Abstract:
PROBLEM TO BE SOLVED: To reduce the deterioration of a battery characteristic under a high temperature environment by treating with a gas a lithium composite oxide of a specific composition in an atmosphere of specific CO2 concentration and a dew point lower than a specific temperature, in a nonaqueous electrolytic secondary battery using the lithium composite oxide as a positive electrode active material. SOLUTION: The lithium composite oxide expressed by the formula, Lix Niy M(1-y) O2 (M is at least one of transition metals B, Al, Ga, and In; 0.05 =0.1 vol.% and a dew point =0.1 vol.% and a dew point
Abstract:
PURPOSE:To maintain high capacity and high preservation by using a carbon material satisfying a condition that rhoP/rhoHe is smaller than a specific value, when assumed rhoP for true specific gravity measured by a liquid immersion substitution method with n-Bu0H serving as an immersion liquid in a negative electrode and f He for true specific gravity measured by a gas substitution method using Li. CONSTITUTION:In this nonaqueous electrolyte secondary battery, a graphitizationdifficult carbon material is used in a negative electrode, and an Li transition metal compound oxide, represented by a formula LixNiyCo1-yO2 (0.05
Abstract:
PURPOSE:To provide a nonaqueous electrolyte secondary battery with high energy density and long cycle life. CONSTITUTION:A nonaqueous electrolyte secondary battery contains a positive electrode 2 using a lithium-containing composite oxide as a positive active material, a negative electrode 1 using a carbonaceous material capable of doping/undoping lithium as a negative active material, and a nonaqueous electrolyte. Lithium-nickel-cobalt composite oxide represented by Li1-xNiyCo1-yO2 (0.50
Abstract:
PURPOSE:To set a grain size of positive electrode active material large, and reduce a self-discharge rate by granulating material powder comprising inorganic compound for the positive electrode active material preliminarily, and then baking obtained grains. CONSTITUTION:In a nonaqueous secondary battery using inorganic compound for positive electrode active material, material powders comprising inorganic compound are mixed, granulated, and baked, and obtained matters are used for the positive electrode active material. An average grain size of the positive active material can thus be set large, thereby a nonaqueous electrolyte secondary battery with a reduced self-discharge rate can be provided.
Abstract:
PURPOSE:To cut the current securely at the time of over charge, and prevent the heat generation with quick temperature rise and the relatively quick damage by including a specified quantity of lithium oxalate in a positive electrode mainly composed of lithium compound oxide. CONSTITUTION:A positive electrodes 2, which is mainly composed of LixMO2, and a negative electrode 1, which can be doped and undoped with lithium, are wound through a separators 3, and they are housed in a battery can 5 under the condition that insulating thin plates 4 are placed in the upper and the lower of this winding body, and nonaqueous electrolyte is filled to form a nonaqueous electrolyte secondary battery. M means transition metal, and 0.05
Abstract:
PURPOSE:To prevent the heat generation with quick temperature rise and the relatively quick damage even if over-charging is performed with high current by forming a part, which is coated with lithium carbonate, in the surface of a positive electrode mainly composed of lithium compound oxide. CONSTITUTION:A positive electrode 2, which are mainly composed of LixMO2, and a negative electrode 2, which can be doped and undoped with lithium, are wound through a eparators 3, and the positive electrode 1 and the negative electrode 2 are housed in a battery can 5 under the condition that insulating plates 4 are placed in the upper and the lower of the winding body to form a nonaqueous electrolyte secondary battery. M means transition metal, and at least one kind of Co and Ni is desirable, and 0.05
Abstract:
PURPOSE:To prevent drop of the capacity and achieve excellent charging/ discharging cycle characteristics by synthesizing LiMO2 as pos. electrode active substance from Li compound and a compound incl. transfer metal in an atmosphere which has a specific oxygen concentration value in %. CONSTITUTION:LixMO2 as active substance of pos. electrode 2, where M is one or more sorts of transfer metal, and 0.05
Abstract:
PURPOSE:To obtain an organic electrolyte secondary battery of large capacity in addition to little deterioration in capacity associated with charging and discharging duty, by using LixMnOy as material of the positive electrode of the organic electrolyte secondary battery, and specifying an analysis value of valency number of Mn of LixMnOy and a ratio x of Li. CONSTITUTION:An organic electrolyte secondary battery comprises a negative electrode material to contain lithium, a positive electrode material described by a formula LixMnOy, and organic electrolyte liquid, and maintains such a relation that an analysis value m of a valency number of Mn in a formula LixMnOy and an atomic ratio x of Li/Mn satisfy 0.5
Abstract:
PROBLEM TO BE SOLVED: To make high safety and high battery characteristics compatible in a nonaqueous electrolyte battery used by a charging voltage over 4.20 V. SOLUTION: A separator used for the nonaqueous electrolyte secondary battery in which a positive electrode and a negative electrode are opposedly arranged via the separator, and in which an open circuit voltage in a full charged state per a pair of the positive electrode and the negative electrode is in a range of 4.25 V to 6.00 V, has a constitution that the separator has a base material layer made of a polyolefin based resin material, and a surface layer which is formed at least at a positive electrode side face of the base material layer and made of at least one kind of a group consisting of polyvinylidene fluoride, polytetrafluoro ethylene and polypropylene, and that by forming a coating layer in which at least one kind of a group consisting of all aromatic polyamide resin, polyimide and ceramics is contained in, for example, at least one of surfaces of the separator, at least one kind of the group consisting of the all aromatic polyamide resin, polyimide and ceramics exists on the outermost surface of the separator. COPYRIGHT: (C)2009,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte secondary battery capable of improving a cycle property and a low temperature load property. SOLUTION: The nonaqueous electrolyte secondary battery has a cathode 2 and an anode 3 electrochemically doping and dedoping lithium, and an electrolyte interposed between the cathode 2 and the anode 3. The cathode 2 contains a cathode activator made by mixing a first activator expressed by general formula: Li t CoM s O 2 and a second cathode activator expressed by general formula: Li x Ni (1-y-z) Co y Mn z A a O 2 . In the formula, M denotes a metal, 0≤s≤0.03, 0.05≤t≤1.15, and A denotes aluminum, 0.05≤x≤1.15, 0.15≤y+z≤0.70, 0.05≤z≤0.40, 0≤a≤0.10. COPYRIGHT: (C)2006,JPO&NCIPI