this electrode has the 2-oxo acid carboxy-lyase which is a decarboxylase, as well as, the 2-hydroxycarboxylic acid producing enzyme and the 2-oxo acid producing enzyme which are oxidoreductases, an oxidation product having a carboxyl group which does not react with the oxidoreductases, can be decarboxylated and converted into a substance on which the oxidoreductases can act. Accordingly, oxidation reaction and decarboxylation reaction are allowed to proceed repeatedly for a given substrate, and a large amount of reduced coenzyme is produced, accompanying the proceeding of the reactions. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：从给定的基材以多级方式提供产生还原型辅酶的电极。 解决方案：电极含有至少2-羟基羧酸生成酶，2-氧代酸产生酶和2-氧代酸羧基裂解酶。 由于该电极具有脱羧酶的2-氧代羧基裂解酶，以及作为氧化还原酶的2-羟基羧酸生成酶和2-氧代酸生成酶，具有羧基的氧化产物不是 与氧化还原酶反应，可以脱羧并转化为氧化还原酶可以作用的物质。 因此，对于给定的底物，允许反复进行氧化反应和脱羧反应，随着反应的进行，产生大量还原型辅酶。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009049012A

公开(公告)日：2009-03-05

申请号：JP2008208838

申请日：2008-08-14

Applicant: Sony Corp ,  ソニー株式会社

Inventor： SAKAI HIDEKI ,  NAKAGAWA TAKAAKI ,  TOKITA YUICHI ,  HATASAWA TAKENOBU

IPC: H01M8/16 ,  C12M1/00 ,  H01M4/90 ,  H01M8/00

CPC classification number: H01M8/16 ,  C12Q1/001 ,  Y02E60/527 ,  Y02P70/56

Abstract: PROBLEM TO BE SOLVED: To provide a biofuel cell capable of drastically improving a current density or an output density by optimizing concentration of an electronic mediator to be immobilized together with an enzyme to a cathode or an anode, and to provide a manufacturing method thereof. SOLUTION: The biofuel cell has a structure in which a positive electrode 2 and a negative electrode 1 are opposed to each other via an electrolyte layer 3 provided therebetween, at least either the positive electrode 2 or the negative electrode 1 made of an electrode on which at least one kind of enzymes and at least one kind of electron mediators are immobilized. A concentration of the electron mediator immobilized on the electrode is at least 10 times a Michaelis constant K m of the enzyme of the electron mediator, which is determined by measurement in solution. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供能够通过优化将待固定在阴极或阳极上的酶固定的电子介体的浓度来显着改善电流密度或输出密度的生物燃料电池，并提供制造 方法。

解决方案：生物燃料电池具有通过设置在其间的电解质层3使正极2和负极1相互相对的结构，至少由正极2或负极1制成的正极2或负极1 其上固定有至少一种酶和至少一种电子介体的电极。 固定在电极上的电子介体的浓度是电子介体酶的米氏常数K SB> m / s>的10倍，这是通过溶液中的测量来确定的。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2006156354A

公开(公告)日：2006-06-15

申请号：JP2005304863

申请日：2005-10-19

Applicant: Sony Corp ,  ソニー株式会社

Inventor： TOKITA YUICHI ,  HATAKEYAMA TSUKASA ,  SAKAI HIDEKI ,  SATO ATSUSHI ,  NAKAGAWA TAKAAKI ,  TOMITA TAKASHI

IPC: H01M8/16 ,  C12N9/02 ,  C12N11/14

CPC classification number: Y02E60/527

Abstract: PROBLEM TO BE SOLVED: To provide a fuel cell which widely improves an output by using an electronic mediator in which a potential can be raised while taking a large current value. SOLUTION: In the fuel cell including a structure having a fuel electrode 1 and an air electrode 3 facing to each other via an electrolyte layer 5 of a proton conductor, and an enzyme immobilization electrode in which at least fuel decomposition enzyme and an electronic mediator are immobilized to the fuel electrode 1, a concrete chemical constitution of the electronic mediator is specified. The electronic mediator are 2-amino -1, 4-naphthoquinone (ANQ), 2-methoxy -1, 4-naphthoquinone (MNQ), etc. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种燃料电池，其通过使用能够提高电位的电子介体而大幅度地提高输出，同时获得大的电流值。 解决方案：在包括具有通过质子导体的电解质层5彼此面对的燃料电极1和空气电极3的结构的燃料电池中，以及酶固定电极，其中至少燃料分解酶和 电子介体被固定在燃料电极1上，指定了电子介体的具体化学结构。 电子介体是2-氨基-1,4-萘醌（ANQ），2-甲氧基-1,4-萘醌（MNQ）等。版权所有（C）2006，JPO＆NCIPI